Rosebriar-SP121107 (3) STATEMENT OF CONCRETE MIX DESIGN GATE: 112A5,2007 07
......... .__..
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ASHLEY CONCRETE MIX DESIGN rt. C7020-3K2
DALLAS,TX
0,y i MAX SIZE AGG.: 1 k.
PROJECT: I f R.EXL I.S TH NfA
RAPID STRENGTH CONCRETE i COMPRESSIVE STREi3GTI 3000 PSI at 2 rotas
SLUMP: 150 mm+f-50 mm(B In 41-Y)
' )Z.' LOCJN STRUCTURE: Pavement
MIX DESIGN METHOD: ACT 211
MATERIAL SOURCES:
ARCHIENGfit Cement CTS CEMENT-RAPID SET
CONTRACT.:I'.: Sand TXt CORP.-PARADISE SAND PLANT
SUPPLIER: ASHLEY CONCRETE Rock Da CORP.-MILL CREEK
PRIMARY AGGRIMATE GRADATION CONCRETE MIX DESIGN(SSD BASIS)FOR 1 CUBIC YARD AND 1 CUBIC METER
.US Standard : :.
Ill '• .""3 ,:€1111'7! 2dmp► =MN MATERIAL SP OR ABS CU BATCH WT - BATCH WT
M4 ( I t1YCS �� ♦i ,_ CU `T tae KoS
111111111111110 0 0 53 0 1111M 1 Cubic Y_aM 1 Conic Meter
IlUalaCni NMI_1111111111man gm dement 7.00 2.98 + 0.00 0 lbs 0 kgs
t 100 ® 100 En i00 i ter�YEK�l+NT: ` 2,98 3.54 ' 858 Ma 390 cgs
1-5' PPM r' 100 111111.1. 00111111 100 Washed Canasta Sand:,1+ 2.80 8.82 1841 914 ogs r 100�r 90 98 a efirtAgig ,
0.00 0.00 0 the 0 kgs
'75' ErTtrn IIKEINIMINII IIIIIIIIWININ Ma 25.0mm.1') 2.76 9.95 1707 Its 1013
a- '� �
1„1 100����� 27.Srtum►x ikntp( 'U2"IAg� D�iO 0.00 :� 0 Itls 0 � � ;
_}t_ 94511Im 100 ME M 20 MI MC L.W.: NIA tr oo 000 0 ; the 0
r ."'•" 88miamm e Ilimmu ao fat Loose wine
::,11 81�w�1 - 39 Air 1; % 0840 0.34 1 0.00 ova.. 0.0 1
IltilliMMINEI11111111111111111111111111111111111111111M au s. 1.00 I 4.27 1 267 I bs i 158 I Item
N ! ADMIXTURES: 70 degree F dome indica*t dksUby below for vdtsne celculatbre
E50 11r7r11 22 111111111111 1111.1111111111111111111 ME RscoverlDelvo mektwt aao 0.06 52.8 oaf 20 Nets
/t Ileum ���� ] F.G.abicAdd.o rt I 4.00 0:03 . 28.3 1 cos 1 1.0 Ears
*,I t 75um J ��� 0 27.00
283 1111111111MIN 8.07 WIN .502 **See shed blow for doeagdantbisnt cond'don at time of actual placement
- Carlo add b be dosed st use dbiastbrt of producer on Job site
- Al the Indicated sdmbdtra dosages and ambient lamPeTehifee.the
PERTmENT PROPERTIES: Donors*I Is designed f r 35 mkt to 45 mmn i►t U apt and a final alt of
W1(C;Pk Unit Weight CemeMttkws Factor: approximately 8 to 20 intrudes after kIIW sat.
4.57 galleadc 154.54 pd 7.00 IIkJtss yd - Thiel batdtbtg oleo mix to verify water demand end strength Is required.
0.4i by wt(lbs) 100.0%RSC - Use warmed water b hest comet*to 70 to 80 F(21.1 to 28..7 C)for
18.28 645 kg 2476 kgroum ambient temperetares under 50 degrees F.
0.41 bywt(igs) - Use deed water Cool concrete to 70 to 80 F(21.1 to 26.7 C)to
ambled temperatures in excess of 90 degrees F.
Reterreng_Atimtdure Dosage GUN
Ambient TemQ.Deena,F 50 60 70 80 90 j
Anent Tend C 10.0 16.8 21,1 28.7 1 32,2
G Cibic Add ,Age eft'er Arid firm th l.9 6.5 y.1 7.7 ;
Atie' Fiesta Strength C:ompmesive Strength
'yy�■
MPa� !Os ,.,
s 20.70 illE t.l
3hisiiiiiiMMEM MIMI illana 3500
ELM 11112211111 11M1111111111111111 2023
n"fl Mai IIIMMIIMIN 31.05 4500
, __... � . . .w.� .- ..F _�..now see corned•CS • g •esemsoe•Commie Pharmacy'•Consent Ai'•OmPai •VA.ndelfic'•U yk'`• ...
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CONCRETE MIX DESIGN REPORT ACI 214(2 HR. &28 DAYS)
ASHLEY CONCRETE 5526 CRYSTAL LAKE MIX DESIGN:C7020-3K2/4500
DALLAS, TX 75236 BASIS FOR SELECTION
ACI 318, SECT 5.3.2.1
28 DAY AVG STRENGTH 6067
2 HOUR COMPRESSIVE STRENGTH 28 DAY COMPRESSIVE STRENGTH
# DATE
SLUMP AIR% CYL 1 CYL 2 AVG CYL 1 CYL 2 AVG RUNAVG
1 3/25/2011 5,00 N/A 2976 2976 4127 4127 4127.00
2 3/25/2011 5.50 3150 3150 6090 6090 5108.50
3 3/25/2011 4.50 3890 3890 5880 5880 5365.67
4 3/25/2011 6.00 3251 3251 4632 4632 5182.25
5 3/25/2011 5.00 4340 4340 5170 5170 5179.80
6 3/25/2011 5.00 6220 6220 8010 8010 565150
7 3/25/2011 5.00 2978 2978 4631 4631 5505.71
8 3/25/2011 5.50 4850 4850 7070 7070 5701.25
9 3/25/2011 6.00 3011 3011 5260 5260 5652.22
10 4/9/2011 4.50 5160 5160 6960 6960 5783.00
11 4/9/2011 4.50 5230 5230 7360 7360 5926.36
12 4/9/2011 430 5770 5770 7370 7370 6046,67
13 4/9/2011 5.00 4330 4330 5800 5800 6027.69
14 4/9/2011 6.00 4380 4380 6200 6200 6040.00
15 4/9/2011 6.00 6210 6210 7390 7390 6192.14
16 4/9/2011 5.50 5750 5750 7070 7070 6188.75
17 4/9/2011 5.00 5220 5220 7680 7680 6276.47
18 4/9/2011 5.00 4580 4580 6890 6890 6310.56
19 4/16/2011 430 3580 3580 6320 6320 6311.05
20 4/16/2011 5.50 4030 4030 5320 5320 6261.50
21 4/16/2011 5.00 4040 4040 5560 5560 6228.10
22 4/16/2011 5.00 4350 4350 6120 6120 6223.18
23 4/16/2011 6.00 4550 4550 6340 6340 6228.26
24 4/16/2011 4.50 3216 3216 4860 4860 6171.25
25 4/30/2011 5.00 4440 4440 5380 5380 6139.60
26 4/30/2011 5.00 4230 4230 5290 5290 6106.92
27 4/30/2011 5.50 3520 3520 5140 5140 6071.11
28 4/30/2011 6.00 4030 4030 5731 5731 6058.96
29 4/30/2011 5.00 4820 4820 7010 7010 6091.76
30 4/30/2011 5.00 3560 3560 5370 5370 6067.70
q1p.... TXI corp.
Dallas Blend Plant TECHNICAL SERVICES LAB
11139A Goodnight Lane PHONE: 972-647-7232
Dallas, Texas 75229
FAX: 972-647-7244
DATE June 22, 2011
COMPANY/NAME Ashley Concrete / Jeff
MATERIAL Concrete Sand
TEST RESULTS '
ASTM C 33
SIEVE SIZE WT. RETAINED % PASSING %RETAINED SPECIFICATIONS
U. S. METRIC
Retained Passing
3/8" 9.5mm 0 100.0% 0.0% 0 100
#4 4.75mm 1.4 99.8% 0.2% 0 - 5 95 - 100
#8 2.36mm 78.5 89.8% 10.2% 0 - 20 80 - 100
#16 1.16mm 233.5 69.6% 30.4% 15 - 50 50 - 85
#30 .600mm 366.4 52.3% 47.7% 40 - 75 25 - 60
#50 .300mm 622.2 19.0% 81.0% 70 - 95 5 - 30
#100 .150mm 752.3 2.0% 98.0% 90 - 100 0 - 10
#200 .075mm 762.9 0.6% 99.4% 97 - 100 0 - 3
FM 2.68
TOTAL WEIGHT 767.8
SPECIFIC TEST RESULTS
TxDot 403-A Specific Gravity(SSD) 2.69 TxDot 411-A Magnesium Soundness 6
Sodium Soundness 3
TxDot 403-A Absorption 0.7
Unit Weight:
TxDot 612-J Acid Insoluble Residue 69 Dry Loose 104.2 LB./CF,
Dry Rodded 110.5 LB./CF.
TxDot 203-F Sand Equivalent 92
u a...,F& ?.- , n jai Vkr.k _ 1..:: .skip;:::iP
Skeet Caruthers
TXI REPRESENTATIVE
:,••'0 .
.2 ‘;'':.,,
Mill TXI Creek core TECHNICAL SERVICES LAB
3 Miles South Hwy 1 PHONE: 972-647-7232
Mill Creek , Oklahoma FAX 972-647-7244
DATE June 22, 2011
COMPANY/NAME Ashley Concrete / Jeff
MATERIAL 1" - #4 Class A
TEST RESULTS
..
UL . . . ,r
SIEVE SIZE WT. RETAINED % PASSING % RETAINED SPECIFICATIONS
U. S. METRIC
11/2"' 37.5mm Retained Passing
0.0 100.0% 0.0% 0 100
1" 25.0mm 0.6 98.1% 1.9% 0 - 5
3/4" 19.0mm 10.2 67.1% ° 95 -100
1/2" 12.5mm 32.9/0 (10 - 40) (60 - 90)
19.9 35.8% 64.2% 40 - 75 25 - 60
3/8" 9.5mm 25.5 17.7% 82.3%
#4 4.75mm 29.7 4.2% 95.8% 90 - 100
#8 2.36mm 30.4 0 - 10
1.9% 98.1% 95 - 100 0 - 5
TOTAL WEIGHT 31.0
SPECIFIC TEST RESULTS
TxDot 403-A Specific Gravity(SSD) 2.78 TxDot 411-A Magnesium Soundness 3
Sodium Soundness 1
TxDot 403-A Absorption 0.5
Unit Weight:
TxDot 410-A L A Abrasion 25 Dry Loose 96.5 LB./CF.
Dry Rodded 106 LB./CF. .
TxDot 413-A Clay Lumps 0
TxDot 406-A Decantation 0.7
,, ,. . F ., irtzii:
Skeet Caruthers
TXI REPRESENTATIVE.
The Euciki Chemical Company
'9218 Redwood Road
Clavetand,OH 44110
Phone:800-321-7828
Fax:216-531-9595
EUCLID CHEMKAi wwweackichonecat own
Prepared for: 6/29/2010
Ashley Concrete
Dallas, TX
Project:
Certification of Eucon Air 30
The Euclid Chemical Company hereby certifies that its liquid admixture, Eucon
Air 30, meets or exceeds the requirements of ASTM C-260. Furthermore, it is
also certified that Eucon Air 30 does not contain calcium chloride nor added
chloride ions other than those normally present in water.
For additional information please contact Euclid Chemical Technical Support at
•
(800)321-7628.
• Euclid Chemical
Technical Support Department
WWI*"MR28
BARBARA L.MUER
.4 AVIA°
Opp MY
4 As>' efilIMMER 10,2012
® All 9M Company
' .
vaiUn:: 217 Camp V/isdunz Road
SHLE
Ste. \� Bw\ 9|2
Terp
0 Duncan N, -75116-- Off: -1419-916-3o 7
{ax: 888-517-6977
Volume Metric Mixers buOatt �rcoucrc�ocmo
serving the V�F�/ llctroplmz ~ '
February 28,2012
Re: Approved Water Source
Ashley Concrete LLC, solely uses approved City of Dallas water for all our concrete mixes.
Thanks,
Jeff Savera
Vice President Sales
jua ncrete.conl
............. . ..........
•
Construction Cement s �.:
CERTIFICATE OF COMPLAINCE
Date: October 16, 2009.
Re: Cement Preference Certification.
This letter is to certify that Rapid Set cement conforms to the requirements of Piano,
Texas Public Works as indicated below.
1. Rapid Set cement is produced in a dry kiln process.
2. The Rapid Set cement kiln process has an emission level of NOx below
1.7 lbs. per ton of clinker.
•
Ryan G--finer
Quality Manager
P[Y:lfe ssSorxi S,�.w.' ef3+3rc✓?:�i,x::"'s
• s;;.,i;° ,,,:,3 4 O:w,)..,..
Material Safety Data Sheet
The Euclid Chemical Company
V4eeurseion ss 1 NAI.R.,..30 te,G A.., L...t U 1fiE....t.1ODl A 1R'36- v... 5 i,Te
2;5'2".
Print Date 03/11/20013
REVISION DATE:03/03/2006
SECTION 1 - PRODUCT IDENTIFICATION
Trade name : EUCON AIR 30-55 GAL DRUMEUCON AIR 30-55 GAL DRUM
Product code : 723 55
COMPANY : Euclid Chemical Company
19218 Redwood Road
Cleveland,OH 44110
Telephone : 1-800-321-7628
Emergency Phone: : U.S.only: 1-800-255-3924
International Users Call Collect: 1-813-248-0585
Product use : Admixture
SECTION 2- HAZARDS IDENTIFICATION
Emergency Overview
Brown. Liquid. No serious effects anticipated under normal conditions of use. Leave area to breathe fresh air.
Avoid further overexposure.If symptoms persist,get medical attention.
Acute Potential Health Effects!Routes of Entry
Inhalation No serious effects anticipated under normal conditions of use.
Eyes . Direct contact may cause mild irritation.
Ingestion , May cause gastrointestinal irritation,nausea,and vomiting.
Skin : May cause mild irritation.
Aggravated Medical Conditions
Pre-existing eye,skin and respiratory disorders may be aggravated by exposure.
Chronic Health Effects
Fillers are encapsulated and not expected to be released from product under normal conditions of use.
SECTION 3-PRODUCT COMPOSITION
Chemical Name CAS-No. Weight%
Water 7732-18-5 >60.0
Triethanolamine 27323-41-7 3.0-7.0
dodecylbenzenesulfonate
Trade secret NJ TSRN#51721300-5592P 1.0-5.0
SECTION 4- FIRST AID MEASURES
Get immediate medical attention for any significant overexposure.
Inhalation : Leave area to breathe fresh air.Avoid further overexposure.If symptoms persist, get
medical attention,
a,Icompeny 1/5 723 55
Material Safety Data Sheet
e
The Euclid Chemical Company
E'/ UN AIR �4 ,a5'G`l. DRUMEtl `011(A1R43 557i ® ° � :: r"
Version 1 � _,... . .. . �... ,.. .:. .m.
Print Date 03/11/2008'
REVISION DATE:03/03/2006
Eye contact : Flush with water for 15 minutes. If irritation persists,get medical attention.
Skin contact : Wash area of contact thoroughly with hand cleaner followed by soap and water. If
irritation, rash or other disorders develop,get medical attention immediately.
Ingestion : Get medical attention. Do not induce vomiting.
Notes to physician : Not applicable.
SECTION 5-FIRE FIGHTING MEASURES
Flash point Not available.
Method Not available.
Lower explosion limit Not available.
Upper explosion limit : Not available.
Autoignition temperature Not available.
Extinguishing media This product is not expected to burn under normal conditions of use.
Hazardous combustion Carbon monoxide and carbon dioxide can form.Smoke,fumes.
products
Protective equipment for Use accepted fire fighting techniques. Wear full firefighting protective
firefighters clothing,including self-contained breathing apparatus(SCBA).
Fire and explosion conditions This product not expected to ignite under normal conditions of use.
SECTION 6-ACCIDENTAL RELEASE MEASURES
Transfer to appropriate container for disposal.Stop flow. Contain spill. Keep out of water courses. Absorb
spill in sand,earth or other suitable material.Transfer to appropriate container for disposal.Use appropriate
protective equipment.Avoid contact with material.
SECTION 7-HANDLING AND STORAGE
Handle in compliance with common hygienic practices.Clean hands thoroughly after handling.Keep from
freezing.Do not use in confined or poorly ventilated areas.Prevent inhalation of vapor,ingestion,and contact
with skin eyes and clothing.Keep container closed when not in use. Precautions also apply to emptied
containers.Store in sealed containers in a dry,ventilated warehouse location above freezing.
SECTION 8-EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protection equipment
Respiratory protection : Not required under normal conditions of use.Wear appropriate, NiOSH/MSHA
approved respirator with combination particulate filter and vapor/gas
removing cartridge when the ventilation Is not adequate or if it is necessary to
abrade or grind surfaces coated with this product.
Hand protection : Use suitable impervious rubber or vinyl gloves and protective apparel to
reduce exposure.
Eye protection : Wear appropriate eye protection.Wear chemical safety goggles and/or face
artgaconpany 2/5 723 55
Material Safety Data Sheet
The Euclid Chemical Company
#EUCON AIR 30 55`GAf DR HELICON AIR 30 5_ A S 641 V 7 s :' *
Version 1 Print Date 03/11/200:
REVISION DATE: 03/03/2006
shield to prevent eye contact. Do not wear contact lenses.Do not touch eyes
with contaminated body parts or materials.Have eye washing facilities readily
available.
Skin and body protection : Prevent contact with shoes and clothing.Use rubber apron and overshoes.
Protective measures : Other equipment not normally required.Use professional judgment in the
selection,care,and use.
Engineering measures : Not required under normal conditions of use.Use local exhaust when the
general ventilation is inadequate.
exposure Limits
No known components with exposure limits.
SECTION 9-PHYSICAL AND CHEMICAL PROPERTIES
Form : Liquid
Color : Brown
Odor : Soapy
pH : 7-9
Vapour pressure : Not available.
Vapor density : Heavier than air
Melting point/range : Not available.
Freezing point : Not available.
Boiling point/range : 214°F, 101 °C
Water solubility : Soluble
Specific Gravity : 1 +1-0.01
%Volatile Weight : 94.0%
SECTION 10- REACTIVITY/STABILITY
Substances to avoid : Strong acids.Strong bases.
Stability : Stable
Hazardous polymerization : Will not occur.
SECTION 11 -TOXICOLOGICAL INFORMATION
No Data Available
an9lcm+ +v 3/5 723 55
Material Safety Data Sheet
0\>
The Euclid Chemical Company
l'10:0014114(464561401, 4/0000NA0404-C. 1.„MATTTIMOrgt
Version 1 Print bate 03/11/2008
REVISION DATE:03/03/2006
SECTION 12- ECOLOGICAL INFORMATION
No Data Available
SECTION 13- DISPOSAL CONSIDERATIONS
Disposal Method : Waste not regulated under RCRA. Dispose of in compliance with state and local
regulations.
SECTION 14-TRANSPORTATION /SHIPPING DATA
TDG/DOT Shipping Description:
NOT REGULATED
:SECTION 15- REGULATORY INFORMATION
North American Inventories:
All components are listed or exempt from the TSCA inventory.
This product or its components are listed on,or exempt from the Canadian Domestic Substances List.
U.S.Federal Regulations:
SARA 313 Components None present or none present In regulated quantities.
SARA 311/312 Hazards : Acute Health Hazard
OSHA Hazardous Components:
Triethanolamine dodecylbenzenesulfonate 27323-41-7
OSHA Status:Considered : Irritant
hazardous based on the
following criteria:
OSHA Flammability : Not Regulated
Regulatory VOC(less water and : 0 g/I
exempt solvent)
VOC Method 310 : %
U.S.State Regulations:
MASS RTK Components : Triethanolamine 27323-41-7
dodecylbenzenesulfonate
Penn RTK Components : Water 7732-18-5
Triethanolamine 27323-41-7
dodecylbenzenesulfonate
NJ RTK Components : Water 7732-18-5
AnIM company 4/5 723 55
Material Safety Data Sheet
41"\r,
The Euclid Chemical Company
�EL/Ct3N A;R 3D r:; GAS
Version 1
REVISION DATE:03/03/2006 Print Date 03/11/2008
Triethanolamine 27323-41-7
dodecylbenzenesulfonate
Trade secret NJ TSRN#51721300-5592P
Chemicals known to the State of California to cause cancer birth defects and/or other reproductive harm:
None known.
SECTION 16- OTHER INFORMATION
4
HMIS Rating:
Health 1 0=Minimum
Flammability 0 1 =Slight
Reactivity 0 2=Moderate
PPE 3=Serious
4=Severe
Further information:
For Industrial Use Only. Keep out of Reach of Children.The hazard information herein Is offered solely for the
consideration of the user,subject to their own investigation of compliance with applicable regulations,including
the safe use of the product under every foreseeable condition.
Prepared by:-Rich Mikol
Legend
ACGIH-American Conference of Governmental Hygienists PEL-Permissible Exposure-Comprehensive Environmental Response,Compensation,and
posure Limit
Act
h' RCRA-Resource Conservation and Recovery Act
DOT-Department of Transportation RTK-Right To Know
DSL-Domestic Substance List SARA-Superfund Amendments and Reauthorization Act
EPA-Environmental Protection Agency STEL-Short Term Exposure Limit
HMIS-Hazardous Materials Information System TLV-Threshold Limit Value
tARC-international Agency for Research on Cancer TSCA-Toxic Substances Control Act
MSHA-Mine Safety Health Administration TWA-Time Weighted Average
NDSL-Non-Domestic Substance List V-Volume
NIOSH-National Institute for Occupational Safety and Health VOC-Volatile Organic Compound
NTP-National Toxicology Program WHMIS-Workplace Hazardous Materials Information
System
OSHA-Occupational Safety and Health Administration
Anl O:nvenx
5/5 723 55
Product,#: 756338 Name: CITRIC ACID POWDER Desc:
From: BRENNTAG SOUTHWEST INC. To: Tuesday,February 23,2010
GAIM
Material Safety Data Sheet BRENNi'A
MSDS Revision Date 10/22/2007
Page I of
1. Product and Company Identification
Product Identity: Citric Acid Teehnicid Information:27B-839-1200
CAS: 77-92-9(Anhydrous) Emergency Number: 800-42443110(t lEMfREC)
5349-28-1(Monohydrate)
Chemical Formula:H3CHH507(Anhy s)
H3CSH507.H20(Monohydrate)
Molecular Weight: 132.12 (Anhydrous)
210.14 (Monohydrate)
Synonyms: 2-Hydroxy-1.2,3-propanetriccarboxyIc acid
Company Identity: DISTRIBUTED BY BRENNTAG
8renag Greet Lakes LLC. Bremtag NJ-South Inc. Rrennta,Northeast,Inc.
4420 It Harley Davidson Avenue 1405 Hwy 136 W 81 West Hiller Lane
Wauwatosa.WI 53225 Henderson.KY 42420 Reading.PA 19605
8resntes Southeast Inc. Brenntag Southwest.Inc. $renmap Pacific.Inc.
2000 East Pettigrew Street 610 Fisher Road 10747 Patterson Place
Durham,NC 27703 Longview.IX 75804 Santa Fe Springs.CA 90630
2. Hazards Identification }
Emergency Overview
WARN ,
IRRITANT!
CAUSES SEVERE EYE MRITATION.
CAUSES tRRITATIQN TO SKIN AND RESPHIATORY TRACT.
Inhttian
Causes kttitation to the respiratory tract.Symptoms may include coughing,shortness of breath.
Iveat ett
Product#: 75633k Name: CITRIC ACID POWDER Desc:
From: BRENNTAG SOUTHWEST INC. To: Tuesday,February 23,2010
Material Safety Data Sheet BRENNTAGAffitt
MSDS Revision Date 10/22/2007
Page 2 of 7
Causes irritation to the gastrointestinal tract.Symptoms may include nausea,vomiting and diarrhea.Extremely
large and dosages may produce gastrointestinal disturbances.Calcium deficiency in blood may result in severe
cases of ingestion.
Skin Canted
Causes irritation to skin.Symptoms include redness.itching,and pain.
Eye Centect
Highly irritating:may also be abrasive.
3. Composition/Information on Ingredients
Cos# w_ Chemical Nem Percent by Weight
77-92-9 Citric Acid 90-100%
4. first Aid Measures
Intelatham
Remove to fresh air.If nut breathing.give artificial respiration.If breathing is difficult.give oxygen.Get medical
attention,
Ingsation:
Induce vomiting immediately as directed by medical personnel.Never give anything by mouth to an unconscious
person.Get medical attention.
Skin Contact: .
Immediately flush skin with plenty of water far at least 15 minutes.Remove contaminated clothing and shoes_Get
medical attention.Wash clothing before reuse.Thoroughly clean shoes before reuse.
Eye Contact:
• Immediately flush eyes with plenty of water for at least 15 minutes.lifting lower and upper eyelids occasion*,
Get medical attention immediately.
•
Product#: 756338 Name: CITRIC ACID POWDER Desc:
From BRENNTAC SOUTHWEST INC. To Tuesday,Februexy 23,2010
Material Safety Data Sheet BRENNTAG
MSUS Revision Date l0/27/21107
Page 3 of 7
5. Fire Fighting Measures
Go to Sucre 9 for Flsmma p Prwertios.
Rre:
Not considered to be a fire hazard.
Embalm
Not considered to be an explosion hazard.
Fire Extiegoishing Media:
Use suitable extinguishing media.
Steel Information:
In the event of a fire.wear full protective clothing and NIUSH-approved self-contained breathing apparatus with
full faceplece operated in the pressure demand or other positive pressure mode.
6. Accidental Release Measures
isolate and ventilate the area and prevent entry to unnecessary and unprotected workers. Wear appropriate
personal protective equipment. Prevent exposure to the environment. Clean up material in a way that minimizes
generation of dust and fumes and place in a suitable container for proper disposal.
7. Handling and Storage
Keep in a tightly closed container.Protect from physical damage.Stare in a cool,dry,ventiated area away from
sources of heat,moisture and incompatibilities.Containers of this material may be hazardous when empty since
they retain product residues(dust.solids);observe all warnings and precautions listed for the product.
Product#: 756338 Name: CITRIC ACID POWDER Desc:
From: BRENNTAG SOUTHWEST INC. To: Tuesday,February 23,2010
Material Safety Data Sheet BRENNTAG AlMir
MSDS Revision Date 10/22/20117
Page 4 of 7
8. Exposure Controls/Personal Protection
OSHA PEE for Particles net otherwise regulated(PNCR):
total Dust: 15 mg/m3
Respirable Fraction: 5 mg/m3
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne
Exposure limits.Local exhaust ventilation is generally preferred because it can control the emlons of the
contaminant at its source:preventing dispersion of it into the general work area.Please refer to the ACGIH
docwnent./ndustr/al Yanttrstiowt AMinus'ofRecommandedPractices most recent edition,for details.Personal
Respirators(NIOSH Approved):ff the exposure limit is exceeded and engineering controls are not feasible.a half
faceplece particulate respirator(NIOSH type N95 or better filters)may be worn for up to ten times the exposure
omit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is bwest.A fuN-face piece particulate respirator(MUSH type NIDO filters)may be warn up to 511 times
the exposure limit or the maximum use concentration specified by theropriate regulatory agency.or
respirator suppler,whichever is lowest.If oil particles(e.g.lubricants,cutting fluids,glycerine,'etc.)are present.
use a NIUSH type R or P filter.for emergencies or instances where the exposure levels are not known.use a full-
facepiece positive•pressure,air-supplied respirator.WARNING:Air-purifying respirators do not protect workers
in oxygen-deficient atmospheres.
Consult your industrial hygienist.
Skin Proton:
Use impervious gloves clothing,boots,and equipment to prevent contact with this material. Consult your
industrial hygienist
Eye Protection
Splash-proof or dust resistant goggles are advised. Consult your industrial hygienist.
Product#: 756338 Name: CITRIC ACID POWDER Desc:
From BRE\FNTAG SOLTHVVEST INC. To: Tuesday,February 23,2010
Material Safety Data Sheet BRENNTAM
MSOS Revision Bite 111/22/2007
Page 5 of 7
9. Physical and chemical Properties
Appearance: White granules.
Oder: Odorless
Odor Threshold: No Information Found
Physical State: Solid
pH: 2.2(0.1N sal)
Malting Paint: 153C(307F)
Boiling Point: No information Found
Auto-ignition Temperature: No information Found
Flash Point: Not Applicable
Upper Explosive Limit: Not Applicable
Lower Explosive Limit: Not Applicable
Vapor Pressure: 1.0 P 714C(1317F)
Vapor Density: No Information found
Specific Gravity: 1.665 P 20C/4C
Solubility in Water: ca.60 g/100 ml P 20C(Anhydrous)
Evaporation Rate: Not Applicable
Coefficient of water/olL Not Applicable
10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Uectmpositlun Prod
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Pulymeriza •
Product 4: 756338 Name: CITRIC ACID POWDER Dese:
From BRENNTAG SOUTHWEST INC. To Tuesday,February 23,2010
1 BRENNTAGOM
Material Safety Data Sheet
nos Revision Data 10/22/2007
Page 6 of 7
Will not occur.
lnmanpatifbaattes:
Metal nitrates(potentially explosive reaction),a&ali carbonates and bicarbonates.potassium tartrate.Will
corrode copper,zinc,aluminum and their alloys,
Detainee to Avnid:
Heat,flames,ignition sources and incompatibles.
11. Toxicological Information
Acute Oral/Dermel/Infteletien Effects
Oral rat 1050:3 gm/kg:
Irritation skin rabbit:500 mg/24H mild;
Eye rabbit:750 ug/24H severe.
12. Ecological Information
Potassium Hydroxide:Tim:B0 ppm/Mosquito fish/24 hr./Fresh water
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste
facility.Although not a listed RCRA hazardous waste,this material may exhibit one or more characteristics of a
hazardous waste and require appropriate analysis to determine specific disposal requirements.Processing,use
or contamination of this product may change the waste management options.State and local disposal regulations
may differ from federal disposal regulations.Dispose of container and unused contents in accordance with
federal state and local requirements.
• t
Product#: 756338 Name: CITRIC ACID POWDER Desc:
From BRENN`fAG SOUTHWEST INC. 1'o: Tuesday,February 23,2010
Material Safety Data Sheet BRENNTAGAIlliIMF
MSDS Revision Data 10/22/2007
Page 7 of 7
4. Transport Information
NOT HAZARDOUS ACCORDING TO THE RAM
15. Regulatory Informat on
SARA 302 SARA 304 SARA 30 gifflaA TSCA hyena
Not listed Nat Listed Not Listed Not listed Yes
Wanda a LPremutioie 65
Not listed
16. Other Information
This MSDS is provided as an information resource only. It should not be taken as a warranty or representation
for which Orennteg assumes legal liability. While Brennteg believes the information contained herein is accurate
and compiled from sources believed to be reliable,it is the responsibility of the user to investigate and verify its
identity. The buyer assumes all responsibility for using and handling the product in accordance with applicable
federal state,and local regulations.
MSDS I mad by: BRENNTAI
Brendan Great lakes tIC. Brenntan Mid-South Inc, Grenrtag Northeast.Inc.
4420 H.Hwy Davidson Avenue 1485 Hwy 13B W SI West H>dIar Lone
Wauwatesa WI 53225 Henderson.KY 42420 Reading PA 196115
Branotag Southeast.Inc. Brennteq Southwest.Ins. Bremen Paciris.Ins.
21100 East Pettigrew Street 610 Fisher Road 111147 Patterson Place
Durham NC 27783 Longview,TX 75884 Scala Fe Springs.CA 90670
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