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SS9901-SP020523 Earald Environmental, Safety and marvin Transportation Data Sheet f6RZFbflD--' �,:;:-" .i_�.�a� �, �^.`'>'A-°'\'k:�3'�'4'f.w';, ?ror�a�4E "'T.7. �,;,.> • BORE GEL" L PRODUCT IDENTIFICATION SUPPLIER REGULAR TELEPHONE NUMBER 713/987-5900 BAROID DRILLING FLUIDS,INC. EMERGENCY TELEPHONE NO. 713/987-400th ADDRESS P.O.BOX 1675 HOUSTON,TX 77251 TRADE NAME BORE-GEL GENERIC DESCRIPTION FINELY GROUND BENTONITE CAS #1302-78-9 IL HAZARDOUS INGREDIENTS NIATERIAL OR COMPONENT % HAZARD DATA SILICA 14808-60-7 2-6% LOW CONCENTRATIONS OF CRYSTALLINE SILICA(Si02) IN THE FORM OF QUARTZ, CRSTOBALTTE AND TRIDYMITE MAY BE PRESENT (SEE SECTION V) !IL PHYSICAL DATA BOILING POINT(Deg F) NA MUTING POII FREEZING POINT NA SPECIFIC GRAVITY(H20-1) VAPOR PRESSURE(mm H 2.79 NA VAPOR DENSITY(AM- 1) SOLUBILITY IN WATER,%BY WT. NA NA %VOLATILES BY VOLUME EVAPORATION RATE(BUTYL ACETATE- 1) NA APPEARANCE AND ODOR DENSITY @ 20 Deg C(Uncanpacted) TAN TO GREY POWDER,NO ODOR 52.6 LB/FT pH ND NA Not Applicable ND-Not Determined oaf Was ea reoswsdadas ad a gpsdae t+nin m+wdrrp ors pant 1 Ills ptdua All dos grad Corporatism mom my Nobility sisrq from we baud a tees ad data bilged to be Mob's bwso.It It We We the w,4J eMrs,of the product Witold to brio Na is the information narpardbply to debrdm 1M way.toddy,ad suitability fa Yit min use botch is bo mowed as abcdotdy mortise dras Adidas/i faoaticr:may bt of Is product dealbsd bade. S1mo tie acrid we by arbrs Is beyard ws - rwsery r deirde*orbs prtlads a wapSad=dikes a draegitaos mord•no Wratss.'premed a Imorlod Is safe by Barad Capaatim as to oast a beret el-applicable tae or potrauet ru akm- tb Blocs d rri as.In raas to be ebtdmd r tb dety rd mady nr Trademark of Baroid Drilling Fluids,Inc. Barold DteinIog Fluids,Inc. Copyright oBaroid Corporation P.O,Box 1675,Houston,Texas 77251 . BEST Sheet BOB E,-GEL"' Page 2 IV.FIRE AND EXPLOSION DATA WILL NOT SUPPORT COMBUSTION. EXTINGUISHING MEDIA:WATER SPECIAL FIRE FIGHTING PROCEDURES:NONE V.HEALTH HAZARD INFORMATION CARCINOGENICITY- SEE ROUTES OF EXPOSURE AND EFFECTS(BELOW) ACUTE ORAL 11350 ACUTE DERMAL LD50 AQUATIC TOXICITY LC50 ND ND ND ROUTES OF EXPOSURE AND EFFECTS THIS PRODUCT CONTAINS FREE CRYSTALLINE SILICA WHICH ACCORDING TO THE IARC HAS EXHIBITED LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS.PROLONGED INHALATION OF DUST MAY RESULT IN SILICOSIS,A NONCANCEROUS LUNG DISEASE.OSHA FINAL LIMTS TABLE Z-3 MINERAL DUSTS. SILICA:CRYSTALLINE 10 mg/m3 QUARTZ(RESPIRABLE)-- %SiO2+2 30 mg/m3 QUARTZ(TOTAL DUST)— 96 SiO2+2 IF CRISTOBALTTE OR TRIDYMTTE IS DETECTED,USE ONE HALF THE VALUE CALCULATED FROM FORMULAE FOR QUARTZ EMERGENCY AND FIRST AID PROCEDURES RINSE ALL CONTACTED AREAS AFTER USE IF IRRITATION PERSISTS CONTACT PHYSICIAN. BEST Sheet BORE-GELS' Page 3 VL REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY NONE INCOMPATIBILITY NONE HAZARDOUS DECOMPOSITION PRODUCTS NONE CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION NONE VII.SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED VACUUM UP.SALVAGE USABLE MATERIAL CAUSES SLIPPERY SURFACES WHEN WET. NEUTRALIZING CHEMICALS NA WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH ALL LOCAL,STATE AND FEDERAL REGULATIONS. VIII.INDUSTRIAL HYGIENE CONTROL MEASURES VENTILATION REQUIREMENTS MECHANICAL,GENERAL ROOM VENTILATION. USE LOCAL VENTILATION TO MAINTAIN TLV(SEE SECTION V) SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY USE A NIOSH APPROVED MECHANICAL FILTER RESPIRATOR FOR NONTOXIC DUSTS. EYE GOGGLES GLOVES WORK GLOVES OTHER CLOTHING AND EQUIPMENT APRON,EYEWASH STATION • BEST Sheet BORE-GEL"' Page 4 IX.SPECIAL PRECAUTIONS PRECAUTIONARY STATEMENTS AVOID PROLONGED INHALATION. RECOMMENDED LABELING:FRONT PANEL:CAUTION SEE BACK PANEL FOR CAUTION BEFORE USE.BACK PANEL:CAUTION THIS PRODUCT CONTAINS FREE CRYSTALLINE SILICA WHICH ACCORDING TO THE IARC HAS EXHIB- ITED LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS.PROLONGED INHALATION OF THE POWDER MAY RESULT IN SILICOSIS,A NONCANCEROUS LUNG DISEASE.AVOID CREATING DUSTY CONDITIONS AND USE A NIOSH AP- PROVED DUST RESPIRATOR OTHER HANDLING AND STORAGE REQUIREMENTS STORE IN SHELTERED AREA OR COVER FOR MOISTURE PROTECTION. X.DEPARTMENT OF TRANSPORTATION INFORMATION PROPER SHIPPING NAME: PLACARDS: NOT REGULATED AS HAZARDOUS NONE HAZARD CLASS: REPORTABLE QUANTITY: NONE NONE HAZARDOUS SUBSTANCE: ID NUMBER: NONE NONE LABEL: NONE Prepared by DATE Environmental Services February,1995 BEST Sheet BORE-GEL' Page 5 XL REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS Comprehensive Environmental Response,Compensation and Uablrrty Act of 1980,(CERCLA)requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities(RQs)in 40 CFR 302.4. Components present in this product which may require notification are Chemical CAS Number NONE Superfund Amendments and Reauthorization Act of 1986(SARA)Title III requires emergency planning based on Threshold Planning Quantities(TPQs)and release reporting based on RQs. Components present in this product at a level which could require reporting under the statute are NONE SARA requires the submission of annual reports of toxic chemicals that appear in 40 CFR 372(for SARA 313). This information must be included in all MSDS that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: NONE Toxic Substances Control Act(TSCA) The ingredients of this product are on the TSCA inventory. XIL STATE RIGHT TO KNOW NOT ON ANY STATE LISTS. Prepared by: DATE Environmental Services February,1995 Baroid Environmental, Safety and HEALiH ItAACTIVITY Transportation Data Sheet o 0 • CON DET® I. PRODUCT IDENTIFICATION SUPPLIER REGULAR TELEPHONE NUMBER 713/987-5900 BAROID DRILLING FLUIDS,INC. EMERGENCY TELEPHONE NO. 713/987-4000 ADDRESS • P.O.BOX 1675 HOUSTON,TEXAS 77251 TRADE NAME CON DET GENERIC DESCRIPTION MUD DETERGENT H. HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT % HAZARD DATA NONE III.PHYSICAL DATA BOILING POINT(Deg F) MELTING POINT NA FREEZING POINT 212 F ND SPECIFIC GRAVITY(1120 - 1 ) VAPOR PRESSURE(mm Hg) - 1.02 NA VAPOR DENSITY(AIR a 1) SOLUBILITY IN WATER,%BY WT. NA SOLUBLE % VOLATILES BY VOLUME 90 EVAPORATION RATE(BUTYL ACETATE- 1) NA APPEARANCE AND ODOR DENSITY @ 20 Deg C (Uncompacted) LIGHT AMBER LIQUID,SLIGHT ALCOHOL NA pH ND NA - Not Applicable ND -Not Determined All information rucarmhsdati ors ad sultpeatiahs Min conurinp our product of t product nor door Avoid n baud , tats and data Wand to be slid* boyars•,it is dee woes Ct reatim to An ahy Nobility the or horn the u to by ours. of the product Maud to Arnim Nor is th matio may responsibility to dr rmia the sabty. towaty,and suitability for bus wen NM Min to be eastnwd a iWalutaly meets since addtiad information may bu of the gradual daaibs baron. Since Ibe actual use by attest Is beyond our necessary or duiradt stem patiada or*motored eondtias or aramctarat aaurol, no earana, moss* or iahplid,is made by Bared Corporation is to oust a hawse of appliabi.(airs or povamhnt coeditors. the ghats of such use the molts to be obtained.or the safety ad tawdry e Registered Trademark of Baroid Technology,Inc. Baroid Drilling Fluids,Inc. Copyright ©Baroid Corporation P.O.Box 1675,Houston,Texas 77251 BEST Sheet CON DET® Page 2 IV. FIRE AND EXPLOSION DATA CON DET IS NOT FLAMMABLE OR EXPLOSIVE.LOW HAZARD, LIQUID CAN BURN UPON HEATING TO TEMPERATURES AT OR ABOVE THE FLASHPOINT. FLASH POINT: 210 DEG F PMCC. EXTINGUISHING MEDIA:WATER V. HEALTH HAZARD INFORMATION CARCINOGENICITY- NOT NO NTP,IARC OR OSHA LISTS ACUTE ORAL LD50 ACUTE DERMAL LD50 AQUATIC TOXICITY LC50 ND ND 750 PPM ROUTES OF EXPOSURE AND EFFECTS SKIN OR EYE: POSSIBLE IRRITANT. HARMFUL IF INGESTED. EYE CONTACT: IRRITATING BUT DOES NOT INJURE EYE TISSUE. SKIN CONTACT:LOW ORDER OF TOXICITY. IRRITATING INHALATION: NEGLIGIBLE HAZARD AT AMBIENT TEMPERATURE INGESTION: LOW ORDER OF TOXICITY EMERGENCY AND FIRST AID PROCEDURES IF SWALLOWED IN LARGE QUANTITY,INDUCE VOMITING IF PRODUCT HAS NOT ALREADY DONE SO. FLUSH SKIN AND EYES WITH WATER TO AVOID IRRITATION. BEST Sheet CON DET® Page 3 VI.REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY NONE INCOMPATIBILITY NONE HAZARDOUS DECOMPOSITION PRODUCTS ND CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION NONE VII.SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED FLUSH A SMALL SPILL WITH LARGE AMOUNTS OF WATER. FOR A LARGE SPILL PICK UP MATERIAL WITH SAND OR OTHER NONCOMBUSTIBLE ABSORBENT.FLUSH SPILL AREA WITH WATER. NEUTRALIZING CHEMICALS NA WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH LOCAL,STATE,AND FEDERAL REGULATIONS VIII.INDUSTRIAL HYGIENE CONTROL MEASURES VENTILATION REQUIREMENTS NORMAL ROOM VENTILATION. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY NOT NECESSARY EYE NOT NECFS-SARY GLOVES RUBBER GLOVES OTHER CLOTHING AND EQUIPMENT EYEWASH BEST Sheet CON DET® Page 4 IX. SPECIAL PRECAUTIONS PRECAUTIONARY STATEMENTS DO NOT USE,STORE,OR DISPOSE OF CON DET WHERE IT MAY SPILL,LEACH OR RUNOFF INTO WATER WAYS.CON,DET IS MODERATLEY TOXIC TO FISH. OTHER HANDLING AND STORAGE REQUIREMENTS KEEP CONTAINERS CLOSED WHEN NOT IN USE X. DEPARTMENT OF TRANSPORTATION INFORMATION PROPER SHIPPING NAME: PLACARDS : NOT REGULATED NONE HAZARD CLASS : REPORTABLE QUANTITY: NOT HAZARDOUS NONE HAZARDOUS SUBSTANCE: ID NUMBER : NONE NONE LABEL: NONE REQUIRED Prepared by: DATE: Environmental Services October,1992 BEST Sheet CON DET® Page S XI. REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS Comprehensive'Environmental Response,Compensation and Liability Act of 1980,(CERCLA) requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities(RQs)in 40 CFR 302.4. Components present in this product which may require notification are: Chemical CAS Number NONE Superfund Amendments and Reauthorization Act of 1986(SARA)Title III requires emergency planning based on Threshold Planning Quantities (TPQs)and release reporting based on RQs. Components present in this product at a level which could require reporting under the statute are: NONE SARA requires the submission of annual reports of toxic chemicals that appear in 40 CFR 372 (for SARA 313). This information must be included in all MSDS that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: NONE Toxic Substances Control Act(TSCA) The ingredients of this product are on the TSCA inventory. XL. STATE RIGHT TO KNOW NOT ON ANY LISTS. Prepared by: DATE: Environmental Services October,1992 FIRE Baroid Environmental, Safety and HEALTH MO Transportation Data Sheet 0 HA7AA) QUIK-TROL® I. PRODUCT IDENTIFICATION SUPPLIER REGULAR TELEPHONE NUMBER 713/987-5900 HAROLD DRILLING FLUIDS,INC. EMERGENCY TELEPHONE NO. 713/987-4000 ADDRESS P.O.BOX 1675 HOUSTON,TX 77251 TRADE NAME QUIK-TROL GENERIC DESCRIPTION ORGANIC POLYMER II.HAZARDOUS INGREDIENTS • MATERIAL OR COMPONENT 96 HAZARD DATA NONE • • III. PHYSICAL DATA BOILING POINT(Deg F) NA MELTING POINT FREEZING POINT NA SPECIFIC GRAVITY (H20= 1 ) VAPOR PRESSURE(mm Hg) • 1.6 NA VAPOR DENSITY(AIR= 1) SOLUBILITY IN WATER,%BY WT. NA 100 . %VOLATILES BY VOLUME EVAPORATION RATE(BUTYL ACETATE• 1) NA' APPEARANCE AND ODOR DENSITY @ 20 Deg C(Uncompacted) GRANULAR LIGHT POWDER,ODORLESS ND PH ND NA -Not Applicable ND -Not Determined Ali idauetian neamrWtias ad suppstism rosin e vr0 or product or too product nor dos Barad Corporation alum ay liability mashy horn se baud on acts ad data bdisnd to he reliable,b omen it is the oars the use,by atisrs,at the product Bland to Wen. Na is the hdeasUm responsibility to delanins the safety. taidty,ad salability for as am use heroin to be auseusd a*scat*carpets dna*Masi Msssdm sly be at the product dsaibed basin Since the actwl au by otters is beyond our man-y a didrabie sad portiada a segtiord e-Hers a Bra metans antrd,no puaatst apeasd a*Ii* is'mde by laid Corporation as to oast re because d Waldo Ian re pooarserd rapdaoieer. the effects of adt us& the radts to be sbtInsd. or the eddy ad teddy e Registered Trademark of Baroid Technology,Inc. Baroid Drilling Fluids,Inc. Copyright oBaroid Corporation P.O.Box 1675,Houston,Texas 77251 • • BEST Sheet QUIK-TROL® Page 2 IV.FIRE AND EXPLOSION DATA FLASH POINT: NONE EXTINGUISHING MEDIA;WATER,FOAM OR DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES: WEAR FULL PROTECTIVE EUQIPMENT INCLUDING SELF CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS;TREAT AS A FLAMMABLE DUST IN THE FINELY DIVIDED AND SUSPENDED STATE.(0.15 OZ/FT3). INCOMPLETE THERMAL DECOMPOSITION MAY PRODUCE TOXIC GASES. V.HEALTH HAZARD INFORMATION CARCINOGENICITY- NOT ON NTP,IARC OR OSHA LISTS ACUTE ORAL LD50 ACUTE DERMAL LD50 AQUATIC TOXICITY LC50 ND ND ND ROUTES OF EXPOSURE AND EFFECTS INERT OR NUISANCE PARTICLE NUISANCE DUST TLV— 10 MG/M3 EYES:MAY CAUSE IRRITATION OR REDNESS SKIN:MAY CUASE IRRITATION • EMERGENCY AND FIRST AID PROCEDURES TREAT DUST PARTICLES IN EYE AS ANY OTHER FOREIGN BODY BY WASHING WITH RUNNING WATER. NO EMERGENCY PROCEDURES NECESSARY IN OTHER FORMS OF CONTACT. BEST Sheet QUIK-TROL® Page 3 VI.REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY NONE INCOMPATIBILITY NONE HAZARDOUS DECOMPOSITION PRODUCTS CARBON DIOXIDE,CARBON MONOXIDE CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION WILL NOT OCCUR VII.SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED SWEEP UP MATERIAL AND DISPOSE OF IN ACCORDANCE WITH ALL LOCAL,STATE AND FEDERAL REGULATIONS. NEUTRALIZING CHEMICALS NA WASTE DISPOSAL METHOD NONFERMENTING MATERIAL. DISPOSE OF IN DESIGNATED LAND FILL.DISPOSE OF IN ACCOR- DANCE WITH ALL LOCAL,STATE AND FEDERAL REGUALTIONS. VIII. INDUSTRIAL HYGIENE CONTROL MEASURES VENTILATION REQUIREMENTS GENERAL VENTILATION SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY USE A NIOSH APPROVED RESPIRATOR FOR NONTOXIC DUSTS EYE GOGGLES GLOVES GENERAL PURPOSE WORK GLOVES OTHER CLOTHING AND EQUIPMENT EYEWASH T BEST Sheet QUIK-TROL® Page 4 IX. SPECIAL PRECAUTIONS PRECAUTIONARY STATEMENTS DO NOT USE,STORE,OR DISPOSE OF QUIK-TROL WHERE IT MAY LEACH, SPILL OR RUN OFF INTO WATERWAYS.IT IS MODERATELY TOXIC TO AQUATIC SPECIES. USE WITH ADEQUATE VENTILATION. DO NOT USE NEAR SPARKS OR OPEN FLAME. OTHER HANDLING AND STORAGE REQUIREMENTS TO PROTECT QUALITY,STORE IN SEALED CONTAINERS IN A DRY COOL PLACE AWAY FROM SUNLIGHT. STORE AWAY FROM MOISTURE. X.DEPARTMENT OF TRANSPORTATION INFORMATION PROPER SHIPPING NAME: PLACARDS: NOT REGULATED NONE HAZARD CLASS: REPORTABLE QUANTITY: NOT HAZARDOUS NONE HAZARDOUS SUBSTANCE: ID NUMBER: NONE NONE LABEL: NONE Prepared by: DATE: Environmental Services December,1991 11. _ f T BEST Sheet QUIK TROL® Page 5 XI.REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS Comprehensive Environmental Response,Compensation and Liability Act of 1980,(CERCLA)requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities(RQs)in 40 CFR 302.4. Components present in this product which may require notification are: Chemical CAS Number NONE Superfund Amendments and Reauthorization Act of 1986(SARA)Title III requires emergency planning based on Threshold Planning Quantities(TPQs)and release reporting based on RQs. Components present in this product at a level which could require reporting under the statute are: NONE SARA requires the submission of annual reports of toxic chemicals that appear in 40 CFR 372(for SARA 313). This information must be included in all MSDS that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: NONE Toxic Substances Control Act(TSCA) The ingredients of this product are on the TSCA inventory. III. STATE RIGHT TO KNOW NOT ON ANY LISTS. Prepared by: DATE: Environmental Services Derember,1991 fIRE Baroid Environmental, Safety and HEALTH REACTIVITY Transportation Data Sheet 2 v. 0 HAZARD EZ MUD® • I. PRODUCT IDENTIFICATION SUPPLIER REGULAR TELEPHONE NUMBER 713/987-5900 BAROID DRILLING FLUIDS,INC. EMERGENCY TELEPHONE NO. 713/987-4000 ADDRESS P.O.BOX 1675 HOUSTON,TEXAS 77251 TRADE NAME EZ MUD GENERIC DESCRIPTION PARTIALLY HYDROLYZED POLYACRYLAMII)E H. HAZARDOUS INGREDIENTS MATERIAL OR COMPONENT % HAZARD DATA PETROLEUM DISTILLATE HYDRO- '0-40 400 PPM OSHA TREATED LIGHT 64742-47-8 M. PHYSICAL DATA BOILING POINT(Deg F) MELTING POINT NA FREEZING POINT ND >200 F SPECIFIC GRAVITY(H20= 1 ) VAPOR PRESSURE(mm Hg) 1.0 NA VAPOR DENSITY(AIR- 1) SOLUBILITY IN WATER,%BY WT. ND APPRECIABL %VOLATILE.S BY VOLUME EVAPORATION RATE(BUTYL ACETATE- 1) <1 APPEARANCE AND ODOR DENSITY @ 20 Deg C (Uncompacted) CREAM COLORED LIQUID,SLIGHT ODOR pH NA NA- Not Applicable ND -Not Determined All i daaaem aaawwameas and Mpltseas es an ceasaro at abduct of On/mutt mar does land Caoaaeon AMMO any liability Ridp Iran an Mad on tats ad Ina Wald to M n iVit..ioraw. It is M two the ass.M'Ours. al 1 e paiact Mead to Win Ms N Mm ildonrom ragnMOiliy to lowing as slay,toddy,am sitdiiy Nr Vs am as Ann to be oatsaaod s aasdatay owpaa boa tliiad Ndan seen may M a Ira induct daaiMd twin. Since ea sad ea by saws is Myad as ataony a&male Wan p$asa a assure.M aadaas a aaaastaos casts/.ro pwane*aped a maid.N maim by laid CaEaaeat a to ant or Maws a sppiceno lin a poatawM tapaeas. MS alas a aadt vac Me tars to be*Maloof. or Yes tasty AN Welty e Registered Trademark of Baroid Technology,Inc. Baroid Drilling Fluids,Inc. Copyright oBaroid Corporation P.O.Box 1675,Houston,Texas 77251 BEST Sheet EZ MUD® Page 2 1V. FIRE AND EXPLOSION DATA FLASH POINT:>200 DEG.F(PENSKY-MARTENS) FIRE EXTINGUISHING MEDIA: USE WATER SPRAY,CARBON DIOXIDE OR DRY CHEMICAL TO EXTINGUISH FIRES.USE WATER TO KEEP CONTAINERS COOL. SPECIAL FIREFIGHTING PROCEDURES:WEAR SELF CONTAINED,POSITIVE PRESSURE BREATHING APPARATUS AND FULL FIRE-FIGHTING PROTECTIVE CLOTHING. UNUSUAL FIRE AND EXPLOSION HAZARD:NONE STATED V. HEALTH HAZARD INFORMATION CARCINOGENICITY- NOT ON NTP,IARC OR OSHA LISTS ACUTE ORAL LD50 ACUTE DERMAL LD50 AQUATIC TOXICITY LC50 RAT>10mg/k ND ND ROUTES OF EXPOSURE AND EFFECTS EYE:MAY CAUSE IRRITATION. SKIN:ON DIRECT SKIN CONTACT,MAY PRODUCE A SEVERE SKIN IRRITATION INGESTION: INGESTION OF LARGE AMOUNTS MAY CAUSE INJURY. INHALATION: PROLONGED REPEATED EXPOSURE TO VAPOR MAY CAUSE CENTRAL NERVOUS SYSTEM DAMAGE AS WELL AS HEART AND BLOOD DISORDERS.ASPIRATION MAY CAUSE CHEMICAL PNEUMONITIS. OVEREXPOSURE TO VAPOR MAY CAUSE DIZZINESS, DROWSINESS,HEADACHE,AND NAUSEA. EMERGENCY AND FIRST AID PROCEDURES EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP AND WATER AFTER USE. LAUNDER CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AIR IF AFFECTED.CONSULT A PHYSICIAN. BEST Sheet EZ MUD® Page 3 VI. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY — NONE INCOMPATIBILITY STRONG OXIDIZERS. MATERIAL REACTS SLOWLY WITH IRON,COPPER&ALUMINUM HAZARDOUS DECOMPOSITION PRODUCTS THERMAL DECOMP.MAY PRODUCE CARBON MONOXIDE,AMMONIA&OXIDES OF NITROGEN CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION WILL NOT OCCUR VII.SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED CONTAIN SPILL WITH ABSORBENT MATERIAL PLACE IN CONTAINER FOR DISPOSAL FINAL CLEANUP WITH WATER UNTIL SLIPPERY CONDITION IS ELIMINATED. NEUTRALIZING CHEMICALS NONE ARE REQUIRED WASTE DISPOSAL METHOD DISPOSE OF IN ACCORDANCE WITH ALL LOCAL,STATE,AND FEDERAL REGULATIONS VIII. INDUSTRIAL HYGIENE CONTROL MEASURES VENTILATION REQUIREMENTS WHERE THIS MATERIAL IS NOT USED IN A CLOSED SYSTEM,GOOD ENCLOSURE AND LOCAL EXHAUST VENTILATION SHOULD BE PROVIDED TO CONTROL EXPOSURE. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY WHERE EXPOSURE IS BELOW PEL,NO RESPIRATORY PROTECTION REQUIRED. EYE CHEMICAL SPLASH PROOF GOGGLES. GLOVES CHEMICAL RESISTANT GLOVES OTHER CLOTHING AND EQUIPMENT APRON,LONG SLEEVE SHIRT BEST Sheet EZ MUD® Page 4 IX-SPECIAL PRECAUTIONS PRECAUTIONARY STATEMENTS AVOID SKIN AND EYE CONTACT. IF SPILLED MAY CAUSE SLIPPERY FLOOR CONDITIONS. OTHER HANDLING AND STORAGE REQUIREMENTS TO AVOID PRODUCT DEGRADATION AND EQUIPMENT CORROSION,DO NOT USE IRON,COPPER OR ALUMINUM CONTAINERS OR EQUIPMENT. X. DEPARTMENT OF TRANSPORTATION INFORMATION PROPER SHIPPING NAME: PLACARDS: NOT REGULATED NONE HAZARD CLASS: REPORTABLE QUANTITY: NOT APPLICABLE NA HAZARDOUS SUBSTANCE: ID NUMBER : NOT APPLICABLE NOT APPLICABLE LABEL: NOT APPLICABLE Prepared by: DATE: EnvirOAmental Services October,1992 BEST Sheet EZ MUD® Page 5 XI. REGULATORY INFORMATION STATUS ON SUBSTANCE LISTS Comprehensive Environmental Response,Compensation and Liability Act of 1980,(CERCLA)requires notification of the National Response Center of release of quantities of Hazardous Substances equal to or greater than the reportable quantities(RQs)in 40 CFR 302.4. Components present in this product which may require notification are: Chemical CAS Number NONE Superfund Amendments and Reauthorization Act of 1986(SARA)Title III requires emergency planning based on Threshold Planning Quantities(TPQs)and release reporting based on RQs. Components present in this product at a level which could require reporting under the statute are: NONE SARA requires the submission of annual reports of toxic chemicals that appear in 40 CFR 372(for SARA 313). This information must be included in all MSDS that are copied and distributed for this material. Components present in this product at a level which could require reporting under the statute are: NONE Toxic Substances Control Act(TSCA) The ingredients of this product are on the TSCA inventory. M. STATE RIGHT TO KNOW NOT ON ANY LLSTS. Prepared by: DATE: Environmental Services October,1992