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Submittal
Submittal Index 1 . Section 04 01 20.52 Cleaning Products 10 Pages 2. Section 04 01 20.91 Masonry Restoration Brick 4 Sheets (3 front and back) 3. Section 04 05 20.91 Masonry Mortars 14 Pages 4. Section 04 05 23 Masonry Accessories Anchors 5 Pages 5. Section 04 05 23 Flashing 3 Sheets (1 front and back) 6. Section 04 05 23 Steel Lintels 22 Pages 7. Section 07 19 19 Masonry Water Repellents 18 Pages 8. Section 07 92 13 Joint Sealants 38 Pages 9. Section 09 91 00 10. Steel Lintel Paint 9 Pages PROSOCO Enviro Kleanp NEXT GENERATION CLEANERS 2010 All Surfcice Cleaner Enviro Klean®2010 All Surface Cleaner is a next- REGULATORY COMPLIANCE generation product for cleaning and degreasing light-to-heavily soiled stone, tile, masonry and VOC Compliance much more. Powerful enough for industrial use, Enviro Klean® 2010 All Surface Cleaner is flexible enough for jobs around the home, space- compliant with all national, state and district VOC saving EK 2010 replaces a host of individual regulations. cleaning agents. It's concentrated for the toughest industrial cleaning jobs on concrete, metal and TYPICAL TECHNICAL DAT many other plant and warehouse surfaces. It's dilutable for home-use on windows,bathroom tub ( Clear, green liquid FORM and tile, counter tops and more. Fresh odor _ Easy-to-use EK 2010 All Surface Cleaner is water- SPECIFIC GRAVITY 1.070 rinsable and contains no harsh acids, caustics 10.5 or solvents. EK 2010 also removes Sure Klean® pH 7.8-8.2 Typical Rinse water Weather Seal Siloxane PD over spray from windows. WT/GAL 8.90 lbs ACTIVE CONTENT not applicable • Cleans and degreases light-to-heavily soiled stone, TOTAL SOLIDS not applicable tile, masonry and much more. VOC CONTENT not applicable • Effectively removes moderate biological staining. >200°F(>93° C) •Dilutable for jobs around the home. FLASH POINT ASTM D 3278 • Replaces a host of individual cleaning agents. FREF9E POINT 32°F(0°C) • Effective cleaner for windows,bathroom tub and SHELF LIFE 3 years in tightly sealed, tile,counter tops and more. unopened container • Easy-to-use and water-rinsable. • Contains no harsh acids, caustics or solvents. SAFETY INFORMATION Limitation Always read full label and SDS for precautionary • Repeated use may dull polished carbonate instructions before use. Use appropriate safety surfaces, including but not limited to limestone, equipment and job site controls during application marble and travertine. and handling. 24-Hour Emergency Information: SUBMITTAL REVIEW INFOTRAC at 800-535-5053 REVIEWED REVISE AND RESUBMIT 0 FURNISH tS CORRECTED REJECTED ❑ SubLata,Review is for general conformance with the specifications and contract documents Notes or markings shall not be construed as relieving the contractor from compliance with project plans and sr'eut canons Contractor shall be solely responsible for all (let:is ysantities,dimensions,fabrication,technique of assembly, v orluranshtp,and safety requirements �� ! 444 N Associates, _ Product Data Sheet•Page 1 of 3 •Item#41065— 102015 •©2015 PROSOCO,Inc. •www.prosoco.com Product Data Sheet Enviro Klean° 2010 All Surface Cleaner %Nir PREPARAL Equipment Protect people, vehicles,property, plants and all Apply with low-pressure sprayer,brush or heavy surfaces not set for cleaning from the product, nap roller. Scrub heavily soiled surfaces with a splash, rinse, residue, fumes and wind drift. Test all nonabrasive brush or synthetic scrubbing pad. surfaces that may come in contact for compatibility. Rinse with enough water and pressure to flush Immediately rinse non target materials with large spent cleaner and dissolved soiling from the quantities of water. Grass and plantings may be masonry surface and surface pores without protected with sprinklers. damage. Masonry-washing equipment generating Divert pedestrian and auto traffic if necessary. 400-1000 psi with a water flow rate of 6-8 gpm is Clean when traffic is at a minimum. the best water/pressure combination for rinsing porous masonry. Use a 15-45°fan spray tip. Heated r—(1ce and Ai'Temperatr` water (150-180°F; 65-82°C)may improve cleaning Best air and surface temperatures for cleaning are efficiency. 50°F(10°C)or above. Cleaning when temperatures Use adjustable equipment for reducing water flow are below freezing or will be overnight may rates and rinsing pressure for sensitive surfaces. harm masonry. If freezing conditions exist before Rinsing pressures greater than 1000 psi and fan application, let masonry thaw. spray tips smaller than 15°may permanently damage sensitive masonry. Water flow rates less than 6 gpm may reduce cleaning productivity and contribute to uneven cleaning results. Recommended for these substrates. Always test. Storage and Handling Coverage is in sq.ft./m.per gallon of concentrate. Store in a cool, dry place. Always seal container Substrate Type Use? . Coverage after dispensing. Do not alter or mix with other Burnished yes chemicals. Published shelf life assumes upright Architectural Smooth yes 50-150 sq.ft. storage of factory-sealed containers in a dry place. ConcrBlocked Split faced yes 5-14 sq.m. Maintain temperature of 45-100°F(7-38°C). If Ribbed yes product freezes, allow to thaw and mix well. Do not double stack pallets. Dispose of in accordance with Brick yes local, state and federal regulations. Tile yes Concrete Precast Panels yes 50-150 sq.ft. Pavers yes 5-14 sq.m. APPLICATION Cast-in-place yes Read"Preparation"and the Safety Data Sheet before Brick yes use. Fired Clay Tile yes 150-500 sq.ft. ALWAYS TEST a small area of'each surface to Terra Cotta(unglazed) yes 14-46 sq.m. confirm suitability,coverage rate and desired Pavers yes results before beginning overall application. Test Polished yes 500-1000 sq.ft. with the same equipment, recommended surface Marble, 46-93 sq.m. preparation and application procedures planned Travertine, Limestone Unpolished yes 150-500 sq.ft. for general application. Let surface dry thoroughly 14-46 sq.m. before inspection. Polished yes 500-1000 sq.ft. Dilution&Mixing Granite 46-93 sq.m. Use in concentrate to remove heavy soiling. When Unpolished yes used sq.ft. used as a light-duty cleaner, dilute up to 1 part 14-46 sq.m. cleaner to 10 parts clean water. Sandstone Unpolished yes 150-500 sq.ft. 14-46 sq.m. 150-500 sq.ft. Slate Unpolished yes 14-46 sq.m. Always test to ensure desired results. Coverage estimates depend on surface texture and porosity. Product Data Sheet•Page 2 of 3 • Item#41065- 102015 • ©2015 PROSOC O,Inc. •www.prosoco.com Product Data Sheet Enviro Klean® 2010 All Surface Cleaner ® Application Instructions PROSOCO, Inc. warrants this product to be free 1. Working from the bottom to the top,prewet the from defects. Where permitted by law,PROSOCO surface with clean water. makes no other warranties with respect to 2. Apply the appropriately diluted solution to the this product,express or implied, including masonry surface using a brush or low-pressure without limitation the implied warranties of merchantability or fitness for particular purpose. spray. The purchaser shall be responsible to make his own 3. Let the cleaner stay on the surface 1-10 minutes, tests to determine the suitability of this product for based on testing. Gently scrub heavily soiled his particular purpose. PROSOCO's liability shall be areas. NOTE: Do not let EK 2010 dry on the limited in all events to supplying sufficient product surface. If drying occurs, lightly wet surfaces to re-treat the specific areas to which defective with fresh water and reapply the cleaner in a product has been applied. Acceptance and use of gentle scrubbing manner. this product absolves PROSOCO from any other 4. Working from the bottom to the top, rinse the ! liability, from whatever source, including liability surface thoroughly with clean water. for incidental, consequential or resultant damages 5. Repeat steps 1 through 4 if necessary. whether due to breach of warranty, negligence or Cleanup strict liability. This warranty may not be modified or extended by representatives of PROSOCO, its Clean tools and equipment using fresh water. distributors or dealers. RRANTY CUSTOMER CARE The information and recommendations made are Factory personnel are available for product, based on our own research and the research of environment and job-safety assistance with no others, and are believed to be accurate. However, obligation. Call 800-255-4255 and ask for Customer no guarantee of their accuracy is made because Care-technical support. we cannot cover every possible application of our products, nor anticipate every variation Factory-trained representatives are established in encountered in masonry surfaces,job conditions principal cities throughout the continental United and methods used. The purchasers shall make States. Call Customer Care at 800-255-4255, or visit their own tests to determine the suitability of such our web site at www.prosoco.com, for the name of products for a particular purpose. the PROSOCO representative in your area. Pc'ST PRACTICE Do not let EK 2010 dry on the surface. If drying occurs, lightly wet surfaces with fresh water and Apply with low-pressure sprayer,brush or heavy reapply the cleaner in a gentle scrubbing manner. nap roller. Scrub heavily soiled surfaces with a Repeated use may dull polished carbonate nonabrasive brush or synthetic scrubbing pad. surfaces, including but not limited to limestone, Rinse with enough water and pressure to flush marble and travertine. spent cleaner and dissolved soiling from the Never go it alone. If you have problems or masonry surface and surface pores without questions, contact your local PROSOCO damage. Masonry-washing equipment generating distributor or field representative. Or call 400-1000 psi with a water flow rate of 6-8 gpm is PROSOCO technical Customer Care, toll-free,at the best water/pressure combination for rinsing 800-255-4255. porous masonry. Use a 15-45°fan spray tip. Heated water may improve cleaning efficiency. C Product Data Sheet•Page 3 of 3 •Item #41065- 102015 • ©2015 PROSOCO,Inc. •www.prosoco.com -t Enviro Klean® 2010 All Surface Cleaner Cleaning Specification Specifier Note: The information provided below is intended to guide the Architect in developing specifications for products manufactured by PROSOCO, Inc. and should not be viewed as a complete source of information about the product(s). The Architect should always refer to the Product Data Sheet and MSDS for additional recommendations and for safety information Specifier Note: Paragraph below is for PART 1 GENERAL, Quality Assurance. Test Area Test a minimum 4 ft. by 4 ft. area on each type of masonry. Use manufacturer's application instructions. Let the test panel dry 3 to 7 days before inspection. Keep test panels available for comparison throughout the cleaning project. Specifier Note: Paragraphs below are for PART 2 PRODUCTS, Manufacturers and Products. Manufacturer: PROSOCO, Inc., 3741 Greenway Circle, Lawrence, KS 66046. Phone: (800)255- 4255; Fax: (785)830-9797. E-mail: CustomerCare@prosoco.com Product Description Enviro Klean®2010 All Surface Cleaner is a mildly alkaline product for cleaning and degreasing light-to-heavily soiled stone, tile, and masonry. It contains no harsh acids, caustics or solvents. It's concentrated for the toughest industrial cleaning jobs on concrete, metal and many other plant and warehouse surfaces but dilutable for home-use on windows, bathroom tub and tile, countertops and more. Technical Data FORM: Clear Green liquid TOTAL SOLIDS: N/A SPECIFIC GRAVITY: 1.070 pH: 10.5 Typical Rinse water 7.8- 8.2 WT./GAL.: 8.90 lbs. FLASH POINT: >200 degrees F (> 93 degrees C)ASTM D 3278 FREEZE POINT: 32 degrees F(0 degrees C) Limitation • Repeated use may dull polished carbonate surfaces, including but not limited to limestone, marble and travertine. Specifier Note: Paragraphs below are for PART 3 EXECUTION, Installation. Application Before applying, read"Preparation"and"Safety Information"sections in the Manufacturer's Product Data Sheet for 2010 All Surface Cleaner. Use in concentrate or dilute 2010 All Surface Cleaner concentrate with 1-10 parts water. Refer to Product Data Sheet for recommended dilution for intended use. 1. Working from bottom to top, prewet the surface with clean water. 2. Apply the diluted cleaning solution to the masonry surface using a brush or low- pressure spray. 3. Let the cleaner stay on the surface 1-10 minutes, based on testing. Gently scrub heavily soiled areas. 4. Working from bottom to top, rinse the surface thoroughly with clean water. The best combination of rinsing pressure and water volume is provided by masonry washing equipment generating 400-1000 psi with a water flow rate of 6-8 gallons per minute delivered through a 15-45 degree fan spray tip. Equipment should be adjustable to reduce water flow rate and rinsing pressure as required for controlled cleaning of more sensitive surfaces. See also"Equipment" section of the Product Data Sheet. 5. Repeat steps 1 through 4 if necessary. Note: Do not let cleaning solution dry on the surface. If drying occurs, lightly wet surfaces with fresh water and reapply the cleaner in a gentle scrubbing manner. SAFETY DATA SHEET PROSOCO, Inc. PROSOCO Issue Date 18-Nov-2014 Revision Date 17-Jul-2015 Version 1.01 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Enviro Klean®2010 All Surface Cleaner Other means of identification Product Code 41065 Recommended use of the chemical and restrictions on use Recommended Use Restricted to professional users. Uses advised against No information available Details of the supplier of the safety data sheet Manufacturer Address PROSOCO, Inc. 3741 Greenway Circle Lawrence, Kansas 66046 Emergency telephone number 8:00 AM—5:00 PM CST Monday-Friday 785-865-4200 NON-BUSINESS HOURS(INFOTRAC) 800-535-5053 2. HAZARDS IDENTIFICATION Classification Not a dangerous substance or mixture according to the Globally Harmonized System(GHS) Label elements Emergency Overview The product contains no substances which at their given concentration,are considered to be hazardous to health Appearance clear Physical state Liquid Odor Fresh Hazards not otherwise classified(HNOC) Other Information No information available 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight% Trade Secret Water 7732-18-5 60- 100 * Chelating Agent Proprietary 3-7 Poly(oxy-1,2-ethanediyl), a-undecyl-w-hydroxy- 34398-01-1 1 -5 * B-alanine, N-2-carboxyethyl-N-(3-decyloxyl)propyl)- 64972-19-6 1 -5 Page 1 /6 41065 Enviro Klean®2010 All Surface Cleaner Revision Date 17-Jul-2015 monosodium salt *The exact percentage(concentration)of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General advice If symptoms persist, call a physician. Eye contact Immediately flush with plenty of water.After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Keep eye wide open while rinsing. If symptoms persist, call a physician. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes.Wash contaminated clothing before reuse. If skin irritation persists, call a physician. Inhalation Move to fresh air in case of accidental inhalation of vapors or decomposition products. If breathing is difficult, give oxygen. If symptoms persist, call a physician. Ingestion Do NOT induce vomiting. Rinse mouth. Drink plenty of water. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Most important symptoms and effects,both acute and delayed Symptoms May cause eye irritation. May cause skin irritation. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical Keep away from heat. Protective equipment and precautions for firefighters As in any fire,wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent)and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions,protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Ensure adequate ventilation,especially in confined areas. Slippery when spilled. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Page 2/6 41065 Enviro Klean®2010 All Surface Cleaner Revision Date 17-Jul-2015 Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal. Methods for cleaning up Dam up.Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protective equipment as required. Do not breathe dust/fume/gas/mist/vapors/spray. Use with local exhaust ventilation. Conditions for safe storage,including any incompatibilities Storage Conditions Keep containers tightly closed in a cool,well-ventilated place. Keep away from heat. Keep in properly labeled containers. Incompatible materials Strong acids. Strong oxidizing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product,as supplied,does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls Engineering Controls None under normal use conditions. Individual protection measures,such as personal protective equipment Eye/face protection Wear safety glasses with side shields(or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Wash contaminated clothing before reuse.When using do not eat,drink or smoke. Regular cleaning of equipment,work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance clear Odor Fresh Color green Odor threshold No information available Property Values Remarks •Method pH 10.5 Melting point/freezing point 0 °C / 32 °F Boiling point/boiling range No information available Flash point > 100 °C / > 212 °F ASTM D 3278 Page 3/6 41065 Enviro Klean®2010 All Surface Cleaner Revision Date 17-Jul-2015 Evaporation rate No information available Flammability(solid,gas) No information available Flammability Limits in Air Upper flammability limits No information available Lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 1.07 Water solubility completely soluble Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat. Incompatible materials Strong acids. Strong oxidizing agents. Hazardous Decomposition Products Carbon monoxide. Unidentified organic compounds. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Avoid contact with skin,eyes and inhalation of vapors Inhalation Avoid breathing vapors or mists. Eye contact Avoid contact with eyes. May cause irritation. Skin Contact Avoid contact with skin. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Do not taste or swallow. Component Information Chemical Name Oral LD50 _ Dermal LD50 Inhalation LC50 Water >90 mUkg (Rat) 7732-18-5 Information on toxicological effects Symptoms See Section 11:TOXICOLOGICAL INFORMATION. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization May cause sensitization by skin contact. Page 4/6 41065 Enviro Klean®2010 All Surface Cleaner Revision Date 17-Jul-2015 Germ cell mutagenicity No information available. Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Reproductive toxicity No information available. STOT-single exposure No information available. STOT-repeated exposure No information available. Aspiration hazard No information available. Numerical measures of toxicity -Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix(oral) 26664 mg/kg mg/I 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT Not Regulated for all modes of transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSUNDSL Complies Legend: TSCA-United States Toxic Substances Control Act Section 8(b)Inventory Page 5/6 41065 Enviro Klean®2010 All Surface Cleaner Revision Date 17-Jul-2015 DSUNDSL-Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986(SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA(Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act(40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied,does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act(CERCLA)(40 CFR 302)or the Superfund Amendments and Reauthorization Act(SARA)(40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S.State Right-to-Know Regulations 16. OTHER INFORMATION NFPA Health hazards 1 Flammability 0 Instability 0 Physical and Chemical Properties - HMIS Health hazards 1 Flammability 0 Physical hazards 0 Personal protection X Prepared By Regulatory Department Issue Date 18-Nov-2014 Revision Date 17-Jul-2015 Revision Note SDS sections updated 6 16 Disclaimer The information contained on the Material Safety Data Sheet has been compiled from data considered accurate.This data is believed to be reliable,but it must be pointed out that values for certain properties are known to vary from source to source.PROSOCO,Inc.expressly disclaims any warranty express or implied as well as any liability for any injury or loss arising from the use of this information or the materials described.This data is not to be construed as absolutely complete since additional data may be desirable when particular conditions or circumstances exist.It is the responsibility of the user to determine the best precautions necessary for the safe handling and use of this product for his unique application.This data relates only to the specific material designated and is not to be used in combination with any other material.Many federal and state regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material.It is the purchaser's responsibility to familiarize himself with all applicable regulations. End of Safety Data Sheet Page 6/6 44,1}ftl� ,r r.„ .r.. ACME BRICK COMPANY ' :A..-:. A Berkshire Hathaway company (, ., September 21, 2016 Kemco Inc 2420 Glenda Lane Dallas, TX 75229 Re: City of Coppell Building Coppell, TX Dear Sir, The Face Brick to be used on the referenced job is DTP blend 155 Village and PEP blend 160 Steele Gray. This brick meets ASTM C216 Type FBS Grade SW specifications. Thank you for considering Acme Brick on this project and I look forward to working with you in the future. Sincerely Yours, c raiBurks REVIEWED SUBMITTAL REVIEW FURNISH AS CORD 4 REVISE AND RESUBMIT o br2ittaicon Eeview u for Datil confRElEC�p°rrnalIce with the ❑ Acme Brick Company ios rejleZt� �Nforr not � r 9wofs Contractor atm be solely rpe withm l�ab't�Plans and for � technique or assemblyil, CtS �,,. at�I� . /bilk ACME BRICK 0 801 Airport Freeway—Euless,TX 76040—Tel:817/685-9641 din-if MI/ ACME BRtCK ' BrickSafety Data Sheet According To Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules And Regulations brick.c o m Revision Date:06/03/2015 Date of issue: 06/03/2015 Version:1.0 SECTION 1: IDENTIFICATION 1.1. Product Identifier Product Form:Article Product Name:Brick 1.2. Intended Use of the Product Use of the substance/mixture: Building material used for structural support. 1.3. Name,Address,and Telephone of the Responsible Party Acme Brick Company 3024 Acme Brick Plaza Fort Worth,TX 76109 Corporate Office:(817)332-4101 1.4. Emergency Telephone Number Emergency Number (817)870-8348 Safety&Industrial Hygienist: (817)870-8374 SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the Substance or Mixture Classification(GHS-US) Not classified OSHA Regulatory status:This product is considered an 'article' under 29 CFR Part 1910.1200. Under normal conditions of use, users of the product cannot be exposed to its contents. If the article is damaged and/or material is released,contents are not harmful. For informational purposes,this product would have the following OSHA classification; Acute Health Hazard Chronic Health Hazard 2.3. Other Hazards Excessive dust exposure may aggravate any existing respiratory disorders or diseases. Possible complications or allergies resulting in irritation to skin,eyes,and respiratory tract may occur from excessive exposure to dusts. Brick dust may contain crystalline silica,a chemical that has been determined by certain agencies to cause cancer.See Section 11 for more information on health hazards. 2.4. Unknown Acute Toxicity(GHS-US) No data available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substance Not applicable 3.2. Mixture* Name Product Identifier % Classification(GHS-US) Aluminum Silicates (CAS No)Proprietary 50-85 Not classified Quartz (CAS No)14808-60-7 15-40 Carc. 1A,H350 STOT SE 3, H335 STOT RE 1,H372 Chromium compounds (CAS No)Proprietary 0-3 Not classified Manganese compounds (CAS No) Proprietary 0-3 Not classified Calcium compounds (CAS No)Proprietary 0-3 Not classified Iron Compounds as granular body additives (CAS No)Proprietary 0-3 Not classified *Elements such as aluminum,arsenic,boron,calcium,chromium,cobalt,copper,lead,molybdenum,nickel,tin,titanium, vanadium,and zirconium may be present in trace amounts. Brick products as shipped do not present an exposure hazard. ..,, Full text of H-phrases:see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of First Aid Measures First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell,seek medical advice (show the label where possible). Safety Data Sheet According to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations First-aid Measures After Inhalation: When symptoms occur:go into open air and ventilate suspected area.If exposed or concerned:Get medical advice/attention.Remove to fresh air and keep at rest in a position comfortable for breathing.Call a POISON CENTER/doctor if you feel unwell. First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15 minutes. Obtain medical attention if irritation persists. First-aid Measures After Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses,if present and easy to do.Continue rinsing.Seek medical attention. First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting.Get medical advice and attention if you feel unwell. 4.2. Most important symptoms and effects,both acute and delayed Symptoms/Injuries: Causes skin irritation.Causes serious eye irritation. May cause an allergic skin reaction. May cause respiratory irritation.There are potential chronic health effects to consider. Symptoms/Injuries After Inhalation: May cause respiratory irritation. May cause cancer by inhalation. Repeated exposure to respirable(airborne)crystalline silica dust will cause lung damage in the form of silicosis. Symptoms/Injuries After Skin Contact: Causes skin irritation.Redness, pain,swelling,itching, burning,dryness, and dermatitis. Symptoms/Injuries After Eye Contact: Causes serious eye irritation. Symptoms may include: Redness, pain,swelling,itching, burning,tearing,and blurred vision. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms: Causes damage to organs through prolonged or repeated exposure. May cause cancer. 4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed If you feel unwell,seek medical advice(show the label where possible). SECTION 5: FIRE-FIGHTING MEASURES 5.1. Extinguishing Media Suitable Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Unsuitable Extinguishing Media: Use of heavy stream of water may spread fire. Do not use a heavy water stream. 5.2. Special Hazards Arising From the Substance or Mixture Fire Hazard: Non-combustible. Brick as shipped do not pose a fire hazard. Explosion Hazard: Brick as shipped do not pose an explosion hazard. Reactivity: Hazardous reactions will not occur under normal conditions. 5.3. Advice for Firefighters Precautionary Measures Fire: Exercise caution when fighting any chemical fire. Firefighting Instructions: Do not allow run-off from fire fighting to enter drains or water sources. Do not breathe fumes or vapors from fire. Protection During Firefighting: Do not enter fire area without proper protective equipment,including respiratory protection. Other Information: Refer to Section 9 for flammability properties. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Handle in accordance with good industrial hygiene and safety practice.Avoid generation of dust during clean-up of spills. 6.1.1. For Non-emergency Personnel Protective Equipment: Use appropriate personal protection equipment(PPE). Emergency Procedures: Evacuate unnecessary personnel. 6.1.2. For Emergency Responders Protective Equipment: Equip cleanup crew with proper protection. Use appropriate personal protection equipment(PPE). Emergency Procedures: Ventilate area.Avoid creating or spreading dust. 6.2. Environmental Precautions Prevent entry to sewers and public waters. 6.3. Methods and Material for Containment and Cleaning Up For Containment: Contain and collect as any solid.Place spilled material into a container. Avoid actions that cause dust to become airborne. Avoid inhalation of dust.Wear appropriate protective equipment as described in Section 8. Do not wash product down sewage and drainage systems or into bodies of water(e.g. streams). Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. 6.4. Reference to Other Sections See heading 8, Exposure Controls and Personal Protection.Concerning disposal elimination after cleaning,see item 13. 06/03/2015 EN(English US) 2/6 Brick Safety Data Sheet According to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations SECTION 7: HANDLING AND STORAGE 7.1. Precautions for Safe Handling Additional Hazards When Processed: Avoid dust production that exceeds permissible exposure limits. Precautions for Safe Handling: Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Do not breathe dust. Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures.Wash hands and other exposed areas with mild soap and water before eating,drinking,or smoking and again when leaving work.Do not eat, drink or smoke when using this product. 7.2. Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions: Store in a dry,cool and well-ventilated place. Keep container closed when not in use.Store locked up. Incompatible Products: Strong acids.Strong bases.Strong oxidizers. 7.3. Specific End Use(s) Building material used for structural support. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters For substances listed in section 3 that are not listed here,there are no established exposure limits from the manufacturer, supplier, importer,or the appropriate advisory agency including:ACGIH(TLV), NIOSH (REL),or OSHA(PEL). Quartz(14808-60-7) USA ACGIH ACGIH TWA(mg/m3) 0.025 mg/m3(respirable fraction) USA ACGIH ACGIH chemical category A2-Suspected Human Carcinogen USA NIOSH NIOSH REL(TWA)(mg/m3) 0.05 mg/m3(respirable dust) USA IDLH US IDLH (mg/m3) 50 mg/m3(respirable dust) USA OSHA OSHA PEL(STEL)(mg/m3) 250 mppcf/%Si02+5, 10mg/m3/%Si02+2 Chromium(7440-47-3) USA ACGIH ACGIH TWA(mg/m3) 0.5 mg/m3 USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen USA NIOSH NIOSH REL(TWA)(mg/m3) 0.5 mg/m3 USA IDLH US IDLH (mg/m3) 250 mg/m3 USA OSHA OSHA PEL(TWA)(mg/m3) 1 mg/m3 Manganese(7439-96-5) USA ACGIH ACGIH TWA(mg/m3) 0.02 mg/m3(respirable fraction) 0.1 mg/m3(inhalable fraction) USA ACGIH ACGIH chemical category Not Classifiable as a Human Carcinogen USA NIOSH NIOSH REL(TWA)(mg/m3) 1 mg/m3(fume) USA NIOSH NIOSH REL(STEL)(mg/m3) 3 mg/m3 USA IDLH US IDLH(mg/m3) 500 mg/m3 USA OSHA OSHA PEL(Ceiling)(mg/m3) 5 mg/m3(fume) 8.2. Exposure Controls Appropriate Engineering Controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure.Use local exhaust or general dilution ventilation or other suppression methods to maintain dust levels below exposure limits. Power equipment should be equipped with proper dust collection devices. Personal Protective Equipment : Protective goggles.Gloves. Protective clothing. Dust formation: dust mask.111 • Materials for Protective Clothing : Chemically resistant materials and fabrics. Hand Protection : Wear chemically resistant protective gloves. Eye Protection : Chemical safety goggles. Skin and Body Protection : Wear suitable protective clothing. Respiratory Protection : If exposure limits are exceeded or irritation is experienced,approved respiratory protection should be worn. Environmental Exposure Controls : Avoid release to the environment. Safety Data Sheet According to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on Basic Physical and Chemical Properties Physical State : Solid Appearance : Granular brick-shaped solid;comes in wide range of colors Odor : Essentially odorless Odor Threshold : No data available pH : No data available Evaporation Rate : No data available Melting Point : No data available Freezing Point : No data available Boiling Point : No data available Flash Point : No data available Auto-ignition Temperature : No data available Decomposition Temperature : No data available Flammability(solid,gas) : No data available Vapor Pressure : No data available Relative Vapor Density at 20°C : No data available Relative Density : No data available Solubility : Water: Negligible Partition Coefficient:N-Octanol/Water : No data available Viscosity : No data available 9.2. Other Information No additional information available SECTION 10: STABILITY AND REACTIVITY 10.1. Reactivity: Hazardous reactions will not occur under normal conditions. 10.2. Chemical Stability: Stable under normal ambient conditions. 10.3. Possibility of Hazardous Reactions: Hazardous polymerization will not occur. 10.4. Conditions to Avoid: Direct sunlight. Extremely high or low temperatures.Incompatible materials. 10.5. Incompatible Materials: Strong acids.Strong bases.Strong oxidizers. 10.6. Hazardous Decomposition Products: May include oxides of aluminum and silicon. SECTION 11: TOXICOLOGICAL INFORMATION 11.1. Information On Toxicological Effects Acute Toxicity:Not classified Quartz(14808-60-7) LD50 Oral Rat >5000 mg/kg LD50 Dermal Rat >5000 mg/kg Chromium(7440-47-3) LD50 Oral Rat >5000 mg/kg Manganese(7439-96-5) LD50 Oral Rat >2000 mg/kg Skin Corrosion/Irritation:Causes skin irritation. Serious Eye Damage/Irritation:Causes serious eye irritation. Respiratory or Skin Sensitization:May cause an allergic skin reaction. Germ Cell Mutagenicity:Not classified Carcinogenicity:May cause cancer. Quartz(14808-60-7) IARC group 1 National Toxicology Program(NTP)Status Known Human Carcinogens. OSHA Hazard Communication Carcinogen List In OSHA Hazard Communication Carcinogen list. Chromium(7440-47-3) IARC group 3 Reproductive Toxicity: Not classified 06/03/2015 EN(English US) 4/6 Brick Safety Data Sheet According to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations Specific Target Organ Toxicity(Single Exposure): May cause respiratory irritation. Specific Target Organ Toxicity(Repeated Exposure):Causes damage to organs through prolonged or repeated exposure. Aspiration Hazard: Not classified Symptoms/Injuries After Inhalation: May cause respiratory irritation. May cause cancer by inhalation. Repeated exposure to respirable(airborne)crystalline silica dust will cause lung damage in the form of silicosis. Symptoms/Injuries After Skin Contact:Causes skin irritation. Redness, pain,swelling,itching, burning,dryness,and dermatitis. Symptoms/Injuries After Eye Contact:Causes serious eye irritation.Symptoms may include: Redness, pain,swelling, itching, burning,tearing,and blurred vision. Symptoms/Injuries After Ingestion: Ingestion is likely to be harmful or have adverse effects. Chronic Symptoms:Causes damage to organs through prolonged or repeated exposure. May cause cancer. SECTION 12: ECOLOGICAL INFORMATION 12.1. Toxicity Manganese(7439-96-5) NOEC chronic fish 3.6 mg/I (Exposure time:96h;Species:Oncorhynchus mykiss) 12.2. Persistence and Degradability Brick Persistence and Degradability Not established. 12.3. Bioaccumulative Potential Brick Bioaccumulative Potential Not established. 12.4. Mobility in Soil No additional information available 12.5. Other Adverse Effects Other Information : Avoid release to the environment. SECTION 13: DISPOSAL CONSIDERATIONS 13.1. Waste treatment methods Sewage Disposal Recommendations: Do not empty into drains. Do not dispose of waste into sewer. Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional,national,provincial, territorial and international regulations. SECTION 14: TRANSPORT INFORMATION 14.1. In Accordance with DOT Not regulated for transport 14.2. In Accordance with IMDG Not regulated for transport 14.3. In Accordance with IATA Not regulated for transport SECTION 15: REGULATORY INFORMATION 15.1 US Federal Regulations Brick SARA Section 311/312 Hazard Classes Immediate(acute)health hazard Delayed(chronic)health hazard SARA Section 313-Emission Reporting This product may contain constituents listed under SARA(Title III) Section 313,but not in amounts requiring supplier notification under 40 CFR Part 372 Subpart C. Quartz(14808-60-7) Listed on the United States TSCA(Toxic Substances Control Act)inventory SARA Section 311/312 Hazard Classes Immediate(acute) health hazard Delayed(chronic)health hazard Aluminum silicate(1327-36-2) Listed on the United States TSCA(Toxic Substances Control Act)inventory Chromium(7440-47-3) Listed on the United States TSCA(Toxic Substances Control Act)inventory Listed on United States SARA Section 313 SARA Section 313-Emission Reporting 1.0 Manganese(7439-96-5) Listed on the United States TSCA(Toxic Substances Control Act)inventory Listed on United States SARA Section 313 Safety Data Sheet According to Federal Register/Vol.77,No.58/Monday,March 26,2012/Rules and Regulations SARA Section 313-Emission Reporting 1.0% Iron(7439-89-6) Listed on the United States TSCA(Toxic Substances Control Act)inventory Calcium(7440-70-2) Listed on the United States TSCA(Toxic Substances Control Act) inventory 15.2 US State Regulations Quartz(14808-60-7) U.S.-California-Proposition 65-Carcinogens List WARNING:This product contains chemicals known to the State of California to cause cancer. Quartz(14808-60-7) U.S.-Massachusetts-Right To Know List U.S.-New Jersey-Right to Know Hazardous Substance List U.S.-Pennsylvania-RTK(Right to Know) List Chromium(7440-47-3) U.S.-Massachusetts-Right To Know List U.S.-New Jersey-Right to Know Hazardous Substance List U.S.-Pennsylvania-RTK(Right to Know)-Environmental Hazard List U.S.-Pennsylvania-RTK(Right to Know)-Special Hazardous Substances U.S.-Pennsylvania-RTK(Right to Know) List Manganese(7439-96-5) U.S.-Massachusetts-Right To Know List U.S.-New Jersey-Right to Know Hazardous Substance List U.S.-Pennsylvania-RTK(Right to Know)-Environmental Hazard List U.S.-Pennsylvania-RTK(Right to Know) List Calcium(7440-70-2) U.S.-Massachusetts-Right To Know List U.S.-New Jersey-Right to Know Hazardous Substance List U.S.-Pennsylvania-RTK(Right to Know) List SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION Revision Date : 06/03/2015 Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA Hazard Communication Standard 29 CFR 1910.1200. GHS Full Text Phrases: Carc. 1A Carcinogenicity Category 1A STOT RE 1 Specific target organ toxicity(repeated exposure)Category 1 STOT SE 3 Specific target organ toxicity(single exposure)Category 3 H335 May cause respiratory irritation H350 May cause cancer H372 Causes damage to organs through prolonged or repeated exposure This information is based on our current knowledge and is intended to describe the product for the purposes of health,safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. SDS US(GHS HazCom) 06/03/2015 EN(English US) 6/6 U.S.A. PORTLAND LIME & SAND SPEC---N nnIx V MASONRY MORTAR (M, S, N) ; �� ,,177: o,V S e s MASONRY PRODUCTS O 4 ic til P f.r_' —Al -� ,may... r • ....c----- y ' POPb ✓* . , -( * • its 40 f r .. +� ' 441k "4410,104. q , , A -"- Great Workability. Increased Productivity. SPEC MIX' Portland Lime&Sand mortar is aesignea to be compatible with the �'s� is a dry preblended mortar mix containing characteristics of the specified masonry �..� Portland cement,hydrated lime and dried unit.It is acceptable for all types of masonry xt masonry sand formulated for superior bond, construction with submittals available upon water retention and board life.Available in request.It may be used above or below Types M.S and N,each meets ASTM C 270 grade when manufactured to the appropriate ` and ASTM C 1714 requirements.In addition specification. to custom mix designs that are available SPEC MIX Portland Lime&Sand is produced for specific applications or properties,the under strict manufacturing standards.and TOTAL DUALITY CONTROL WITH EVERY BAG standard Portland Lime&Sand mortar complete quality control measures are ASTM C 270 LABORATORY TESTED MIX DESIGNS implemented with each batch.A digital PREBLENDED WITH SAND TO MINIMIZE LABOR COST printout displaying the proper proportions per CONSISTENCY BATCH TO BATCH OA MATERIALS USED batch may be kept as a permanent record. 46 Each SPEC MIX manufacturer certifies that GREAT WORKABILITY AND BOARD LIFE SPEC MIX masonry products are designed to NO SAND PILES OR WASTED MATERIALS LEFT ON SITE meet the project specifications and applicable ASTM and ACI standards. 0 1101 51 v F O it F w 1i%ti apit 1Vaail 08 w 'ft -t, ; gid U 'O p od vii A � � 8 ,���� . 1111 SPE``C Maj ,,,,,„.,„„,,,....„,,,,.....,...., DIVISION I A, INSTALLATION/APPLICATION -----Thi Mortar type should correlate with the particular APPLICABLE STANDARDS:ASTM AND ACI [ ASTM C 144 a7 FOR MASONRY 1,2 ASTM C 150 ,NDARD masonry unit to be used.The specifier should FOR Prmil AMP r,FMt- ASTM C 207 .NDARD SPECIE, ?,1E FOR evaluate the interaction of the mortar type and ASTM C 270 ,,haul' t i iuATlON FOR MORT.'. masonry unit specified.That is,masonry units ASTM C 595 a FOR BLENDED HYDRAULIC CEMEI: ASTM C 780_STANDARD TEST having a high initial rate of absorption will have METHOD Elk ,AND CONSTRUCTION EVALUATION OF MORTAilS i-us PLAIN AND REINFORCED greater compatibility with mortar that has high TINT'", _'^^ ASTM C 1093., ,HOARD PRACTICE FOR ACCREDITATION OF TESTING AGENCIES FOR UNIT water retentivity.The material properties of h1 ASTM C 1157 ':ANDARD PERFORMANCE SPECIFICATION FOR HYDRAULIC CEMENTS ASTM C 1314 mortar that influence the structural performance S1i,.. FOR COMPRESSIVE STRENGTH OF MASONRY PRISMS ASTM C 1586 STANDARD GUIDE of masonry are compressive strength,bond FOR QUALITY ASSURANCE OF MORTAR ASTM C 1714 STANDARD SPECIFICATION FOR PREBLENDED DRY MORTAR strength and elasticity.Because the compressive MIX FOR UNIT MASONRY ACI53t1 SPECIFICATION FOR MASONRY STRUCTURES strength of masonry mortar is less important \ than bond strength,workability and water retentivity,the latter properties should be given principal consideration in mortar selection.Select mortar based on the design requirements and ; 11 74444 1 with consideration of code and specification provisions affected by the mortar. A sample of the proposed product will be provided by the manufacturer for architectural ON approval and testing,if required.Preparation of this panel with all materials and systems employed in the final project is imperative. ,,,..,.. —: Retain the mock-up or field sample through the completion of the project. 1s' MIXING I Use a mechanical batch mixer to ensure homogeneity,workability and good board life. •Add the maximum amount of clean,potable Y• water for optimum workability. •Mix for five minutes consistently from batch to batch. job site forklift and the product is dispensed into Avoid direct contact with skin and eyes.If this a mechanical batch mixer.(See silo operations product should contact eyes,immediately flush •Tool mortar joints when the surface is thumb- manual.) with water for at least 15 minutes and consult print hard.Keep tooling times consistent. a physician.For skin exposure,wash promptly •Hand mix mortar only with written approval by LIMITED PRODUCT WARRANTY with plenty of soap and water.Remove soaked the specifier who should outline procedures. SPEC MIX,Inc.warrants this product to be of clothing promptly.If this product burns your skin, •Use mortar within 2.5 hours after initial mixing. merchantable quality when used or applied in see a physician immediately.This product may accordance with the instructions.This product contain silica.Silica dust if inhaled may cause •Retemper mortar only when mixing water is lost respiratory or other health problems.Prolonged idue to evaporation. snot warranted as suitable for any purpose or inhalation may cause delayed lung injury, use other than the general purpose for which it is •Allow mortar to cure a minimum of 7 days but intended.Liability under this warranty is LIMITED including silicosis and possibly cancer.A N95 no more than 28 days before cleaning.Consult to the replacement of the product(as purchased) approved dust mask,eye protection,and rubber manufacturer of the masonry units and cleaning if found to be defective,or at the shipping boots and gloves are recommended when using chemicals for further instructions to ensure company's option,to refund the purchase price. this product.Material Safety Data Sheets can be proper washing procedures. All claims under this warranty must be written viewed online at www.specmix.com Clean masonry only with a national proprietary and submitted to SPEC MIX,Inc. KEEP OUT OF REACH OF CHILDREN cleaning agent(following the manufacturer's WARNING:This product contains chemicals instructions)or potable water.SPEC MIX LIMITATIONS known to the State of California to cause cancer. products are custom packaged to the specification.They must be kept dry,covered SPEC MIX Portland Lime&Sand mortar should and protected from weather and other damage. be installed in accordance with the provisions of the local building code and applicable ASTM SIZES AND EQUIPMENT standards.Good workmanship coupled with proper detailing and design assures durable, SPEC MIX Portland Lime&Sand mortar is functional,watertight construction. TECHNICAL SUPPORT available in 80 lb.(36 kg.)packages for easy •CONTACT YOUR LOCAL SPEC MIX MANUFACTURER hand loading or in 3,000 lb.(1,362 kg.)reusable WARNING bulk bags to be used with the various SPEC • VISIT WWw.SPECMIx.COM MIX silo systems.When using the silo system, IMPORTANT!READ BEFORE USING This •CONTACT SPEC MIX`,INC. once the bulk bags of mortar are delivered to product contains Hydraulic cement.Contact with PHONE:888-SPEC-MIX FAX:888-FAX-SPEC the project site,the portable silo is loaded with a freshly mixed product can cause severe burns. IN SPEC MIX PRODUCTS ARE PRODUCED BY ITS LICENSED MANUFACTURING FACILITIES THROUGHOUT THE US.AND CANADA EACH MANUFACTURER ADHERES TOA STRICT QUALM ASSURANCE PROGRAM TO BSINtE COMPLETE OIIMII'CBNTBOL N EVERY BATCH 2025 CENTRE POINTE BLVD MENDOTA HEIGHTS, MN 55120 T 1 888-SPEC-MIX F 1 888-329-7732 ,.. . ,i i ,":.,.C:4, I,,, 0 2011 SPEC MIX,INC. , h l Y........m KEEP GOING.KEEP MOVNG KffP WORKING Material Test Report SPEC MIX Product Description: 3000 lb. SPEC MIX®Portland Lime and Sand/Type N Item Number: SRSM19008 Manufacturing Plant: QUIKRETE®-Dallas Sample Identification Initial Testing Test Date: 8/30/2010 Test Specification Results Lab Code: 10-2292 Water(%) As required 16.3 Consistency 105-115%@25d 114 Unit Weight 1 132 Set Time Air(%) Strength Testing Test Compressive Strength(psi) Flexural Strength(psi) Age Specification Result Specification Result +r,r 1 day 3 day 7 day 1 1670 28 day 750 2170 Other Testing Test Specification Test Results Water Retention >=75% 90 +#4 Sieve 0% 0 Certified by: THE QUIKRETE®COMPANIES Inc. A. .+14.40„..,a, 4 /, Technical and Engineering Center 500 Marathon Parkway Lawrenceville,GA 30046 Wendy Henry 770.216.9580•www.quikrete.com Quality Assurance Manager 651.994.7120•www.specmix.com KEEP GOING.KEEP MOVING.KEEP WORKING. Amok SPEC MIX April 30,2013 Product Description: 3000 lb.SPEC MIX®Portland Lime&Sand Mortar/Type N Item Number: SRSM19008 Manufacturing Plant: QUIKRETE®-Dallas This letter certifies that the bulk masonry mortar referenced above,manufactured according to the approved formulation with approved raw materials,will meet the proportion and property specifications of both ASTM C 1714, Standard Specification for Preblended Dry Mortar Mix for Unit Masonry,and ASTM C 270,Standard Specification for Mortar for Unit Masonry,for a Type N mortar. The raw materials used in this product formulation are:Type I/II Gray Portland Cement meeting ASTM C 150,Standard Specification for Portland Cement, Hydrated Lime Type S meeting ASTM C 207,Standard Specification for Hydrated Lime for Masonry Purposes,and Mason Sand meeting ASTM C 144,Standard Specification for Aggregate for Masonry Mortar. It is available as a standard gray,as well as in a variety of custom colors. For custom colors,or versions with integral water repellent, mortar set retarder,or mortar set accelerator,the finished product item number will vary from the base design item number above depending upon the specific pigment and/or additive.These versions will also meet the specifications described above. Mortar property characteristics including compressive strength are specified according to ASTM C 270 with laboratory testing. ASTM C 270(property specification)is not for use to specify minimum compressive strengths to be achieved by field mixed mortars. Field mixed mortar may be tested according to ASTM C 780 to evaluate mortar properties such as mortar water content or consistency.As defined in ASTM C 1586,compressive strength values determined through ASTM C 780 in the field are not expected nor required to achieve the compressive strengths of laboratory tested ASTM C 270 specification mortars. We are pleased to be of service to you. If you have any questions,please let us know. THE QUIKRETE®COMPANIES Inc.-Technical and Engineering Center 500 Marathon Parkway Lawrenceville,GA 30046 770 216 9580•www quikrete corn SPEC MIX Safety Data Sheet(SDS)-Portland/Lime Based Masonry MortarsAL A , SECTION I: PRODUCT IDENTIFICATION SPEC MIX, Inc. 1230 Eagan Industrial Rd. Ste 160 Eagan, MN 55121 Emergency Telephone Number(800) 282-5828 Information Telephone Number(888) 773-2649 Revision: Jun-15 SDS SM4 Spec Mix®Product Name Item #(s) a. Portland Lime&Sand Mortar (PL-01) b. Portland Lime&Sand Mortar-Type M (PL-02) c. Portland Lime&Sand Mortar-Type S (PL-03) d. Portland Lime&Sand Mortar-Type N (PL-04) e. Portland Lime&Sand Mortar-Color (PL-05) f. Integral Water Repellent Mortar(IWR)-Type M (IW-01) g. Integral Water Repellent Mortar(IWR)-Type S (IW-01) h. Integral Water Repellent Mortar(IWR)-Type N (IW-01) i. Integral Water Repellent Mortar(IWR)-Color (IW-05) j. Tuckpoint Mortar (TP-01) k. Tuckpoint Mortar-Color (TP-05) I. Set Accelerated Mortar-Type M (SA-01) m. Set Accelerated Mortar-Type S (SA-01) n. Set Accelerated Mortar-Type N (SA-01) o. Set Accelerated Mortar-Color (SA-05) p. Set Delayed Mortar-Type M (SD-01) q. Set Delayed Mortar-Type S (SD-01) r. Set Delayed Mortar-Type N (SD-01) s. Set Delayed Mortar-Color (SD-05) t. Underground Utility Mortar (UG-01) u. Underground Utility Mortar-Color (UG-05) v. Stone Veneer Mortar (VM-01) w. Stone Veneer Mortar-Color (VM-05) x. Building Stone Mortar (SM-01) y. Building Stone Mortar-Color (SM-05) z. Setting Bed Mortar (SB-01) aa.Setting Bed Mortar-Color (SB-05) Product Use: Mortars for construction with block, brick, veneer stones, etc. Page 1of10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 SECTION II - HAZARD IDENTIFICATION Hazard-determining components of labeling: Silica, Portland cement 2.1 Classification of the substance or mixture Carcinogen-Category 1A Skin Corrosion-Category 1B Skin Sensitization -Category 1B Specific Target Organ Toxicity Repeat Exposure-Category 1 Specific Target Organ Toxicity: Single Exposure-Category 3 2.2a Signal word DANGER! 2.2b Hazard Statements May cause cancer through chronic inhalation Causes severe skin burns and serious eye damage May cause an allergic skin reaction Causes damage to lungs through prolonged or repeated inhalation May cause respiratory irritation 2.2c Pictograms 2.2d Precautionary statements Do not handle until all safety precautions have been read and understood. Wear protective gloves, eye protection, and protective clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Use in a well-ventilated area. Do not breathe dust. If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on skin (or hair): Remove immediately all contaminated clothing and wash before re-use. Rinse skin or hair with water. If significant skin irritation or rash occurs: get medical advice or attention. Immediately seek medical advice or attention if symptoms are significant or persist. Page 2 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/containers in accordance with all regulations. 2.3 Additional Information Precautions must be observed because burns occur with little warning -- little heat is sensed. 2.3a HNOC-Hazards not otherwise classified: Not applicable 2.3b Unknown Acute Toxicity: None 2.3C WHMIS Classification Class D2B-Skin/Eye Irritant Class D2A-Chronic Toxic Effects-Carcinogen Class E-Corrosive Material 2.3d Label Elements According To WHMIS Hazard Symbols Signal Word DANGER! SECTION III - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION Hazardous Components CAS No. % by Weight Sand, Silica, Quartz 14808-60-7 40-70* Portland Cement 65997 15 1 10-30* Lime 01305-62-0 5-10* May Contain Inorganic Pigment Non-Hazardous 0-5 *The concentrations ranges are provided due to batch-to-batch variability. None of the constituents of this material are of unknown toxicity. SECTION IV-FIRST AID MEASURES 4.1 Description of the first-aid measures General information: After inhalation: Remove person to fresh air. If breathing is difficult, administer oxygen. If not breathing, give artificial respiration. In case of unconsciousness, place patient stably in side position for transportation. Page3of10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 After skin contact: Wash skin with cool water and pH-neutral soap or a mild detergent. If significant skin irritation or rash occurs: get medical advice or attention. After eye contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. After swallowing: Do not induce vomiting. If conscious, have the victim drink plenty of water and call a physician immediately. Never give anything by mouth to art unconscious person. 4.2 Most important symptoms/effects, acute and delayed Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or repeated inhalation. This product contains crystalline silica. Prolonged or repeated inhalation of respirable silica from this product can cause silicosis. Skin contact: Causes skin irritation. Handling can cause dry skin, discomfort, irritation, and dermatitis. May cause sensitization by skin contact. Product becomes extremely alkaline when exposed to moisture, and can cause alkali burns and affect the mucous membranes. Precautions must be observed because burns occur with little warning -- little heat is sensed. Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Ingestion: May be harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or vomiting. 4.3 Indication of immediate medical attention and special treatment needed: Immediately seek medical advice or attention if symptoms are significant or persist. SECTION V - FIRE FIGHTING MEASURES 5.1 Flammability of the Product: Non-flammable and non-combustible 5.2 Suitable extinguishing agents: Treat for surrounding material 5.3 Special hazards arising from the substance or mixture: None 5.3a Products of Combustion: None 5.3b Explosion Hazards in Presence of Various Substances: Non-explosive in presence of shocks SECTION VI-ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures: Wear personal protective equipment (See section VIII). Keep unprotected persons away. 6.2 Methods and material for containment and cleaning up: Do not allow to enter sewers/surface or ground water. Dispose of unwanted materials and containers properly in accordance with all regulations. Page 4 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND STORAGE 7.1 Handling Precautions for safe handling: Ensure good ventilation/exhaustion at the workplace. DO NOT BREATHE DUST. In dusty environments,the use of an OSHA, MSHA or NIOSH approved respirator and tight fitting goggles is recommended. Wear appropriate PPE (See section 8). Do not mix with other chemical products, except as indicated by the manufacturer. Do not get in eyes, on skin or clothing. Good housekeeping is important to prevent accumulation of dust. 7.2 Storage Requirements to be met by storerooms and receptacles: No special requirements. Information about storage in one common storage facility: Not required. Further information about storage conditions: Keep out of the reach of children. Keep container tightly closed and prevent exposure to humidity. Do not allow water to contact the product until time of use to preserve product utility. SECTION VIII-EXPOSURE CONTROL MEASURES/PERSONAL PROTECTION 8.1 Components with limit values that require monitoring at the workplace: Hazardous Components CAS No. PEL(OSHA) TLV(ACGIH) mg/M3 mg/M3 Silica Sand, crystalline 14808-60-7 0.1 0.025(resp) Portland Cement 65997-15-1 5(resp) 15(total) 10 (resp) Lime 01305-62-0 5 5 Pulverized Limestone 01317-65-3 5(resp) 15 (total) 10 (resp) 8.2 Exposure Controls Use ventilation adequate to keep exposures below recommended exposure limits. 8.3 General protective and hygienic measures Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing.Wash hands before breaks and at the end of work.Avoid contact with the eyes and skin. 8.3a Personal protective equipment Protection of hands: Wear gloves of adequate length to offer appropriate skin protection from splashes. Nitrile, Butyl and PVC gloves have been found to offer adequate protection for incidental contact. Precautions must be observed because burns occur with little warning -- little heat is sensed. Eye protection: Wear approved eye protection (properly fitted dust- or splash-proof chemical safety glasses. Respiratory protection: Page 5 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 A NIOSH-approved dust mask or filtering face piece is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirators should be selected by and used under the direction of a trained health and safety professional,following requirements found in OSHA's respirator standard (29 CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2). SECTION IX- PHYSICAL/CHEMICAL CHARACTERISTICS General Information Appearance Form: Granular Solid Color: Gray to gray-brown colored Odor: None pH-value at 20°C (68°F): 13 (10%) Boiling point/Boiling range: Not applicable Flash point: Not applicable Auto igniting: Product is not self-igniting Vapor pressure at 21°C (70°F) Not available Density at 25°C (77 °F): 2.6 to 3.15 Solubility in/Miscibility with Water: Insoluble VOC content: 0 g/L VOC SECTION X-STABILITY AND REACTIVITY 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal storage conditions. Keep in dry storage. 10.3 Possibility of hazardous reaction No dangerous reaction known under conditions of normal use. 10.4 Thermal decomposition/conditions to be avoided No decomposition if used according to specifications. 10.5 Incompatible materials Contact of silica with powerful oxidizing agents such as fluorine, chlorine trifluoride, manganese trioxide, or oxygen difluoride may cause fires 10.6 Hazardous Decomposition or By-products Silica will dissolve in Hydrofluoric Acid and produce a corrosive gas-silicon tetrafluoride. SECTION XI-TOXICOLOGICAL INFORMATION Page 6 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 11.1 Exposure Routes: Skin contact, skin adsorption, eye contact, inhalation, or ingestion. 11.2 Symptoms related to physical/chemical/toxicological characteristics: Inhalation: May cause respiratory tract irritation. Causes damage to organs through prolonged or repeated exposure. This product contains crystalline silica. Prolonged or repeated inhalation of respirable silica from this product can cause silicosis. Skin contact: Causes skin irritation. Handling can cause dry skin, discomfort, irritation, and dermatitis. May cause sensitization by skin contact. Product becomes extremely alkaline when exposed to moisture, and can cause alkali burns and affect the mucous membranes. Eye Contact: Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Ingestion: Harmful if swallowed. Ingestion may cause discomfort and/or distress, nausea or vomiting. 11.3 Delayed, immediate and chronic effects of short-term and long-term exposure Short Term Skin Corrosion/Irritation: Causes severe skin burns. Serious Eye Damage/Irritation: Causes severe eye damage. Respiratory Sensitization: Not available Skin Sensitization: May cause an allergic skin reaction. Specific Target Organ Toxicity-Single Exposure: (Category 1) Causes respiratory irritation. Aspiration Hazard: Not available Long Term Carcinogenicity: May cause cancer through chronic inhalation. Germ Cell Mutagenicity: Not available Reproductive Toxicity: Not available Specific Target Organ Toxicity- Repeated Exposure: (Category 1)Causes damage to lungs through prolonged/repeated exposure Synergistic/Antagonistic Effects: Not available. SECTION XII-ECOLOGICAL INFORMATION 12.1 Ecotoxicity May cause long-term adverse effects to the aquatic environment. Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. Must not reach bodies of water or drainage ditch undiluted or un-neutralized 12.2 Persistence and degradability No further relevant information available. Page 7 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 12.3 Bioaccumulative potential: No further relevant information available. 12.4 Mobility in soil No further relevant information available. 12.5 Other Adverse Effects No further relevant information available. SECTION XIII- DISPOSAL CONSIDERATIONS 13.1 Waste Disposal Method The packaging and material may be land filled; however, material should be covered to minimize generation of airborne dust. This product is not classified as a hazardous waste under the authority of the RCRA (40CFR 261) or CERCLA (40CFR 117&302). Disposal must be made in accordance with local, state and federal regulations. 13.2 Other disposal considerations Uncleaned packaging recommendation: Disposal must be made in accordance with local, state and federal regulations. Recommended cleansing agent: Water, if necessary with cleansing agents. SECTION XIV-TRANSPORT INFORMATION DOT(U.S.) TDG (Canada) UN-Number Not Regulated Not Regulated UN proper shipping name Not Regulated Not Regulated Transport Hazard Class(es) Not Regulated Not Regulated Packing Group (if applicable) Not Regulated Not Regulated 14.1 Environmental hazards: Not Available 14.2 Transport in bulk according to Annex II of Marpol 73/78 and the IBC Code Not available 14.3 Special precautions for user Do not handle until all safety precautions have been read and understood. SECTION XV-OTHER REGULATORY INFORMATION Page 8 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 15.1 Safety, Health and Environmental Regulations/Legislations specific for the chemical Canada WHMIS Classification: Considered to be a hazardous material under the Hazardous Products Act as defined by the Controlled Products Regulations and subject to the requirements of Health Canada's Workplace Hazardous Material Information (WHMIS).This document complies with the WHMIS requirements of the Hazardous Products Act (HPA) and the CPR. 15.2 US Federal Information SARA 302/311/312/313 Components No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302, 311, 312 or 313. RCRA: Crystalline silica (quartz) is not classified as a hazardous waste under the Resource Conservation and Recovery Act, or its regulations, 40 CFR§261 et seq. CERCLA: Crystalline silica (quartz) is not classified as a hazardous substance under regulations of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), 40 CFR§302. Emergency Planning and Community Right to Know Act (SARA Title Ill): Crystalline silica (quartz) is not an extremely hazardous substance under Section 302 and is not a toxic chemical subject to the requirements of Section 313. FDA: Silica is included in the list of substances that may be included in coatings used in food contact surfaces, 21 CFR §175.300(b)(3)(xxvi). NTP: Respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, is classified as Known to be a Human Carcinogen. OSHA Carcinogen: Crystalline silica (quartz) is not listed. 15.3 State Right to Know Laws California Prop. 65 Components WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Inhalation Reference Exposure Level (REL): California established a chronic REL of 3 pg for silica (crystalline, respirable).A chronic REL is an airborne level of a substance at or below which no adverse health effects are anticipated in individuals indefinitely exposed to the substance at that level. Massachusetts Toxic Use Reduction Act: Silica, crystalline (respirable size, <10 microns) is "toxic" for purposes of the Massachusetts Toxic Use Reduction Act. 15.4 Global Inventories DSL All components of this product are on the Canadian DSL list. TSCA No.: Crystalline silica (quartz) appears on the EPA TSCA inventory under the CAS No. 14808-60-7. All constituents are listed in the TSCA inventory. 15.5 NFPA Ratings Page 9 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 T 888.773.2649 F 651.454.5315 e 1 •. NFPA Rating Explanation Guide 4► HEALTH HAZARD FLAMMABILITY HAZARD 4•Can tsa lethal r-wt. 3=Can •``..' or permanent injury _ O 4.1 mpoCan nry .,.i seupaeltation or residual injury ..,.a..w - 1 a Can cause significant , tt inflation . / r..`••• O.No hazard n-:4,`C,'::.,. .. 0 i ALX•Alkalina ACID•Acidic '„:" •"• COP=c /':W Ingle./of nxr. OX -o-am=oy _ _ M :Radinactirvn cr,*air aD = Pnrrrunnr ± E : o.s..m. SPECIAL HAZARD INSTABILITY HAZARD Rax nun M*ease arty•ror compl.M1.M.Acalran.cancan fne xr01 lw Sea rasa __ J SECTION XVI-OTHER INFORMATION Last Updated: June 19, 2015 NOTE: The information and recommendations contained herein are based upon data believed to be correct. However, no guarantee or warranty of any kind, express or implied, is made with respect to the information contained herein. We accept no responsibility and disclaim all liability for any harmful effects which may be caused by exposure to silica contained in our products. Prepared by SPEC MIX, Inc. Phone (888) 773-2649 www.SPECMIX.com End of SDS Page 10 of 10 SPEC MIX, Inc. 1230 Eagan Industrial Rd. Suite 160, Eagan, MN 55121 7 888.773.2649 F 651.454,5315 SUBMIT''. L REVIEW /�: in Veneer Anchors REviEviED cl ,vvD,t RESUBMIT ' iii `'I�• DW-1 OHS® "ubrutW Review is for � R�JECfFD C reldacumratt Notes or marl�p raanceshall notwftli the sPecificatiom HOHMANN &BARNARD, INC. g a. contrractorfrom -liana°fhb l 7 Plans t a MiTek company ^'pec.'ievuppt orkmanship, and safety mgmre�ments OD tecbaique of auembly, DW-10HS® Arnold&Associates,Inc. kVa Vee Byna-Tie ( I''''N't. ,,,,,,„,,z1;4.',..",, >. IIIIIIIIk\ O 3" � moi. \ `ts '''''...N..),\H -84 initio.. _! DRAWINGS FOR ILLUSTRATIVE PURPOSES ONLY H&B RECOMMENDS 16"X 16"SPACING Description: Dimensions: The DW-10HSwanchor is for anchoring brick veneer to metal stud, DW-10HSw is 5 W long with 3"vertical adjustability and is furnished masonry,concrete or wood backups when there is no insulation or little with 9132"0 holes. Available 14 ga.or 12 ga.thick. potential for wallboard deterioration. Vee Byna-Tiewis 3116"0 or 114"0 x 3",3'A",4",4 W,5"long. Wire(Carbon Steel): Finish: Cold-drawn steel wire conforming to ASTM Al 064/A1064M: ❑ Mill Galvanized Tensile Strength-80,000 p.s.i.,Yield Point-70,000 p.s.i.minimum Zinc Coating: E✓ Hot-Dip Galvanized Mill Galvanized:ASTM A641/A641M(0.1 oz/ft')(0.1 oz/ft') Stainless Steel: ❑Type 304 ❑Type 316 Hot-Dip Galvanized after fabrication:ASTM A153/A153M-B2(1.5 oz/ft') Wire(Stainless Steel): Note: H&B recommends Stainless Steel for maximum protection ASTM A580/A580M-AISI Type 304 or Type 316 against corrosion Sheet Metal(Carbon Steel): Anchor Thickness: ASTM A1008/A1008M Zinc coating: ❑ 14 gauge a 12 gauge ASTM A653/A653M(0.6 oz/ft')(Mill Galvanized) ASTM A153/A153M-82 Class B(sheet metal ties and anchors hot-dip Vee Byna-Tie 0: galvanized after fabncation). ❑✓ 3116"0 Standard Sheet Metal(Stainless Steel): ❑ 1/4"0 Heavyweight ASTM A 666,ASTM A480/480M,and ASTM A240/A240M AISI Type 304 or 316 Vee Byna-Tie Length: NOTE:DW-10HS should NOT be installed on top of insulation. ❑ 3" ❑ 314" ❑ 4" ❑ 4'f:" ❑ 5" ❑ Other IMPORTANT:Since each construction project is unique,the appropriate selection and use of arty product contained herein must be determined by competent architects,engineers and other appropnate professionals who are familiar with the specific requirements of the project in question. This drawing and/or data sheet is the confidential and proprietary information of Hohmann 8 Barnard,Inc.and is not to be reproduced,copied or disclosed,in whole or in part,without the prior written consent of H&B. HOHMANN&BARNARD,Inc. Branch/Subsidiary Locations: ©2013-2016 MiTeke CORPORATE HEADQUARTERS ALABAMA-ARIZONA-ILLINOIS 30 Rasons Court I Hauppauge,NY 11788 MARYLAND-NEW YORK T:800.645.0616 F:631.234.0683 PENNSYLVANIA-TEXAS-UTAH www.h-b.com CANADA Aro HOHMANN&BARNARD,INC. SAFETY DATA SHEET a MiTek company 1. Identification Product Identifier:Zinc Metal: Special High Grade Manufacturer: Telephone Numbers Hohmann&Barnard, Inc. During normal business hours call: (800)645-0616 30 Rasons Court 24-hour emergency call Chemtrec: (800)255-3924 Hauppauge, NY 11788 (631)234-0600 www.h-b.com 2. Hazards Identification EMERGENCY OVERVIEW: Short Term Overexposure:ZINC: Inhalation of high levels of zinc vapor(zinc oxide fumes)may result in tightness of chest, metallic taste, cough, dizziness, fever, chills, headache, nausea, and dry throat. Overexposure may produce symptoms known as metal fume fever or"zinc shakes"; an acute, self-limiting condition without recognized complications. Symptoms of metal fume fever include: chills, fever, muscular pain, nausea and vomiting. Long Term Overexposure:ZINC: Chronic exposure to zinc may cause respiratory tract irritation with nasopharyngitis and laryngitis Medical Conditions Generally Aggravated By Exposure: Inhalation of dust may be an irritant to pre-existing respiratory conditions Prevention:Avoid contact with acids and alkalis.. Route of Exposure: PRIMARY: Inhalation, if material has been heated above the boiling point, driving off zinc fume. SECONDARY: Ingestion of dusts.. GHS Ratings: Inhalation Toxicity:Acute 4 GHS Hazards H332 May be harmful if inhaled GHS Precautions P261 Avoid breathing dust/fume/gas/mist/vapours/spray P271 Use only outdoors or in a well-ventilated area P312 Call a POISON CENTER or doctor/physician if you feel unwell P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a posi-tion comfortable for breathing Signal Word:Warning •POTENTIAL HEALTH EFFECTS: Inhalation: Inhaling dust may be an irritant to pre-existing respiratory conditions. Skin: No data found. Ingestion: No data found. Eyes: No data found. Carcinogenicity: N/A. Page 1 of 4 HOHMANN & BARNARD, INC. SAFETY DATA SHEET 3. Composition/Information on Ingredients Component CAS No. ZINC 7440-66-6 99.9 Hazardous Material National Fire Protection Information System(HMIS) Association(NFPA) Flammability HMIS&NFPA Hazard Rating Legend 11 ". t • *-CHRONIC HEALTH HAZARD 1 0=INSIGNIFICANT 1 Health .. 0 O Instability 1=SLIGHT 2=MODERATE ' Personal Protection 01 3=HIGH Special 4. First-Aid Measures Symptoms resulting from inhalation overexposure usually disappear within 24 hours. Symptomatic treatment,such as bed rest and pos- sibly aspirin is recommended to provide relief from fever and chills. In all cases, consult physician for medical attention. 5. Fire-fighting measures FLASH POINT: N/A EXTINGUISHING MEDIA: Smother and cool with a suitable dry extinguishing agent(class D fires)such as dry powder(Ansul Met-L- X), zinc oxide or dry sand.Water should not be used; however wherever it is necessary to cool exposures,extreme caution should be taken to prevent contact with molten zinc or burning zinc products. HAZARDOUS COMBUSTION PRODUCTS: No data found. FIRE FIGHTING PROCEDURES: No Data Found. FIRE FIGHTER PROTECTION: Use NIOSH/MSHA approved self-contained breathing apparatus. UNUSUAL FIRE AND EXPLOSION HAZARDS: Heating of metal beyond boiling point results in evolution of zinc vapors,which immedi- ately reacts with air to form zinc oxide fume.Slabs must be completely dry before charging into molten metal to prevent a steam explosion. 6.Accidental release measures STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Material should be contained for recycling. WASTE DISPOSAL METHODS:Material may be recycled or disposed of in accordance with Federal,State,and Local Environmental Regulations.This material may be regulated under CERCLA,TSCA,SARA,and/or RCRA Regulations. CLEAN WATER ACT REQUIREMENTS: No data found RESOURCE CONSERVATION AND RECOVERY ACT(RCRA)REQUIREMENTS: No data found 7. Handling and storage PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in a dry location, separate from acids and alkalis. Keep metal dry so it does not contain any moisture when ready for use. OTHER PRECAUTIONS: Damp slabs placed in molten metal may result in a steam explosion.Always practice good personal hygiene when working in areas where this material exists. REGISTRATIONS/CERTIFICATIONS: No data found. 8. Exposure controls/personal protection ENGINEERING CONTROLS: No data found ADMINISTRATIVE CONTROLS: No data found VENTILATION: Local exhaust or other ventilation that will reduce dust concentrations to less than permissible exposure limits PROTECTIVE GLOVES: Recommended to prevent skin irritation in hypersensitive individuals EYE PROTECTION: Use safety eyewear for protection against airborne particulate matter. RESPIRATORY PROTECTION(SPECIFIC TYPE): Use NIOSH/MSHA approved type respirator for protection against dust and metal fume. OTHER:To prevent burns from contact with molten metal, appropriate protective garments should be worn. Such garments may include aprons,face shields, leggings,etc., depending on conditions of use. LOCAL EXHAUST: N/A. MECHANICAL(GENERAL): N/A SPECIAL: N/A Page 2 of 4 HOHMANN & BARNARD, INC. SAFETY DATA SHEET OTHER: N/A. 9. Physical and chemical properties Physical Form: Solid Taste: No data found Appearance: Silver-white, or Bluish-white metal Odor: None Color: No data found Odor Threshold: No data found Boiling Point: 1665°F Vapor Pressure: 0.13kPa @ 909°F Melting Point: 788°F Vapor Density: N/A Freezing Point: No data found Evaporation Rate: N/A Specific Gravity: 7.12 VOC(Weight): No data found Density: No data found VOC(Volume): No data found Bulk Density: No data found Volatiles(Weight): No data found Viscosity: No data found Volatiles(Volume): No data found pH: No data found Flash Point: N/A Water Solubility: Negligible Upper Explosion Limit: N/A Partition Coefficient-Octanol/Water: No data found Lower Explosion Limit: N/A Molecular Weight: No data found Auto Ignition: No data found Decomposition Temp.: No data found Flammability(Solid, Gas): No data found 10. Stability and reactivity STABILITY: Stable. HAZARDOUS DECOMPOSITION:Zinc boils off as vapor at elevated temperatures. HAZARDOUS POLYMERIZATION:Will not occur. CONDITIONS TO AVOID: None. INCOMPATIBLE MATERIALS:Avoid contact with acids and alkalis. 11. Toxilogical information ROUTES OF ENTRY: PRIMARY: Inhalation, if material has been heated above the boiling point, driving off zinc fume. SECONDARY: Ingestion of dusts. TARGET ORGANS: No data found. EFFECTS OF OVEREXPOSURE: Short Term Overexposure:ZINC: Inhalation of high levels of zinc vapor(zinc oxide fumes)may result in tightness of chest, metallic taste, cough, dizziness,fever, chills, headache, nausea, and dry throat.Overexposure may produce symptoms known as metal fume fever or"zinc shakes";an acute,self-limiting condition without recognized complications.Symptoms of metal fume fever include chills, fever, muscular pain, nausea and vomiting. Long Term Overexposure:ZINC: Chronic exposure to zinc may cause respiratory tract irritation with nasopharyngitis and laryngitis. CARCENOGENICTY: None. 12. Ecological Information No data available for this product. 13. Disposal Considerations Material may be recycled or disposed of in accordance with Federal, State, and Local Environmental Regulations.This material may be regulated under CERCLA,TSCA, SARA, and/or RCRA Regulations. 14.Transport information D.O.T. Shipping Information: Not data found. I.M.O. Shipping Information: Not data found. Page 3 of 4 HOHMANN & BARNARD, INC. SAFETY DATA SHEET 15. Regulatory Information No data found. 16. Other information Issue Date: May 31, 2015 Revision Date: May 31, 2015 The data in this Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process.This information is taken from sources or based upon data believed to be reliable; however, Hohmann&Barnard, Inc.disclaims any warranty,express or implied, as to the absolute correctness or sufficiency of any of the foregoing or that additional or other measures may be required under particular conditions. The information contained herein is based on current knowledge and experience; no responsibility is accepted and that the information is sufficient or correct in all cases. Users should consider this data only as a supplement to other information. Users should make independent determinations of suitability and completeness of information from all sources to assure proper use and disposal of these materials,the safety and health of employees and customer, and the protection of the environment. .::' - Hohmann & Barnard, Inc. Page 4 of 4 30 Rasons Court I Hauppauge, NY 11788 w10> ig TEL:800-645-0616 ( FAX:631-234-0683 HOHMANN&BARNARD,INC. www.h-b.com SUBMITT L REVIEW '.'` REVIEWED REVISE AND RESUBMIT ❑ lb FURNISH AS CORRECTED C REJECTED,_ ❑ A:: Flashing and Reglets Sukarno?Review is for general conformance With the specifications - and contract documents.Notes or markings shall not be construed ` w R caving the contractor from compliance with project plans and F I ex-F l a s h° F I a s h i 3.R,Cavo Contractor shall be solely responsible for all HOHMANN & BARNARD, INC. de c quantities,dimensions,fabrication,technique of assembly, a MiTek company Self Adhering Flashing workmanship,and safety requirements. Arnold k • ..-.. : Inc. �� �� TERMINATION wAnoN �� B . --k ) ''--1 *'::.::---, 0 1 4 I I‘) . 1"l'( ',(I>. 1 4Iii _- .-----r, ►ate\ 1t�1:r..► I •rrar%dili,4 1 --•6- 14% 11NillN* 0 `--DRIP PLATE •'•PLATE DRIP PLATE CMU THRU-WALL CMU � METAL STUD �j 10•1210v11 - � `0 2 I ' ' eN1� ISMS 0 V V. 2-1 I eAL 1 OKi' ,,fir':7 .Y " d.1-1- .,0 DRAWINGS FOR ILLUSTRATIVE PURPOSES ONLY Flex-Flash®Flashing Sizes: (Rolls ar- 5 ft. long) Thru-Wall/Surface-Mount Flashing Widths: El 12" ❑16 : ❑20" El 24" Flex-Flash®is a polyester scrim reinforced 40-mil thick mem- brane formulated with Elvaloy®Kee*. Flex-Flash®has a ❑36" ❑Other pressure-sensitive,clear adhesive that will not drool when exposed to UV or heat. Stainless Steel DP-Drip Plate: (Recommended) •Extremely tough,with excellent impact and tear resistance. ❑1 '/2" ❑3" ❑Other •Flexibility is maintained in all weather environments,even in Flex-Flash®Drip Edge: extreme heat or cold. ❑3" •Highly resistant to oils and will repel most chemicals. •Compatible with most silicone and urethane sealants. Termination Bar: •Not susceptible to degradation by UV. ©Stainless Steel(Type 304) •An optional stainless steel drip edge is recommended to 0 Aluminum ensure diversion of moisture to outside of building(product El Plastic can be cut flush with exterior wall) HB Sealant:1 Quart Tube ❑ HB Sealant:2 Gallon Pail •Surface mount applications should be attached with a stainless steel or aluminum termination bar. E Primer-SA Water-Based Self-Adhering Flashing Primer(5 gal.pail) U.S.Patent No.6,584,746 Other Patents Pending Flex-Flash®conforms to: NOTE: •ASTM D412-99a •See www.h-b.com for sealant compatibility info. •ASTM D2240-00 •ASTM D624-00 Die C •ASTM G154-00a *Elvaloy®is a registered trademark of the DuPont Company IMPORTANT:Since each construction project is unique,the appropriate selection and use of any •Please refer to Hohmann&Barnard installation product contained herein must be determined by competent architects,engineers and other appropriate professionals who are familiar with the specific requirements of the project in question. instructions for more information. This drawing and/or data sheet is the confidential and proprietary information of Hohmann R. Barnard,Inc.and is not to be reproduced,copied or disclosed,in whole or in part,without the prior written consent of H&B. HOHMANN & BARNARD, Inc. Branch/Subsidiary Locations: ©2013-2016 MiTek® 30 Rasons Court I Hauppauge,NY 11788 ALABAMA-ARIZONA-ILLINOIS CORPORATE HEADQUARTERS MARYLAND-NEW YORK T: 800.645.0616 F: 631.234.0683 PENNSYLVANIA-TEXAS-UTAH www.h-b.com CANADA O • , . A • • SUBMIT" L REVIEW REVIEWED REVISE AND RESUBMIT 0 FURNISH AS CORRE ❑ ubraittal Review is for general conformance with the specifications �u P U N7 .d contract documents Notes or markings shall not be construed - relieving the contractor from compliance with project plans and pecificationa Contractor shall be solely responsible for all etails,quantities,dimensions,fabriation technique of assembly, Tyvek. orkmanship,and safety requirements. 4Araold&AssociatesInc. / 7k ° bhy.:,yy DUPONT1YNF �fp BENEFITS 14 Superior protection from water damage • Helps seal the building envelope when used with DuPont Weatherization Systems products • Meets the AAMA 711-13 material standard at the highest CL classification levels: Class A(no primer)and Level 3 Thermal Exposure (80°C/ 176°F for 7 days) A411F • Meets and Exceeds ASTM E331 Standard Test Method for Water Penetration of Exterior Windows,Skylights, Duie11‘11)-101 —" 1( Doors,and Curtain Walls by Uniform Static Air Pressure `+ Difference: no leakage at 300 Pa(equivalent to 50 mph a�,,,, N� LINT windload),even after thermal aging(0-120°F) r • Does not contain asphaltic/bitumen adhesive materials which many window manufacturers prohibit due to adverse material reactions,such as black staining,oozing, and deformation over time,particularly with vinyl flanges. DuPont'"FlexWrap'°NF addresses the issues of flashing vulnerable bottom corners of the sill where water damage is • Can be installed at external temperatures as low as-4°C most likely to occur. (25°F)as long as the surface is clean and free from frost and ice An integral component of DuPont Weatherization Systems,DuPont" FlexWrap'-NF is a Easy installation conformable,self-adhesive flashing solution for • Packaged in ready-to-use 6",9"x 75 ft rolls sills and non-straight portions of windows, • Helps to facilitate the creation of airtight and water tight doors and other wall penetrations. seals around windows,door sills,chimney breasts,pipe penetrations,and any custom shapes. DuPont—F1exWrap'"NF is a premium performance, extendable self-adhered flashing material that can be Superior durability applied over a wide range of building substances,including • Extendable flashing constructed with a durable,micro- non-nailable sheathing materials like PS foam board, creped DuPont""Tyvek•top-sheet,a premium butyl fiberboard,concrete masonry unit(CMU) and other such adhesive layer,and a specially designed release liner materials.Unlike competitive products,DuPont`" • Designed to withstand up to 270 days of UV exposure F1exWrap"NF does not require the use of mechanical fasteners in the flexed corner areas. Excellent adhesion performance •DuPont''FlexWrap""NF also flashes round-top or 100%butyl adhesive performs through extreme custom-shaped windows in a seamless manner,eliminating temperatures the need to cut and place individual pieces of conventional • Adheres to most common building materials flashing on an arched opening. h C Ci R Mill Certification MTR#. J1-347634 8812 Hwy 79W TX 7548 NUCOR CORPORATION 8/3/2016 JO(903)626-4461 NUCOR STEEL TEXAS Fax:(903)626-6290 Sold To: J&M STEEL CO Ship To J&M STEEL CO PO BOX 164485 3280 CHESSOR BOYER RD FT WORTH,TX 76161-4485 FT WORTH,TX 76106 817)624-2181 (817)624-2181 Fax:(817)625-5346 Customer P.O 64593-S Sales Order 239802.2 Product Group Merchant Bar Quality Part Number 20301118824010W0 Grade NUCOR MULTIGRADE Lot# JW16110569653 Size 3x3x3116 Angle heat# JW16105696 Product 3x3x3/16 Angle 20'NUCOR MULTIGRADE B.L.Number J1-74-3038 Description NUCOR MULTIGRADE Load Number J1-347634 Customer Spec Customer Part# I hereby certify that the material described herein has been manufactured in accordance with the speahcabons and standards iisted above and that it satisfies those+eau lemenis Roll Date:7/27/2016 Melt Date:7/18/2016 Qty Shipped LBS:10,388 Oty Shipped Pcs:140 C Mn P S Si Cu Ni Cr Mo V Cb Sn 0.12% 0.83% 0.010% 0.023% 0.20% 029% 0.13% 0.23% 0.051% 0.0354% 0.001% 0.010% CE4020 CEA529 0.35% 0.38% CE4020:C.E. CSA G4020 AASHTO M270 CEA529:A529 CARBON EQUIVALENT Yield 1:56,900psi Tensile 1:73,200psi Elongation::4% in 8*(%in 203.3mm) Yield 2'55.500psi Tensile 2:71,800psi Elongation 2 Pio in 8'(%in 203.3mm) Specifi63cation Comments:NUCOR MULTIGRADE MEETS THE REQUIREMENTS( 5OF:ASTM A36/A36M-14;A529)/529M-055((200911 AASHTOSt�270/M270M-100 GR36((270(&):A709/709M-10 GR50(345):ASME 3A36/S 3A 6M-07:MEETS REPORTING REQUIREMENTS OF EN50 204 SEC 3.1 Comments'E-mail: websales®nstexas.com 1.All manufacturing processes of the steel,inducing melting,casting¬ rolling,have been performed in U.S.A 2. Mercury in any form has not been used in the production or testing of this product. 3.Welding or weld repair was not perfomed on this material. 4.This material conforms to the specifications described on this document and may not be reproduced,except in full,without written approval of Nucor Corporation. 5.Results reported for ASTM E45(Inclusion content)and ASTM E381(Macro-etch)are provided as interpretation of ASTM procedures. SUBMI AL REVIEW REVIEWED REVISE AND RESUBMIT 0 FURNISH AS CORRECTED ^ REJECTED C Subruttal Review is for general conformance with the specifications and contract document&Notes or markings shall not be construed as relieving the contractor from compliance with project plans and specifications. Contractor shall be solely responsible for all details,quantities,dimensions,fabrication,technique of assembly, workmanship,and safety requirement& Arnold&Associates,Inc. 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O o iv n m m O O -i CO ...1 O A 0 N N rNi N N y S O _ j 3 A x .• ' 03 03 C x co N NN N N r -+ r O J - cn o N 2 o m D - J O CO N J O1 O O N N N 4:n z O �' Oo O J Z Ut A W J Z Q1 al A j o 7 V1 -! D Ni * co41 W * cT N -A a• O o F W 7 o 4 m N N O O N '4 52 0 A X A C t m n O v Z -4 m D EV Z 2 DA m `° O ' y 2 n D o. cr m w n -i N O m mI 0/ a �w m A o O ti 21 . < O N N �O 770 < 3 S 3 a y A 77 77 1 '� sc W j o d to < ▪ r "Cl..) 0 < 19 A d n CI # J .. - a to E 0 cn N jp -c a t . a) m = X A cz CO I m .m r*+ 0 a 'n < o ioD CtncoI dm e U+ y in A W m A CO ID A m N RI A e m m D p n m Oa o 5 a Cr- . co 3. o m 1 1 P`i U C O R Mill Certification MTR#: J1.340140 8812 Hwy 79W NUCOR CORPORATION 5/18/2016 Jewett,TX 75846 903 626-4461 NUCOR STEEL TEXAS Fax: 903 626.6290 Sold To: J&M STEEL CO Ship To: J&M STEEL CO PO BOX 164485 3280 CHESSOR BOYER RD FT WORTH,TX 76161-4485 FT WORTH,TX 76106 (817)824-2181 (817)624-2181 • Fax:(817)625-5346 Customer P.O. 64120-S Safes Order 236004.4 Product Group Merchant Bar Quality Part Number 2060C 37524010W0 Grade NUCOR MULTIGRADE Lot# JW1610247751 Size 6x6x3/8 Angle Heat# JW16102477 Product 6x6x3/8 Angle 20'NUCOR MULTIGRADE B.L.Number J1-73 r641 Description NUCOR MULTIGRADE Load Number J1-340140 Customer Spec Customer Part# I hereby certify that the material described herein has been manufactured in accordance with the specifications and standards Gated 35056 and that 4 saesees those repuiaernents Roll Date:4113/2016 Melt Date:4/2/2016 Oty Shipped LBS:5,066 Qty Shipped Pcs:17 C Mn P S Si Cu Ni Cr Mo V Cb Sn 0.13% 0.95% 0.011% 0.024% 0.20% 0.24% 0.13% 0.18% 0.051% 0.0430% 0.002% 0.008% CE4020 CEA529 0.37% 0.40% CE4020:C.E. CSA G4020 AASHTO M270 CEA529'A529 CARBON EQUIVALENT Yield 1:55,200psi Tensile 1:72,900psi Elongation:24% in 8"(%in 203.3mm) Yield 2:55,100psi Tensile 2:73.200psi Elongation 2�4 in 8"(%in 203.3mm) Specification Comments:NUCOR((MULTIGRADE MEETS THE REQUIREMENTS�(( $� OF:ASTM A36/A36M-14;A529/529M-055((2009))y) AASHTOStv(2701M27OM 10-07 GR36(270)&GR500(345);ASME6SA36�/SA36M--074 MEETS REPORTING REQUIREMENTS OF EN5 0104 SEC 3.1 Comments:E-mail: websales@nstexas.com 1.Ali manufacturing processes of the steel,including melting,casting&hot rolling,have been performed in U.S.A 2.Mercury in any form has not been used in the production or testing of this product. 3.Welding or weld repair was not perfomed on this material. 4.This material conforms to the specifications described on this document and may not be reproduced,except in full,without written approval of Nucor Corporation. 5.Results reported for ASTM E45(Inclusion content)and ASTM E381 (Macro-etch)are provided as interpretation of ASTM procedures. 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A i., ,..1 1_It tit ' • . ° > .t. T I I 1 ,,, V J,..-I" I 3 i & S • t--- 'I 1 j .. _ . ., „ t . • , ' _ • . r•41I3,,...,--.;.- _ _ . ; 1 n a i • t _ , . i it i i:" +— ___ 1 ii: si i. , . - • S •- -:, 1 1i 1 i : I t _,..' ® CORPORATE OFF CE /ovtto, o e. To: II Nucor Customers �fMBEa : Re: Z00S Recycled Content of!Nucor Steel i'roducts Nut or( oiporatit n is the nation's ;are:st tees t er. u.1111,! ,,s C. .q nuliion tons of scraps ,s nos ns produ,ts. Nucor uses I.Iee:ric \ii. i'urnace ii Ai-i technology at all c I it.sir.` ,.. tat-Mlle: f \1 s ;ANA: oa-c,snsunsCr ss-rap n; rap aieef aterial as the major feedstock. unlike bi:t,� r b .n ,`Ik•r:tnu3 , 'h.f• u.r rtmLILd lets! 'r•as t it itiattfr leedsitwk. Nucor has prerared the tolltt+cir ,. :, !,.iniafu,n 'ir.p:.:i ulute the re:seled content or prt,ducts none used in"(ireeri liuildinl...apphc:u o-,• .,7 nre .,,.�,,, ... . i 11)' ."k-g:afl; I'ir •nt.,, ai :ipprt s nt.ite and bawd un the'ot:il ssCivi ;\rodat.tN ( aisMatiom are based ii!. .7,')Ofi serap r, p steel Jrinrrt:d and finished r-laterai.pr,,! „ Jefi r iJ i i accord ince ‘lith ISO t ii)29 ,(491-) I he :Ale. in the unit:unit: ;a on if' s page gl' JIB r5+a? t :, ., ,c ral or `erar 'c•neraleti:insult:. it is :l\_i,,shite• for in the pei.ifie tacilit), infilrmation on tii l la rf:n�, I,alcs .,1- his anc,..iierlt \lore spt:t:iii, pruduei information ma) he a% from taeiliis .Trevi•etas::, RCCN(led Content I 1 1.1) \ crsl,-n 2 ( re&it 4 i and 42 22008 Recycled Steel Content of Nucor Products (% by Total Weight)0 Product (:roupA>erege TZec dad Content~ \.::.':" Rai p-odtici., j •/".7"0 Beam Products 76.2°0 \ ,_ ' 1'l:ve t'rt Ktut. s t)1 ;o _.._._.._., a V.:. t .lull Ifrt`\l:llt. I -7(1.?CC Total Nucor steel ('ombittedT i 89,7°,4 \ ..:c:,,tl �uusucrai I'rsKlutts t y 7°u \ uicrafi l)t kine — 11--! 7h 100 --- \ ` r fitii din (iiour) 1y ^o _ --� 1 1:111 (r idyl 1 ranini� i 71) 2o0 \act-r I�a.tencr Product, ,' ____.._____....__._._-.222___.�_ _.-_-- -- ._ Li:c`r Vk ter I'rtstlUcls "`__ 2222__- - _ __ . \u:t-r ( t`id I'Imsh �...._-- .. " Regional \la(eriak I 1 1 1) \ :rsion , 2 ( rcdll s I and Nucor tra,ks thl -IL n ,,i scrap shipments to our mills \u:or can appro\:urate the amount of strap evractc'd 'r,''m an:. proit:o sue r eion Nucor oisns steel and stc l products manufacturing, faeilit.w. tnrotiekotil the 1 S that are ++ithi) 5( t) miles of almost an prt+jctI site 1'i ;isc refer to the I ' ' , and contact he specific Nucor represcntathe at the lai ilit+ c irc•c tI+ 0 0 _ _ - -_ CORPORATE OFFICE Bar hili (,roup- Darlington,S( .Norfolk.NF.:Jewett.TX: Pb mouth. I-I: Auburn. \'t: lir!'mdhant. \I Kankakee. IL.Jackson.\IS:Seattle. WA: Marion,OI l:\lcntphis. '\ 20018 Approximate Recycled Steel Content Of All Nucor Bar Mill(:roup l'!oducts( ' iit� ��t t! rap Ioral \110 ,and j Intal Pint-cunsumet tnl 'rc-ti�n,umer .,1,4,.; 71,,,,20,•,!' Other Ir,n 1 nit. ttc; ictii Content \11 2.3%, t 8. /a;r , 13% r I he Auo•r Bar Viii Group produces rebar.angles. flats.rounds arid other miscellaneous sires. 1 he bar mill _rot p uses recycled scrap steel ter 97.�U0 of the feedstock Sheet NlillGroup-- Crauti•rd,t+lie. i`.. Iliekrt.ut yR. lia. '( : liecatur. v: 2(11)8 Approximate Recycled Steel Content Of Nucor Sheet Mill Group Pr ucts('' I'ta!Scrap total tal \Ito 1s arul Total Post(.t.n unae, ;rte re-consumer Steel I. sed Other Iron Inns Recycled Content Re..s 'led Content •:i.,;, • ,,,,....,„ti 85.9% 14.1% 74.9% 1.1% ni: .. , .:.. ',t, 66.4% 33.6% 57.8Y/ 8.6°�a 61.2°., 38.8% 53.2% $.0"t 33.9% 58.4% It3."% 1 he Nucor Sheet Mill(;roup piodnce, hot hand. .old rolled.pickled and ca;sart,:led pr.iuc . NucorSheet rn is use 1 ars inr amounts of recycled materials depending on metallurgic31 product d mands and market conditions. The combined sheet mill total recycled content is approximate!) 7o.20„ Beam Group - ,Jae'. k er. .t Jetta 2008 Approximate Recycled Sled Content of Beam Mill Products _ i ac Ia. ,,t,r s, ,if.' ,q,ti Ailr ,,AllaI.,ta; Post('r'ItsuntCl .,C!Pic-.:onsume! \tee: .<d tither Iron I nit, Rrt Jed( ontcnt k:. .ctcci( .narnt \11‘..o, l�auiat.t tee;. - f31 diel illi'. :\K 91.2",. 8.8% ?9.3% 11.8"/0 l\twin iierkelo. ttu:ri. tit 61.2% ANA% 53.1" - t)";. \ r.or i;cr , :; ,,,, rrodic • aarntu till 0,ide flange strtictutal Kearns. \uc<x l:u?iatrr gapntsituatcic i I°°.'cr-ar+ •;eel titr their feedstock. Nucor Steel lierkeles uses a hr her p rcent:ke of-nor'-soap iton due 'o metall rrgicai product demands for-heel steel produced using: the same VA rite combined beam :ii:':! -,..i• :lett cone :t is approsintatei, -6.:.'", Plate (;roup - ,:,,.'r.:(', ;‘,...11,,,,i 2008 A 'proximate Recycled Steel Content of Plate Hill Products'' ,tt;t1::/ur ap1otai .\Iios'nil ,1tcr.aI,'tall''''t( �4"." tet t r'rr cort.untc'rSled .ed Other Iron t nit. Rccv..led('ontern r,irled('intent '.9 ° 80.1`I«80.8% 1 1.9"�. , ., •a. :\1 92.9% 10. 12.0% ,. ,. +: hat,:late'tttills prodoeci , ,. u, '111ti1'tlt i iiC. r „,I:_.,J Malt' "\. 1'a.tr 2 of ` ter'' I', r?; _ t. CORPORATE OFFICE i. Vulcraft Group— l torero.St Norton. Ni .13rteham C'ih,L I;C,rapeland, I\. St.Joe, ►ort Payne. Al.:Chemune \1. \ergo Decking,Inc.—t'hocnic,AL; Fontana.( : \iuu><h.C\ li It Joints- f le oar steel ?or nest \uleraft,fu sus is obtained from one of the nine..Nucor bar mills that usi4 Y'700 scrap steel as their teedsteoek. .\ breakdown of he recycled content of Nucor bar mill product:is detailet. zjliose i hat ‘souks mean that tie post and pre coftsunt_r reYyeled content would be approximately $'O and 1 0:speclixedy \utcr rot tacrhtie,may revels e steel from sources outside of Nuetsr that may contain dosser amounts oil reesctetd steel specific Product In is a%ailable tom facility representatises. R', Deck - Steri .or decking produced to \uterali I:tetlnies are typically obtained from one of the burr �`cur sheet mills. :\ breakdown of the recycled content of Nucor sheet mill products is detailed shone. Vulcratl eck product, contain appros'match 70.2°„recycled steel 'That would mean that the post and pre consumer recssato Content wtouid he approx irately 59 ,°"and 8.8°n respeelisety Vero Ikekint.Inc ntay obtain steel tarn sogrces outside et Nucor that may contain Loser amounts of recycled e•ontent:specific product informatior: is asailable porn facility reprcxnt.noses Products Grout,- .,, . . • roup- • Nucor Building(;roup—Swansea,SC: V.Amiss).IN: ?errell, I.\: Brigham( Its. ; I American Buildings( um pans —Eufaula. ,\L;La Crosse.\ -V,Carson City \\, 1,4 Pass. IL: Kirby Building Ssstems —Portland.TN:Gulf States M:utufaciurer Starks tote. \IS: ('H(' Steel ". athrop.CA, • 'tI( ON Steel— )cntor. : \.: Dallas.(;:A • Nucor Fastener--St bac IN • Nucor IA ire Products 1'ennss Is saw— \css Salem.I'\.Nucor Steel Co(tncc ticnt 1\alitnetord.(.1: L MP Steel— \lars sills,\11): • Nucor Cold Finish—Milwaukee, V.I:Darlington, SC: Brigham City. t I. Ao•'''lk NJ ® Nucor Building group i iteludtrtg \ntcrrcan Iiuildtru>('omBuildingpany. Kirby Building Ss.toms,,Gull ull State Manufacturer and("liC Steell Nucor lit.ilding.Group products may contain steel lion)all of the Nue' -:,t null including sheet plate.hat and beam- Ile as erase amount.,t ryes sled steel used in Nucor Huildin_: (4•al'Tr::af:.,t, Is approxunateis N9 7..„ ghat ysouid mean that the post and pre consumer reeyeled content would he approximneiy'5 ' and I I I".restscctis:I% Nucor Building(iroup facilities may obtain steel from sus outside o )side of Nucor:hat Mai :ontain borer atnounh oo recs.led content. s*ecrfi, l product imtiuzr af;csst is ay aiisusli from facility `t'rtre.entatil eN. 4 \t ( ONS!'ELI: NI. ( ONS(1-.1.1. fight; ui e steel framing products are t)piealh .obt:uneJ from cue- .the flour Nocor shoe:nouns .break!overt of the rs :y ell d content or\uwo:-sheet mill products us detailed alloy Ni ('t)\ products contain approximately 7u.2°°recycled steel That would mean that the post ane: pre consume recy crest content Si mid he asproxirnatets 50.2°.and 8.8°°respeciisel) Nucor f*stetter Steri t.tt fasteners is typically obtained from Nucor bar mills that use scrap steel as heir feedstock Some fasteners may contain high percentages of alloy,that may reduce the total recycled c''nterit of the rtKduct ,ut Naso- Fastcnct products ty pically contain 97 7",recycle.(}materials.That scouid near if it the post :Ind NC nsumer rccy sled content would be appros'match 85 and I +°o respectively. Nucor\\ire Products Pennsy Is anis, Nucor( unnec•ticut.1.\IP Steel - Steel to' wire is typically o'. -Med from a Nucor^.sr until that uses .crap:,s the feedstock. \user wire products contain')77.',°recy eked steel. I h t would mean that the post and pre consumer recycled content would he appr,oyiroately 85O.and i respectr •1) Nucor cold Finis}: Steel processed at!swot Cold Finish is typicalh, obtained from N..icor bar mr 1s I he Nueot Cold t inish is os er 07 ,°,>rccy elect steel.'That would mean that the post and pre consumer recycled so tent would be approximate y Ry"„and 13'.respectiscly. Nucor Cold I-inish facilities may obtain,ter: from sours: s outside of ear:ha' r.)au ,main Iola er arnounts of recycled cunfent Specific product intormatioe is a'.atial+ie I. urn facility tprescniati♦es. \Lich:T oni': mlunna:icnu is auarlahle online throuc h the Steel 1(ecycling Institute at . Page 3 iii a . latmintit CMC Steei Alabama To Whom It May Concern CMC Steei Alabama, in Birmingham. Alabama uses scrap steel as its primary raw material in melting steel. It is 100% domestic. recycled material. Due to cur methods of purchasing, receiving and moving of scrap into our melt shop, we have no way to know exactly what percentage of a particular heat is made up of post-consumer or post- industrial scrap. However, based on our purchasing records we can say that we use approximately 50% post-consumer scrap and 50% post-industrial scrap over the course of a year. This varies with the availability of the various commodities available for purchase in the Birmingham area. Respectiully. John F. Powell Manager of Customer Services H a So. >%`'St IC-S.50T Stets "haK 2C5 592 Pa/ f3mvgM1r 3523i-$5 Bit wrw,£�4?W r n+rpham.�l 35.1� �a:K15 SW.'4*; t Material Safety Data Sheet 'swear MANt,EACruKF:K: Structural Metals, Inc. DBA CMC Steel Texas Annurss: Y.O.Box 911 Seguin,TX 78156-0911 i'IIONE (830)372-8200 + DA'TF:: February 2006 1 r I. Materia! Identification % CIIIMICALNAME: Non-resulferIzed and Resulferized Carbon and Alloy Steels SYNONYMS: Various steel products such as reinforcing bar(rebar),angles,smooth rounds,square sections,flats,channels,special AT=_shapes,studded AT:steel fence post stock,etc. (-AIt,MICAI.FAMILY: Metal II. Ingredients and Hazards°•` Constituent CASb# o/a OSHA PEL`(mg,m3)ACGIH TI,V-TWAd(rttgirne) Aluminum 7429-90-5 0-<0.1 5 (resp frac) 10(dust) 15(total dust) 5(welding fumes) Boron 7440-42-8 0-<0.0i Not Established Not Established Carbon(in solution with Iron) 7440-44-0 <I 3.5 3.5 Chromium 7440-47-3 0.05-<1.5 0.5(Chromium 11 and III) 0.5(metal and Cr Ill) 1 (metal) 0.05(water-soluble Cr VI) Columbium 0.01 (Insoluble Cr VI) 7440-03-1 0-<0.1 Not Listed Not Listed Copper 7440-50-8 0.01-<1 0.1 (dust and mist) 0.2(fume) Iron 1 (dusts and mists) 1309-37-1 BALANCE 10(oxide dust and fume) 5(oxide dust and fume) Manganese 7439-96-5 0.5-<2 5 0.2 Molybdenum 7439-98-7 0-<0.5 5(soluble compounds) 5(soluble compounds) 15(metal) 10(metal and insoluble) Nickel 7440-02-0 0.05-<0.5 1 1.5(metal) 0.1 (soluble compounds) Phosphorous(yellow) 7723-14-0 0-<0.1 0.1 0.2(Insoluble compounds) Silicon 7440-21-3 05 0-<0.5 ]5 10 Sulfur 7446-04-95 0-<0.5 13sulfur dioxide)) S.24(sulfur dioxide) Tin 7440-31-5 0-<0.1 2(metal) 2 (metal and oxide) 0.1 (organic compounds) 0.1 (organic compounds) 1 ttanium 13463-67-7 0-<0.J 15 10 Vanadium 1314-62-I 0-<0.1 0.1 (pentoxide fume) 0,05(pentoxide dust or fume) Welding fumes NA 0.5(pentoxide dust) NA 5 5 'rotes: ;rr) This listing it a summary of elements used In alloying steel. Various grades of steel will contain different combinations of thesecicmcnts. 'Trace elements may be present In minute amounts. No permissible exposure limits(PELs)or threshold limit values(TLVs)exist for steel. Values shown are applicable to component elements. (ts) CI+emirat Abstract Number (c) Occupational Safety and h ealtlr Administration,Permissible Exposure Limit-time-weighted average that must not be exceeded during any 8-hour work shift of a 4n-hour work week (d) American Conference of Governmental industrial Itygienists,Threshold Limit Value,Time-Weighted Average-the time-we gbtod average concentration for a conventional R-hour workday and a 40-hour workweek,to which Ii Is believed that nearly all workers may he repeatedly exposed.day after day. without adverse effect. le) Non-resuifcrfzrd and Reaulferized Carbon and Alloy Steels contain a toxic chemical or chemicals subject to the reporting requirements of section 313 or Title III of the Superfund Amendments and Reauthorization Act of 1986 and 4D CFR part 372. III. Physical Data -- ROILING PT.At 1 atm.,deg.F: 5420 EvAP.RATE(NAw1): N'A VAPOR PRE\SURF.at(mm Hg): NA VOLATILES,a/o Volume: NA VAPOR DENSITY(Air 1): NA MOLECULAR WT.: NA WATER SOLUBILITY: Insoluble APPEARANCE AND ODOR: Odorless gray solid with metallic SPECIFIC'Cu.Avrry(1120 I): 8.0 cutter. WK., IV. Fire and Explosion Data EXTiNt;ulslnnG MEDIA: NA SPECIAI.FIRE FIGIITINO PROCEDURES: NA UNUSUAL FIRE OR EXPLOSION HAZARDS: NA �t ` t Note: Steel products in the solid state present no fire or explosion hazard. V. Health Hazard Information ROUTE.OF ENTRY-SKIN: No noun/.of ENTRY-INHALATION: Yes(as dust) RoUTF.Or'ENTRY-INGESTION: 1p HI:AI.TII HA/ARDS Acurr:AND CHRONIC: Steel products under normal conditions do not present an Inhalation,ingestion, contact health hazard. I lowevtr,short term exposure to fumes/dust from operations such as burning,welding,sawing,brazing,grinding,etc. ay produce irritation of eyes and respiratory system or metal fume fever. Chronic respirator)effects such as asthma,silicosis,or other pneu oconloses and chronic bronchitis occur among iron and steel Industry workers. EFFECTS OF OVERExPOSURI!: No toxic effects would be expected from Inert solid form. inhalation of metal dust and fumes may result from further processing of the material by the user,particularly during welding,burning,cutting,grinding and machining activities: Excessive exposure to fumes or dust may cause respiratory system irritation or effects such as pneumoconiosis(siderosis). Metal fume fever res Its in the appearance of delayed,flu-like symptoms including dyspnea,coughing,pains in muscles and joints,fever and chills. Exposure to mangan a fumes may adversely affect the reproductive or central nervous system(Amanganistn_)with symptoms such as weakness in lower extremiti ,sleepiness,salivation, nervousness and apathy. Prolonged contact with certain non-metallic surface coating may cause dermatitis. MEDICAL CONDITIONS AGGRAVATED;Chronic diseases or disorders of the respiratory system may be aggravated by duct or fumes. CARCINOGENICITY-NTP: Yes(constituents) ExPI.ANATioN OP CARCINOGENICITY: IARC 1987: Iron and steel founding entails exposures that are carcinogenic to humans. Elevated risk of cancers of the lung,stomach and genito-urinary system have been observed among iron and steel Industry workers. NTT 8`s Annual Report on Carcinogens,1998:Crystalline silica,beryllium,arsenic,nickel,lead acetate and cadmium reasonably anticipated to he human carcinogens. Hexavalent chromium known to be a human carcinogen. Inadequate data available to evaluate the carcinogenicity of chromium and trivalent chromium compounds. FIRST Amu: Eve Contact: Flush well with running water to remove particles;obtain medical attention. Skin Contact:Brush off excess dust;wash area well with soap and water, Inhalation: Remove to fresh air;obtain medical attention. Ingestion: Seek medical attention if large quantities of material have been ingested. VI. Reactivity Data — STABILITY:Stable INCOMPATIBILITY(Materials to Avoid): Reacts with strong acids to produce hydrogen gas. HAZARDOUS DECOMPOSITION PRODUCTS:Hydrogen gas;metallic dust or fumes may be produced during welding,burning,grinding or machining. HAZARDOUS POt.YMER17ATION: Will not occur. CONDITIONS TOAvotn: Exposure to concentrated Inorganic acids and/or hydrogen gas. VII. Spill, Leak and Disposal Procedures ---- SPII.I.s,L)AKs(Steps to be taken): NA WASTE DISPOSAL METHOD: Material should be reclaimed for re-use; follow local,state and federal waste disposal requirements. Vili. Special Protection information RESPIRATORY PROTECTION:During welding,cutting/burning or grinding operations,precautions should be taken to control airborne particles and/or fumes;use general service or nuisance dust respirator of type approved by NIOSH/MSHA. VENTILATION: Local Exhaust: Recommended to control dust,fumes,etc.when grinding,cutting/burning. Mechanical(General): NA PRoTerrtvE CLOVES: Recommended for protection against skin abrasion as required for welding,burning or handling operations. Ever.PROTECTION: Safety glasses with sideshields of type approved by OSHA/MSHA. O Mira Poorernvt.EQu1PMe,rT AND PRECAUTIONS:As required depending on operations and safety codes. IX. Special Precautions and Comments - ;;T TRACE AND HANDLIN{;INFORMATION:General good housekeeping practices ere sufficient. OTIut R PRECAUTIONS: None DOT CLASS: Nonhazardous NUC MATERIAL SAFETY DATA SHEET 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Trade Name: Carbon and Alloy Steels CAS Number: Not applicable Synonyms: Steels Use/Description: Bar and structural steel products. billets (sheet steel for Castrip Nucor Mill Locations 24 Hour Contact-CHEMTREC 1-800-424-9300 Nucor Steel - South Carolina Nucor Steel Kankakee, Inc. Nucor Steel Jackson. Inc Nucorteel--Nebraska 300 Steel Mill Road One Nucor Way 3630 Fourth Street 2911 East Nucor Road Darlington. S C 29540 Bourbonnais. IL 60914 Flowood. MS 39232 NorfolktNebraska 68701 (843(393-5841 (815)939-5541 (601)939-1623 402 ( )644-0200 Nucor Steel- Auburn, Inc Nucor Steel- Utah Nucor Steel Birmingham. Inc Nucor Steel Seattle Inc 25 Quarry Road West Cemetery Road 2301 F L Stlutttesworth Dove 2424 S Andover Auburn, N Y. 13021 Plymouth. Utah 84330 Birmingham.Alabama 35234 Seattle, WA 98106 (315)253-4561 (435)458-2300 (205)250-7400 (206)9033-2222 Nucor Steel - Texas Nucor Steel Marion Inc Nucor Steel-Berkeley Nucor Yamato Steel)Nucor U.S Highway 79 South 912 Cheney Avenue 1455 Hagan Avenue Castro Arkansas. LLC Jewett, Texas 75846 Marton Ohio 43302 Huger, SC 29450 5929 EState Hwy 18 (903)626-4461 (740)383-4011 (843)336-6000 (870)Armor AR 72310 2-5500 Nucor Steel Connecticut. Inc 35 ToeUes Road Nucor Steel Kingman. LLC Wallingford. CT 06492 3000 West Old Highway 66 (203)265-0615 Kingman. AZ 86413 (928) 718-7035 2. COMPOSITION/INFORMATION ON INGREDIENTS Components CAS No. Oo Weight Exposure Limits ACGIH TLV(mg/m') OSHA PEL /mm ' Base Metal. t 9 ) IC Oxide Alluyiny Eleni Iiu Aru"'enu*r•• . t)us' 15 Dust ru"'' 5 Respirable tract-'n A "• .SLi 7440-30-0 c0 9 '5 As 0 5 As Anin,r,ny i As i 7440-38-2 <0C9 U01 As Arson Al; ;:uc,nornn` 3 r 0 01 As Arsenic Beryllium (Bel (440-41-7 0.00 As Be nun= <0 09 M (AlIA 1 Carcinogen t 0002 As Beryllium 2 A5 Berytioim tSTi'. 0 005 A,n Rer4lxrei C.,•ujr r l i Huron B't 7440 428 `i1 9 10 Oxide Dun! 15 Oxide Dust Cs I r<tln <{.d. '440 43 9 0 01 A,Cs v ur'r, r t 0 0,+ a*_rr,yyeni !ie 5 As Cadmium 0 00 Respirable fractiiin 0 0025 As Cadmium(Actical Levels Galr_ium s(1 v Ca. 1305 78 8 - f?xa1i 3uat _ ... 5 0„t;e Just Carbon (C1 7440-44-u • Not FstaDhshe`1 Not Established Page 1 of 8 Carbon and Alloy Steels thille Components CAS No. 4i Weight Exposure Limits ACGIH TLV(mglm') OSHA PEL(rngirn') Chiron nun 7440.4,-.t :;1 1 i 1 Heim {.obaN .,_, 7440.154 •.)0'.w _ - l;ar, Al L 140,:njer p Aetai;`Dust F,,. Corlper iciu 7440-50-8 <0 9 I Dust 1 nus( 112 i-ume 01 Fumc Lead iPb) 7439-92-1 <)05 0 05 Dust Fume 1A3 Carcinogen; 0 05 Dust;Fume MayneSwm ,Mai 7439 95 4 ,._ Not taoi shed Not Established F Manganese iMni 7439-96-5 ti 2-2 '' F inmentai Mn and Inor9 5 Fume(Ceding) Cornrnuuu15 Mcgyhdenum Ak+1 1439-98-7 <0 9 10 .n.4-dut ie Con po;nd`l '5 ,.,M=oOle Carmnoi is Niobium iNbi 7440-03-1 `0'4 Not Established Nickel ,Nii 7440-02-0 <1 0 1 5 Metal 1 Atetaa a 1-+',,,k,h r:,rn.ff,,,fn,l, Nitrogen iN1 7727-37-9 `U' Sunpic Ar;nxxi.art Simple As{;h yxuan P11osur,i'rim P+ 77,i4 -1 ,. <0`) n 1 n,rs;ihrxn:y Selenium ISe,: 7787492 i1 Seiernur' 92Selenium Si,cnn 'Si 7149-21 3 <6 b .. Dus• 15 Dust Sulfur 'SC. '44e 04- <0 y 5 2 self,ri,Inde 13 Sulfur Dioxide 07 13 Sulfur D r,ede i S'El i Tin ,-Set 7440.31-5 <119 7 Me',a' 's-53<And I."r; ur',r 2 1Ia0are 4:1),;X: uts Comiiounas Titanium i Tu 7440-32.6 `t`9 Not Esrahtished Not Established '440-.t3 ' ;r3 xL t,r.npoundan 24 Not Estathshed 10 irs Alu'sl,Compounds as W{STEL) I ® Vanadium v. 7440-62-2 -0 9 0 05 Ox ..t F mu- 0 5 Oxide Dust t Get!, .-) 0t Oxide FumetCedi .i Lint; 2nl 7440 56 9 ;a Dust 5 Oxide Fume 0 0 0 10 5 'rwr'F:in''-' 10 Oxide Dust NOTE No permissible exposure limits(PELT or t',reshold limit values,TLV)exist for steel over an The above I slitig is a summary of elements used in alloying Nucor Steel Products , 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING' WELDING. SAWING. BRAZING GRINDING. ABRASIVE BLASTING, MACHINING AND OTHER PROCESSES MAY CAUSE DUSTS, POTENTIALLY COMBUSTIBLE DUST, AND(OR FUMES TO BE RELEASED MAY BE HARMFUL IF INHALED MAY IRRITATE THE EYES, SKIN, AND RESPIRATORY TRACT MOLTEN MATERIAL MAY CAUSE THERMAL BURNS Potential Health Effects Note: Steel products as sold by Nucordo not present an inhalation, ingestion or skin hazard However, individual customer processes. (such as welding, sawing brazing, grinding, abrasive blasting, and machining) may result in the formation of fumes, dust (combustible or otherwise), and/or particulate that may present a variety of health hazards Molten steel also is hazardous. Eye Contact Dusts or particulates may cause mechanical irritation including pain, tearing, and redness Scratching of the cornea can occur if eye is rubbed. Fumes may be irritating. Contact with the heated material may cause thermal burns Skin Contact Dusts or particulates may cause mechanical irritation due to abrasion Coated steel may cause skin irritation in sensitive individuals (see Section 1€for additional information.)Some components in this Illiee Page 2 of 8 _ . - _ _______ Carbon and Alloy Steels product are capable of causing an allergic reaction. possibly resulting in burning, itching and skin eruptions. Contact with heated material may cause thermal burns. Inhalation Dusts may cause irritation of the nose. throat, and lungs. Excessive inhalation of metallic vmes and dusts may result in metal fume fever, an influenza-like illness. It is characterized by a sweet or metallic taste in the mouth, accompanied by dryness and irritation of the throat, cough, shortness of breath.,pulmonary edema, general malaise. weakness. fatigue. muscle and joint pains. blurred vision. fever arld chills. Typical symptoms last from 12 to 48 hours. Ingestion Not expected to be acutely toxic via ingestion based on the physical and chemical properti of the product. Swallowing of excessive amounts of the dust may cause irritation, nausea. and di rhea. Potential Fire and Explosion Hazards 111111 Under normal conditions, steel products do rot present fire or explosion hazards. and dust enerated by handling steel products is oxidized and not combustible. Processing of steel product by so e individual customers may produce potentially combustible dust that may represent a fire or explosion azard. Chronic or Special Toxic Effects Repeated exposure to fine dusts may inflame the nasal mucosa and cause changes to the ng. In addition, a red-brown pigmentation of the eye and/or skin may occur Welding fumes have been associated with adverse health effects. Contains components th t may cause cancer or reproductive effects- The following components are listed by NTP. OSHA, or IAR as carcinogens: Nickel. chromium (hexavalent). cobalt, lead.cadmium. antimony(trioxide), ars nic. beryllium See Section 1 1.. for additional. specific information on effects noted above. Target Organs Overexposure to specific components of this product that are generated in dusts or fumes v ay cause adverse effects to the following organs or systems eyes, skin, liver. kidney. central nervou system, cardiovascular system respiratory system. Medical Conditions Aggravated by Exposure Diseases of the skin such as eczema may be aggravated by exposure. Also, disorders of t e respiratory system including asthma, bronchitis and emphysema. Long-term inhalation exposure to a ents that cause pneumoconiosis (e.g dust)may act synergistically with inhalation of oxide fumes or dusts this product. 4. FIRST AID MEASURES Eye Contact- In case of overexposure to dusts or fumes. ,mmediately flush eyes with plentf of water for at least 15 minutes occasionally lifting the eye lids. Get medical attention if irritation persists. hermal burns should be treated as medical emergencies. Skin Contact- In case of overexposure to dusts or particulates. wash with soap and pient Of water. Get medical attention if irritation develops or persists. If thermal burn occurs, flush area with co water and get immediate medical attention. Inhalation -In case of overexposure to dusts or fumes. remove to fresh air. Get immediatenedicai attention if symptoms described in this MSDS develop. Ingestion -Not considered an ingestion hazard However, if excessive amounts of dust or.particulates are swallowed, treat symptomatically and supportively. Get medical attention. Notes to Physician - Inhalation of metal fume or metal oxides may produce an acute febrile state, with cough, chills. weakness: and general malaise. nausea. vomiting. muscle cramps. and remarkable leukocytosis. Treatment is symptomatic, and condition is self limited in 24-48 hours. Chronic exposure to dusts may result in pneumoconiosis of mixed type 5. FIRE FIGHTING MEASURES Flash Point (Method) -Not applicable Flammable Limits (% volume in air) - Not applicable Auto ignition Temperature - Not applicable Extinguishing Media -For molten metal, use dry powder or sand For steel dust use or dry sand, water, foam, argon or nitrogen. Special Fire Fighting Procedures -Do not use water on molten metal. Do not use Carbon Dioxide (GO,) Firefighters should not enter confined spaces without wearing NiOSH'MSHA approved positive !111141 pressure breathing apparatus (SCBA)with full face mask and full protective equipment sftwri Page 3 of 8 ____ Carbon and Alloy Steels Unusual Fire or Explosion Hazards - Unusual Fire or Explosion Hazards - Steel produ is do not present fire or explosion hazards under norniai conditions Any non-oxidized fine metal pa. icles/dust generated by grinding. sawing, abrasive blasting. or individual customer processes may pr uce materials that the customer should test for combustibility and other hazards in accordance with appli ble regulations High concentrations of combustible metallic fines in the air may present an ex osion hazard. 6. ACCIDENTAL RELEASE MEASURES Precautions if Material is Spilled or Released - Emergency response is unlikely unless i the form of combustible dust_ Avoid inhalation, eye. or skin contact of dusts by using appropriate prec utions outlined in this MSDS(see section 8) Fine turnings and small chips should be swept or vacuumed nd placed into appropriate disposable containers. Keep fine dust or powder away from sources of ignition. Scrap should be reclaimed for recycling. Prevent materials from entering drains. sewers. or waterways. pecific standards and regulations may be applicable to materials generated by individual custome ,processes. As appropriate, these standards and regulations should be consulted for applicability. Fire and Explosion Hazards Some customer processes may generate combustible dust that may require specific precat4tions when cleaning spills or releases of dust. Environmental Precautions - Some grades of steel may contain reportable quantities of aoying elements See Section 15 for additional information Waste Disposal Methods -Dispose used or unused product in accordance with applicablei Federal, State, and Local regulations Please recycle. 7. HANDLING AND STORAGE Storage Temperatures - Stable under normal temperatures and pressures. Precautions to be Taken in Handling and Storing -Store away from strong oxidizers. Dusts and/or ® powders. atone, or combined with process specific fluids. may form explosive mixtures with air. Applicable Federal, state and local laws and regulations may require testing dust generated from processing of steel products to determine if it represents a fire or explosion hazard and to determine appropriate protection methods. Avoid breathing dusts or fumes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Operations with potential for generating high concentrations of airborne particulates or fumes should be evaluated and controlled as necessary. Eye Protection -Use safety glasses Dust resistant safety goggles are recommended under circumstances where particles could cause mechanical injury such as grinding or cutting. Face shield should be used when welding or cutting. Skin -Appropriate protective gloves should be worn as necessary Good personal hygiene practices should be followed including cleansing exposed skin several times daily with soap and water. and laundering or dry cleaning soiled work clothing. Respiratory Protection -NIOSHtMSHA approved dustifumeimist respirator should be used to avoid excessive exposure. See Section 2 for component material information exposure limits. If such concentrations are sufficiently high that this respirator is inadequate. or high enough to cause oxygen deficiency. use a positive pressure self-contained breathing apparatus (SCBA). Follow all applicable respirator use. fitting, and training standards and regulations. Ventilation - Provide general and/or local exhaust ventilation to control airborne levels of dust or fumes below exposure limits. Exposure Guidelines - No permissible exposure limits(PEL)or threshold limit values(TLV)exist for steel See Section 2 for component materials. Various grades of steel will contain different combinations of these elements Trace elements may also be present in minute amounts 9. PHYSICAL AND CHEMICAL PROPERTIES 444.1, Page 4of8 �} Carbon and Alloy Steels Appearance and Odor—Silver grey to grey black with metallic luster Boiling Point - Not applicable Melting Point -Approximately 280( "F • Specific Gravity (at 15.6°C) - Not applicable Density (at 15.6°C) - Not applicable Vapor Pressure - Nut applicable Vapor Density (air = 1) - Not applicable %Volatile, by Volume - Not applicable Solubility in Water - Insoluble. Evaporation Rate (Butyl Acetate = 1) -Not applicable Other Physical and Chemical Data None 10. STABILITY AND REACTIVITY Stability - Stable Conditions to Avoid -Steel at temperatures above the melting point may liberate fumes c ntaining oxides of iron and alloying elements Avoid generation of airborne fume. Hazardous Polymerization -Will not occur. Incompatibility (Materials to Avoid) -Reacts with strong acids to form hydrogen gas. Do of store near strong oxidizers. Hazardous Decomposition Products - Metallic fumes may be produced during welding, ruing. grinding, and possibly machining or any situation with the potential for thermal decomposition. Refer to ANSI Z49.1 11. TOXICOLOGICAL INFORMATION The primary component of this product is iron Long-term exposure to iron dusts or fumes c{an result in a condition called siderosis which is considered to be a benign pneumoconiosis Symptoms rtiay include chronic bronchitis. emphysema, and shortness of breath upon exertion Penetration of iron iparticles in the 0 skin or eye may cause an exogenous or ocular siderosis which may be characterized by a red-brown pigmentation of the affected area Ingestion overexposures to iron may affect the gastrointestinal, nervous, and hematopoietic system and the liver Iron and steel founding. but not iron or iron oxide, has been listed as potentially carcinogenic by IARC When this product is welded. fumes are generated Welding fumes may be different in composition from the original welding product, with the chief component being ordinary oxides of the metal heino welded. Chronic health effects (including cancer)have been associated with the fumes and dusts of individual component metals (see above). and welding fumes as a general category have been listed by IARC as a carcinogen (Group 2B). There is also limited evidence that welding fumes may cause adverse reproductive and fetal effects. Evidence is stronger where welding materials contain known reproductive toxins, e.g., lead which may be present in the coating material of this product Breathing fumes or dusts of this product may result in metal fume fever, which is an illness produced by inhaling metal oxides. These oxides are produced by heating various metals including cadmium. zinc, magnesium. copper. antimony, nickel, cobalt, manganese. tin. lead beryllium, silver. chromium aluminum. selenium. iron, and arsenic. The most common agents involved are zinc and copper. This product may contain small amounts of manganese. Prolonged exposure to manganese dusts or fumes is associated with "manganism". a Parkinson-like syndrome characterized by a variety of neurological symptoms including muscle spasms, gait disturbances, tremors, and psychoses. This product may contain small amounts of cadmium. Primary target organs for cadmium overexposure are the lung and the kidney. Because of its cumulative nature, chronic cadmium poisoning Can cause serious disease which takes many years to develop and may continue to progress despite cessation of exposure. Progression of the disease may not reflect current exposure conditions. It is also Capable of causing a painful osteomalacia called "Itai-itai" in postmenopausal women, and has caused developmental effects and/or reproductive effects in male arc female animals. Cadmium is a listed carcinogen by N 1 F', OSHA, and IARC (Group 1) Page 5 of 8 Carbon and Alloy Steels This product nray cul tains small amounts of chromium. Prolonged and repeated overexpos're to chromium dusts or fumes may cause skin ulcers, nasal irritation and ulceration, kidney damage and c ricer of the respiratory system. Chromium is skin sensitizer Cancer is generally attributed to the hexa alent (+S)form of chromium which is listed as a carcinogen by NTP and IARC (Group 1). This product may contain small amounts of nickel. Prolonged and repeated contact with ni.kel may cause sensitization dermatitis. Inhalation of nickel compounds has caused lung damage as well a sinus, nasal and lung cancer in laboratory animals, Nickel is a listed carcinogen by NTP and IARC (Gro p 1). This product may contain small amounts of vanadium Adverse effects from dermal. inhale ion or parenteral exposure to various vanadium compounds have been reported. The major targe,for vanadium pentoxide toxicity is the respiratory tract Fumes or dust can cause severe eye and respira'.ry irritation, and systemic effects. Chronic bronchitis, green tongue, conjunctivitis. pharyngitis, rhinitis, rales. chronic productive cough, and tightness of the chest have been reported following overexposure. !Allergic reactions resulting from skin and inhalation exposures have also been reported. A statistical association between vanadium air levels and lung cancer has been suggested. but vanadium currently is not regarded as a human carcinogen This product may contain small amounts of lead Lead can accumulate in the body Consequently, exposure to fumes or dust may produce signs of polyneuritis. diminished vision and peripheral neuropathy, such as tingling and loss of feeling in fingers. arms and legs. Lead is a known reproductive and developmental toxin. It is also associated with central nervous system disorders, anemia, kidney dysfunction and neurobehavioral abnormalities The brain is a major target organ for lead exposure Elemental lead is listed as an IARC 2B carcinogen The product may contain small amounts of copper Copper dust and fumes can irritate the eyes, nose and throat causing coughing. wheezing. nosebleeds, ulcers and metal fume fever Other effects from repeated inhalation of copper fumes include a metallic or sweet taste, and discoloration of skin, teeth or hair Copper also may cause an allergic skin reaction Overexposure to copper can affect the liver. 12. ECOLOGICAL INFORMATION Aquatic Ecotoxicologicat Data - No specific information available on this product. Environmental Fate Data - No specific information available on this product 13. DISPOSAL CONSIDERATIONS Recovery and reuse, rather than disposal. sncou,c lie the ultimate goal of handling efforts. Dispose in accordance with federal, state, and local health and environmental -egulat+ons Prevent materials from entering drains. sewers, or waterways 14. TRANSPORT INFORMATION DOT Proper Shipping Name - Not regulate° DOT Hazard Classification -Not regulated UN/NA Number - Not applicable DOT Packing Group -Not applicable Labeling Requirements -Not applicable Placards - Not applicable DOT Hazardous Substance -Not applicable DOT Marine Pollutant - Not applicable 15. REGULATORY INFORMATION This product is not hazardous undei the criteria of the Federal OSHA Hazard:Communication Standard 29 CFR 1910.1200. However, dusts and fumes from this product may be hazardous. This product is not Page 6 of 8 Carbon and Alloy Steels hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910 1200. However. dusts and fumes from this product may be combustible or hazardous and require protection to comply with --pplicable Federal. state and local laws and regulations. CALIFORNIA PROPOSITION 65 This product contains chemicals (antimony [oxide], arsenic. beryllium, chromium[hexavale tl, cobalt, cadmium, lead, nickel)known to the State of California to cause cancer and chemicals(ca mium, lead) known to the State of California to cause birth defects or other reproductive harm, Regulatory Lists Some components of this product may be specifically listed by individual states; other prod ct-specific health and safety data in other sections of the MSDS may also be applicable for state requi ernents. For details on your regulatory requirements you should contact the appropriate agency in your tate Toxic Substances Control Act(TSCA) Components of this product are listed on the TSCA Inventory Comprehensive Environmental Response, Compensation and Liability Act(CERCLA Steel is not reportable, however, it contains hazardous substances that may be reportable released in pieces with diameters less than or equal to'3 004 inches(RO marked with a Chemical Name Reportable Quantity(In Ibj Ar iLnri ir.y 5000' Arsenic 1' Beryrhum tor Cada 10. Chrorn'urn 5000' Copper 5000• Lead 10' N'r,kel 100' , C Phosphorus 1 Selenium 100' Zine 1000' Superfund Amendments and Reauthorization Act of 1986 (SARA), Title ill SECTION 3111312 HAZARD CATEGORIES. Immediate Health Effect. Delayed Health Effect This product contains the following EPCRA Section 313 chemicals subject to the reporting requirements of section 313 of the Emergency Planning and Community Right—To—Know Act of 1986 (40 CFR 372): SECTION 313 REPORTABLE INGREDIENTS Chemical Name CAS Number Concentration(%by weight) Reportable i No- Less than 1'00 Antimony 7440-36-0 a;9 No- Lest Olen 1% Arsenic 7440-38-2 ;+19 No-Less tqan 0 1% Beryllium 7440-43-9 .;;;< No-Less Cryan 0 1% Cadmium 7440-43-9 '-i:'i?9 No-Less Plan 0.1% Chromium 7440-47-3 f)G'-? '? Yes-Greater'ithan 0 1% Cohan 7440-48-4 La No-Less trwan 0 1% Copper 7440-50-8 <0 9 No- Less-,than 1% Lead 7439-92-- <0 05 No--Less Man 0 1% Manganese 7439-96-0 0 2-2 Yes-Greatkf than 1°4; Nickel 7440-02-U el r) Yes -Greater:2han 9 1°l; Phosphorus 7723-14-0 <0 9 No- Less than 10, Selenium 7782-49-1 <0 9 No--Less than 1'' Vanadium 7440-62-2 <0 9 No-Less than 10'., Zinc 7440-66-6 9-0 10 No-Less than I"k Concentrations based on analytical data and process knowledge of typical products distributed by the facility. Page 7 of 8 Carbon and Alloy Steels 16. OTHER INFORMATION This MSDS covers Nucor product as delivered from the Nucor facility, but does not include hemicals that may be applied by subsequent handlers and/or distributors of this product. This could inclu e a variety of materials including oils. paints, galvanization. etc. that are not included in this MSDS. Addi ovally, specialty orders may require application of coating material not listed in this MSDS. MSDS for any Nucor- applied specialty coating will be provided separately. During welding. precautions should be taken for airborne contaminants that may originate from components of the welding rod. Arc or spark generated when welding or burning could be a source of ignition for conibustible and/or flammable materials. The information in this Material Safety Data Sheet (MSDS)was obtained from sources which we believe are reliable; however, the information is provided without any representation or warranty. expressed or implied, regarding the accuracy or correctness The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge For this and other reasons, we do not assume responsibility arid expressly disclaim liability for loss, damage. or expense arising out of or in any way connected with the handling. storage. use. or disposal of this product Page8of8 SUBMITTAL REVIEW REVIEWED REVISE AND RFS-MIT 0 DPROS O C O FURNISH AS CORRECTED 0 ❑ Submittal Review is for general conforms=with the specifications and contract documents Notes or markings shall not be construed as relieving the contractor from compliance with project plans and Sure K f can °Os Contdimensictorons, shall be sio, responfor all details,quantities,dimensions shall be ole technique of assembly, workmanship,and safety requirements Weather Seal Arnold do Associates, As c By: .` i nue /, PROTECTIVE TREATMENTS Blok-Guard® Contro II & Sure mean®Weather Seal Blok-Guard®&Graffiti • Helps control efflorescence, mildew and other Control II is a clear-drying, water-based silicone moisture-related stains. emulsion for weatherproofing concrete block and • Treated surfaces exhibit excellent surface beading. other porous masonry materials. Blok-Guard®& • Treated surfaces"breathe"-does not trap Graffiti Control II protects interior and exterior moisture. masonry surfaces from graffiti attacks without •Has excellent UV stability. altering the natural appearance. Blok-Guard®&Graffiti Control II also protects lllnitatilrl_ exterior walls exposed to normal weathering. • May darken or enhance the natural color of some Graffiti removal from treated surfaces is fast and surfaces. Always test to ensure desired results. easy using Defacer Eraser®Graffiti Wipe. Blok- • Not suitable for extremely dense or polished Guard®& Graffiti Control II is easy to apply with surfaces. low-pressure spray. • Not appropriate for application to asphaltic or painted surfaces. TYPICAL TECHNICAL DAM • Not suitable for application to synthetic resin r paints, gypsum,plaster or other non-masonry FORM White liquid,slight odor surfaces. •• SPECIFIC GRAVITY 1.00 •Not recommended for below-grade applications. pH not applicable • Will not prevent water penetration through WT/GAL 8.32 lbs structural cracks, defects or open joints. • May be difficult to remove from adjacent surfaces. ACTIVE CONTENT 6% _ Always protect. TOTAL SOLIDS 6%ASTM D 2369 • Not recommended for horizontal surfaces. VOC CONTENT <20 g/L Low Solids Coating REGULATORY COMPLIANCE FLASH POINT >212°F(>100° C) ASTM D 3278 VOC COrtmliance FREEZE POINT 32°F(0° C) Weather Seal Blok-Guard®&Graffiti Control II is SHELF LIFE 1 year in tightly sealed, compliant with the following national, state and unopened container district AIM VOC regulations: ADVANTAGES X US Environmental Protection Agency X California Air Resources Board SCM Districts • Treated surfaces resist penetration of most types of graffiti. X South Coast Air Quality Management District • Low odor. X Maricopa County, AZ • Simplifies graffiti removal. • Effectively protects hard-to-seal surfaces. X Northeast Ozone Transport Commission • Suitable for exterior and interior use. • Controls rainwater penetration through exterior block walls. Product Data Sheet•Page 1 of 4 • Item#40193—061716 • 02016 PROSOCO,Inc. •www.prosoco.com Product Data Sheet Weather Seal Blok-Guard® & Graffiti Control II 0SAFETY INFORMATION Let cleaned surfaces dry completely. Newly constructed surfaces and re-pointed surfaces should Always read full label and SDS for precautionary cure for 28 days before application. Sealant and instructions before use. Use appropriate safety caulking compounds should be in place and cured equipment and job site controls during application before application. and handling. 24-Hour Emergency Information: 1 Surface and Air Temperatures INFOTRAC at 800-535-5053 Best surface and air temperatures are 40-95°F (4-35°C)during use and for 8 hours after. If PREPARATION freezing conditions exist before application, let masonry thaw. Protect people, vehicles,property,plants, windows and all non-masonry surfaces from product, splash, BlokGuard®&Graffiti Control II's water carrier residue, fumes and wind drift. Protect and/or divert may freeze at low temperatures or evaporate in high foot and auto traffic. temperatures. Both conditions impair penetration and results. Surface should be clean, dry and absorbent. If cleaning is necessary, use the appropriate Sure r!1ipment Klean®cleaner. Do not use raw acids. Recommended application is by high volume, low-pressure(<50 psi)spray. Fan spray tips are recommended to avoid atomization of the material. For small scale application, or when spray M Recommended for these substrates. Always test. application is not appropriate, product may be Coverage is in sq.ft./m.per gallon. applied using brush or roller. Contact Customer Substrate Type Use? Coverage Care or your local PROSOCO representative for Burnished yes more information. Architectural Smooth yes 30-100 sq.ft. C Concrete Split-faced yes 3 9 sq.m. Storage and Handling Block Store in a cool, dry place. Always seal container BrickRd yes after dispensing. Do not alter or mix with other yes The yes chemicals. Published shelf life assumes upright Concrete Precast Panels yes 75-175 sq.ft. storage of factory-sealed containers in a dry place. Pavers no 7-16 sq.m. Maintain temperature of 45-100°F(7-38°C). Do not Cast-in-place yes double stack pallets. Dispose of unused product and Brick yes container in accordance with local, state and federal Fired Clay The yes 50-125 sq.ft. ' regulations. Terra Cotta(mgr) yes 5-12 sq.m. Pavers no APPLICATION Marble, Polished no N/A Read"Preparation"and the Safety Data Sheet Travertine, before use. Limestone Unpolished* no N/A ALWAYS TEST a small area of each surface to Polished no N/A confirm suitability, coverage rates and desired Granite - results before starting overall application. Test Unpolished no N/A with the same equipment, recommended surface 100-150 sq.ft. preparation and application procedures planned Sandstone Unpolished yes for general application. 9-14 sq.m. Slate Unpolished no ' N/A Dilution&Mixing May darken or enhance the natural color of some surfaces. Do not dilute or alter. Apply as packaged. *Weather Seal Blok-Guard®&Graffiti Control Ultra or Natural Stone Treatment WB Plus may be more suitable products. Always test to ensure desired results. Coverage estimates depend on surface texture and porosity. C Product Data Sheet•Page 2 of 4•Item#40193-061716 •©2016 PROSOCO, Inc. •www.prosoco.com -ilk Product Data Sheet Weather Seal Blok-Guard® & Graffiti Control II Application Instructions Second Coat/Porous Surfaces Application Lightweight block and porous masonry will need 2 Some surfaces will need an additional coat of coats. See "Second Coat Application." Blok-Guard® &Graffiti Control II for maximum Spray Application protection. Apply the second wet-on-wet coat as 1. Saturate, "wet-on-wet"spraying from the bottom soon as the first application is dry to the touch or up. Avoid excessive overlapping. within one hour. Immediately back roll or brush For textured and porous surfaces, apply enough out runs and drips for a uniform appearance and to material to create 6-8"rundown below the prevent build up. contact point. Allowing more than one hour between coats could NOTA When spray applying to fluted architectural reduce the effectiveness of the second coat or cause block, spray in an"overlapping X pattern" for darkening. complete coverage of recessed surfaces. Drying Time 2. Let first application penetrate masonry surface In normal weather(60-80°F; [16-27°C] 50% for 2 to 3 minutes. humidity), Blok-Guard®&Graffiti Control II dries For textured and porous surfaces, reapply in to the touch in about 1 hour. Drying takes longer at same saturating manner to ensure complete lower temperatures. coverage of recessed surfaces. 3. Immediately brush out runs and drips to prevent Blok-Guard®& Graffiti II Control gains its build up. water-repellency properties in 24 hours. Graffiti resistance properties fully develop in 3 to 5 days, Brush or Roller Application depending upon climate conditions. Protect treated Recommended for small scale application or surfaces from rain for at least 6 hours after when spray application is not appropriate. application. Contact PROSOCO for more information. Saturate uniformly. Let product penetrate for 2-3 minutes. Cleanup Re-saturate. Brush out heavy runs and drips that ! Clean tools, equipment, and over spray with soap don't penetrate. and warm water. Cleanup is more difficult from surfaces hotter than 95°F(35°C). Dense, Smooth Surface Application _ cC 11,095,4{S,' Apply in a single coat using enough to completely wet the surface without creating drips,puddles Remove most types of graffiti with PROSOCO's or rundown. Brush out or back roll all runs and Defacer Eraser®Graffiti Wipe or Enviro mean® drips for uniform appearance. DO NOT OVER SafStrip®. See product literature or call Customer APPLY. Over application may cause unacceptable Care at 800-255-4255. color change. One application is normally enough. Always Test for application rate. RFT PRA(TICFS Apply evenly. Saturate the surface,but do not over apply. Brush out or back roll runs and drips. Surface should be clean, dry and absorbent On dense surfaces, follow the"Dense, Smooth before application. Clean soiled surfaces with the Surface Application"instructions on this page. appropriate Sure Klean®or Enviro Klean®cleaner before application. Call Customer Care toll-free at A second application may be needed on highly 800-255-4255 for recommendations. porous surfaces such as some concrete block. Apply the second coat within one hour or as soon Recommended application for PROSOCO as the first coat is dry to the touch. protective treatments is high volume, low ALWAYS TEST forbest coverage rates and to pressure(<50 psi)spray equipment with a fan-type spray tip and adjustable pressure to confirm results before overall application. Test avoid atomization of the material. For small using the application instructions included herein. scale application, or when spray application Let the test area dry thoroughly before inspection. is not appropriate,brushes or roller may be Never go it alone. If you have problems or used. Contact Customer Care or your local questions, contact your local PROSOCO representative for more information on brush/ distributor or field representative. Or call roller application. PROSOCO technical Customer Care, toll-free at 800-255-4255. _. .�Product Data Sheet•Page 3 of 4 • Item#40193-061716 • ©2016 PROSOCO,Inc. • www.prosoco.com Product Data Sheet Weather Seal Blok-Guard® & Graffiti Control II WARRANTY liability,from whatever source, including liability for incidental, consequential or resultant damages The information and recommendations made are whether due to breach of warranty, negligence or based on our own research and the research of strict liability. This warranty may not be modified others, and are believed to be accurate. However, or extended by representatives of PROSOCO, its no guarantee of their accuracy is made because distributors or dealers. we cannot cover every possible application of our products, nor anticipate every variation CUSTOMER CARE encountered in masonry surfaces,job conditions and methods used. The purchasers shall make Factory personnel are available for product, their own tests to determine the suitability of such environment and job-safety assistance with no products for a particular purpose. obligation. Call 800-255-4255 and ask for Customer PROSOCO, Inc. warrants this product to be free Care-technical support. from defects. Where permitted by law,PROSOCO Factory-trained representatives are established in makes no other warranties with respect to principal cities throughout the continental United this product, express or implied, including States. Call Customer Care at 800-255-4255, or visit without limitation the implied warranties of our web site at www.prosoco.com,for the name of merchantability or fitness for particular purpose. the PROSOCO representative in your area. The purchaser shall be responsible to make his own tests to determine the suitability of this product for his particular purpose.PROSOCO's liability shall be limited in all events to supplying sufficient product to re-treat the specific areas to which defective product has been applied. Acceptance and use of this product absolves PROSOCO from any other Product Data Sheet•Page 4 of 4•Item#40193-061716 • ©2016 PROSOCO,Inc. •www.prosoco.com164. SAFETY DATA SHEET PROSOCO, Inc. PFZOSOCO Issue Date 02-Oct-2014 Revision Date 17-Jul-2015 Version 1.01 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Sure Klean®Weather Seal Blok-Guard®&Graffiti Control II Other means of identification Product Code 40193 Recommended use of the chemical and restrictions on use Recommended Use Restricted to professional users. Uses advised against No information available Details of the supplier of the safety data sheet Manufacturer Address PROSOCO, Inc. 3741 Greenway Circle Lawrence, Kansas 66046 Emergency telephone number 8:00 AM—5:00 PM CST Monday-Friday 785-865-4200 NON-BUSINESS HOURS(INFOTRAC) 800-535-5053 2. HAZARDS IDENTIFICATION Classification Not a dangerous substance or mixture according to the Globally Harmonized System(GHS) Label elements Emergency Overview The product contains no substances which at their given concentration, are considered to be hazardous to health Appearance white Physical state Liquid Odor Slight Hazards not otherwise classified(HNOC) Other Information 3.6%of the mixture consists of ingredient(s)of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight% Trade Secret Water 7732-18-5 60-100 * Silicic acid,diethoxyoctylsilyl trimethylsilyl ester 216689-57-5 1 -5 Triethoxyoctysilane 2943-75-1 1 -5 Page 1 /7 40193 Sure Klean®Weather Seal Blok-Guard®& Revision Date 17-Jul-2015 Graffiti Control II *The exact percentage(concentration)of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures Eye contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash off immediately with plenty of water. Remove contaminated clothing and shoes. If symptoms persist, call a physician. Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. If symptoms persist,call a physician. Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Get medical attention. Most important symptoms and effects,both acute and delayed Symptoms May cause irritation. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the chemical No information available. Protective equipment and precautions for firefighters As in any fire,wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH(approved or equivalent)and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions,protective equipment and emergency procedures Personal precautions Ensure adequate ventilation,especially in confined areas. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Dike far ahead of liquid spill for later disposal. Methods for cleaning up Dam up.Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Page 2/7 40193 Sure Klean®Weather Seal Blok-Guard®& Revision Date 17-Jul-2015 Graffiti Control II Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Conditions for safe storage,including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines This product, as supplied,does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. NIOSH IDLH Immediately Dangerous to Life or Health Other Information Ethyl alcohol is formed upon contact with water or humid air. Provide adequate ventilation to control exposures withinguidelines of OSHA PEL(final rule):TWA 1000 ppm and ACGIH TLV: STEL 1000 ppm.Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA,965 F.2d 962(11th Cir., 1992). Appropriate engineering controls Engineering Controls Ensure adequate ventilation,especially in confined areas. Individual protection measures,such as personal protective equipment Eye/face protection Wear safety glasses with side shields(or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Avoid breathing vapors or mists. Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance white Odor Slight Color white Odor threshold No information available Property Values Remarks •Method pH Not Applicable Not Applicable Melting point/freezing point 0 °C / 32 °F Boiling point/boiling range No information available Flash point > 100 °C / > 212 °F ASTM D 3278 Evaporation rate No information available Flammability(solid,gas) No information available Flammability Limits in Air Upper flammability limits No information available Page 3/7 40193 Sure Klean®Weather Seal Blok-Guard®& Revision Date 17-Jul-2015 Graffiti Control II Lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific Gravity 1.0 Water solubility Soluble in water Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Dynamic viscosity No information available Explosive properties Not Applicable Oxidizing properties Not Applicable 10. STABILITY AND REACTIVITY Reactivity No data available Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials None known based on information supplied. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides(NOx). 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information May cause irritation Inhalation Avoid breathing vapors or mists. Eye contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Ingestion Do not taste or swallow. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Water >90 mUkg (Rat) 7732-18-5 Triethoxyoctysilane =10060 NUkg (Rat) =5910 pUkg (Rabbit) 2943-75-1 Information on toxicological effects Symptoms May cause irritation. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Page 417 40193 Sure Klean®Weather Seal Blok-Guard®& Revision Date 17-Jul-2015 Graffiti Control II Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Reproductive toxicity No information available. STOT-single exposure No information available. STOT-repeated exposure No information available. Aspiration hazard No information available. Numerical measures of toxicity -Product Information Unknown Acute Toxicity 3.6%of the mixture consists of ingredient(s)of unknown toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix(oral) 351924 mg/kg ATEmix(dermal) 206746 mg/kg mg/I 12. ECOLOGICAL INFORMATION Ecotoxicity Persistence and degradability No information available. Bioaccumulation No information available. Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. This product contains one or more substances that are listed with the State of California as a hazardous waste. 14. TRANSPORT INFORMATION DOT Not Regulated for all modes of transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies Page 5/7 40193 Sure Klean®Weather Seal Blok-Guard®& Revision Date 17-Jul-2015 Graffiti Control II Legend: TSCA-United States Toxic Substances Control Act Section 8(b)Inventory DSL/NDSL-Canadian Domestic Substances List/Non-Domestic Substances List US Federal Regulations SARA 313 Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986(SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA(Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act(40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied,does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act(CERCLA)(40 CFR 302)or the Superfund Amendments and Reauthorization Act(SARA)(40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 Methanol-67-56-1 Developmental Ethylbenzene-100-41-4 Carcinogen U.S.State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Xylene X X X 1330-20-7 Ethanol X X X 64-17-5 16. OTHER INFORMATION NFPA Health hazards 1 Flammability 0 Instability 0 Physical and Chemical Properties - HMIS Health hazards 1 Flammability 0 Physical hazards 0 Personal protection X Prepared By Regulatory Department Issue Date 02-Oct-2014 Revision Date 17-Jul-2015 Revision Note SDS sections updated 2311 Disclaimer The information contained on the Material Safety Data Sheet has been compiled from data considered accurate.This data is believed to be reliable,but it must be pointed out that values for certain properties are known to vary from source to source.PROSOCO,Inc.expressly disclaims any warranty express or implied as well as any liability for any injury or loss arising from the use of this information or the materials described.This data is not to be construed as absolutely Page 6/7 40193 Sure Klean®Weather Seal Blok-Guard®& Revision Date 17-Jul-2015 Graffiti Control II complete since additional data may be desirable when particular conditions or circumstances exist.It is the responsibility of the user to determine the best precautions necessary for the safe handling and use of this product for his unique application.This data relates only to the specific material designated and is not to be used in combination with any other material.Many federal and state regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material. It is the purchaser's responsibility to familiarize himself with all applicable regulations. End of Safety Data Sheet Page 7/7 SAFETY DATA SHEET PROSOCO, Inc. PROSOCO Fecha de emision 02-oct.-2014 Fecha de revision 17-jul.-2015 Version 1.01 1. Identificacion de Ia sustancia o la mezcla y de Ia sociedad o Ia empresa Identificador del producto Nombre del producto Sure Klean®Weather Seal Blok-Guard®&Graffiti Control II Otros medios de identificacion Codigo del producto 40193 Uso recomendado de la sustancia y restricciones de uso Uso recomendado Solo para uso de usuarios profesionales. Usos contraindicados No hay informacion disponible Datos del proveedor de la fiche de datos de sequridad Manufacturer Address PROSOCO, Inc. 3741 Greenway Circle Lawrence, Kansas 66046 Telefono de emergencia 8:00 AM—5:00 PM CST Monday-Friday 785-865-4200 NON-BUSINESS HOURS(INFOTRAC) 800-535-5053 2. Identificacion de los peligros Clasificacion No es una sustancia o mezcla peligrosa segun el Sistema Globalmente Armonizado(SGA) Elementos de la etiqueta INFORMACION DE EMERGENCIA El producto no contiene sustancias que, a la concentraciOn especifica, se consideren peligrosas para la salud Aspecto blanco Estado fisico liquid Olor Suave Peliqros no clasificados en otra parte(Peligros n.e.p.) OTRA INFORMACION El 3.6 por ciento de la mezcla consiste en ingrediente(s)de toxicidad desconocida 3. Composicion/informacion sobre los componentes Nombre de Ia sustancia Numero CAS %en peso secreto comercial/industrial Water 7732-18-5 60- 100 Silicic acid, diethoxyoctylsilyl trimethylsilyl ester 216689-57-5 1 -5 * Triethoxyoctysilane 2943-75-1 1 -5 * Pagina 1 /7 40193 Sure Klean®Weather Seal Blok-Guard®& Fecha de revision 17-jul.-2015 Graffiti Control II *The exact percentage(concentration)of composition has been withheld as a trade secret. 4. Primeros auxilios PRIMEROS AUXILIOS contacto con los ojos Lavar a fondo con abundante agua durante al menos 15 minutos,mientras se levantan los parpados inferior y superior.Consultar a un medico. Contacto con la piel Lavar inmediatamente mediante con abundante agua.Quitar la ropa y el calzado contaminados. Si los sintomas persisten,consultar a un medico. inhalacion Trasladar al aire libre.Administrar oxigeno o aplicar respiraci6n artificial si es necesario. Si los sintomas persisten,consultar a un medico. Ingestion NO provocar el vomito. Lavarse la boca con agua y luego beber abundante agua.Consultar a un medico. Principales sintomas v efectos,agudos y retardados Sintomas Puede causar irritaciOn. Indicacion de toda atencion medica v de los tratamientos especiales que deban dispensarse inmediatamente Informacion para el medico Aplicar un tratamiento sintomatico. 5. Medidas de lucha contra incendios Medios adecuados de extincion Utilizar medidas de extinci6n adecuadas para las circunstancias locales y el medio ambiente. Medios no adecuados de Caution: Use of water spray when fighting fire may be inefficient. extincion Peligros especificos del producto quimico No hay informacion disponible. Equipo de proteccion y precauciones para las personas que combaten incendios Como en cualquier incendio, utilizar un equipo de respiracion aut6nomo con demanda de presi6n, MSHA/NIOSH(aprobado o equivalente)y ropa de protecciOn total. 6. Medidas en caso de liberacion accidental Precauciones personales,equipo de proteccion y procedimientos de emergencia Precauciones personales Asegurese de que la ventilaciOn sea adecuada,en especial en areas confinadas. Precauciones para la protecci6n del medio ambientes Precauciones para la proteccion del Vease la Secci6n 12 para ver la InformaciOn EcolOgica adicional. medio ambientes Metodos y material de contencion y de limpieza Metodos de contencion Evitar fugas o derrames adicionales si no hay peligro en hacerlo.Construir un dique por delante y alejado del vertido de liquido para la posterior eliminaciOn del material. Metodos de limpieza Hacer un dique de contenciOn.Absorber con un material inerte absorbente. Recoger y Pagina 2/7 40193 Sure Klean®Weather Seal Blok-Guard®& Fecha de revision 17-jul.-2015 Graffiti Control II transferir a recipientes debidamente etiquetados. Limpiar bien la superficie contaminada. 7. MANIPULACION Y ALMACENAMIENTO Precauciones para una manipulacion segura Recomendaciones para Ia Manipular de acuerdo con las buenas practices de higiene y seguridad industrial. manipulacion segura Condiciones de almacenamiento seguro,incluidas posibles incompatibilidades Condiciones de almacenamiento Mantener los recipientes hermeticamente cerrados en un lugar seco, fresco y bien ventilado. Materiales incompatibles No se conocen de acuerdo con la informaci6n suministrada. 8. CONTROLES DE LA EXPOSICION/PROTECCION PERSONAL Parametros de control Directrices sobre exposicion Este producto, segun se suministra,no contiene materiales peligrosos con limites de exposiciOn ocupacional establecidos por los organismos reguladores especificos de la region. NIOSH IDLH Inmediatamente peligroso para la vida o la salud(IPVS) OTRA INFORMACION Ethyl alcohol is formed upon contact with water or humid air. Provide adequate ventilation to control exposures withinguidelines of OSHA PEL(final rule):TWA 1000 ppm and ACGIH TLV: STEL 1000 ppm. Limites derogados por decision del Tribunal de Apelaciones en AFL-CIO contra OSHA, 965 F.2d 962(11a Cir., 1992). Controles tecnicos apropiados Controles de ingenieria Asegurese de que la ventilaciOn sea adecuada,en especial en areas confinadas. Medidas de proteccion individual,tales como equipos de proteccion personal Proteccion para Ia cara y los Utilizer lentes o gafas de seguridad con protecci6n lateral. ojos Proteccion de la piel y el cuerpo Llevar guantes de protecci6n y ropa protectora. Proteccion respiratoria Si se exceden los limites de exposici6n o se observe irritaciOn, usar protecci6n respiratoria aprobada por NIOSH/MSHA. Es posible que se requieran respiradores con suministro de aire operados mediante presiOn positive en vaso de altas concentraciones del contaminante en el aire. La protecci6n respiratoria debe estar en conformidad con la normative local actual. Consideraciones generales de Evitar respirar vapores o nieblas. Manipular de acuerdo con las buenas practices de higiene higiene y seguridad industrial. 9. Propriedades fisicas y quimicas Informacion sobre propiedades fisicas y quimicas basicas Estado fisico liquid Aspecto blanco Olor Suave color blanco umbra)olfativo No hay informaci&n disponible Pagina 3/7 40193 Sure Klean®Weather Seal Blok-Guard®& Fecha de revision 17-jul.-2015 Graffiti Control II Propiedad Valores Observaciones •Metodo pH no aplicable no aplicable Punto de fusion/punto de 0 °C / 32 °F congelacion Boiling point/boiling range No hay informacion disponible Punto de inflamacion > 100 °C / > 212 °F ASTM D 3278 Tasa de evaporacion No hay informaciOn disponible Inflamabilidad(solido,gas) No hay informacion disponible Limites de Inflamabilidad en el Aire Limites superiores de No hay informacion disponible inflamabilidad Limite inferior de inflamabilidad No hay informacion disponible Presion de vapor No hay informaciOn disponible densidad de vapor No hay informacion disponible gravedad especificas 1.0 Solubilidad en agua Soluble en agua Solubilidad en otros solventes No hay information disponible Coeficiente de reparto No hay informaci6n disponible Temperatura de autoinflamacion No hay informaciOn disponible Temperatura de descomposicion No hay informacion disponible Viscosidad cinematica No hay informaci&n disponible Viscosidad dinamica No hay informacion disponible Propiedades explosivas no aplicable Propiedades comburentes no aplicable 10. Estabilidad y reactividad Reactividad No hay datos disponibles Estabilidad quimica Estable en las condiciones recomendadas de almacenamiento. Posibilidad de reacciones peligrosas Ninguno durante el procesado normal. Condiciones clue deben evitarse Temperaturas extremes y luz solar directa. Materiales incompatibles No se conocen de acuerdo con la informaciOn suministrada. Productos de descomposicion peligrosos Oxidos de carbono. Oxidos de nitrogeno(NOx). 11. Informacion toxicologica informacion sobre posibles vias de exposicion informacion del producto Puede causer irritaci6n inhalacion Evitar respirar vapores o nieblas. contacto con los ojos Evitese el contacto con los ojos. Contacto con la piel Evitese el contacto con la piel. Ingestion NO probar ni tragar. informacion sobre los componentes Nombre de la sustancia DL50,oral DL50,dormice CL50,inhalacidn Water >90 mUkg (Rat) Pagina 4/7 40193 Sure Klean®Weather Seal Blok-Guard®& Fecha de revision 17-jul.-2015 Graffiti Control II 7732-18-5 Triethoxyoctysilane =10060 NUkg (Rat) =5910 NUkg (Rabbit) 2943-75-1 Informacion sobre los efectos toxicologicos Sintomas Puede causar irritacion. Efectos retardados e inmediatos,asi como efectos cronicos producidos por una exposicion a corto y largo plazo sensibilizacion No hay informaciOn disponible. Mutagenicidad en celulas No hay informaciOn disponible. germinales carcinogenicidad Este producto no contiene ninguna sustancia carcinogena ni posiblemente carcinogena, segun las listas de OSHA, ARC o NTP. toxicidad para la reproduccion No hay informaciOn disponible. STOT-exposicion Unica No hay informaciOn disponible. STOT-exposicion repetida No hay informaciOn disponible. Peligro de aspiraciOn No hay informaciOn disponible. Medidas numericas de toxicidad -Informacion del producto Toxicidad aguda desconocida El 3.6 por Ciento de la mezcla consiste en ingrediente(s)de toxicidad desconocida Los siguientes valores se calculan en funcion del capitulo 3.1 del documento del SGA Estimacion de toxicidad aguda 351924 mg/kg de la mezcla(ETAmezcla)(oral) Estimacion de toxicidad aguda 206746 mg/kg mg/I de la mezcla(ETAmezcla) (cutaneo) 12. Informacion Ecologica Ecotoxicidad Persistencia v degradabilidad No hay informaciOn disponible. Bioacumulacion No hay informaciOn disponible. Otros efectos adversos No hay informaciOn disponible 13. CONSIDERACIONES RELATIVAS A LA ELIMINACION Metodos para el tratamiento de residuos Eliminacion de residuos La eliminacion se debe realizar de acuerdo con las leyes y regulaciones regionales, nacionales y locales correspondientes. Embalaje contaminado No reutilizar el recipiente. Este producto contiene una o mas sustancias listadas por el Estado de California como residuos peligrosos. 14. INFORMACION RELATIVA AL TRANSPORTE Pagina 5/7 40193 Sure Klean®Weather Seal Blok-Guard®& Fecha de revision 17-jul.-2015 Graffiti Control II DOT Not Regulated for all modes of transportation. 15. INFORMACION REGLAMENTARIA Inventarios Internacionales TSCA Cumple/Es conforme con DSL/NDSL Cumple/Es conforme con Leyenda: TSCA-Estados Unidos-Ley del Control de Sustancias Toxicas, Seccion 8(b),lnventario DSL/NDSL-Lista de Sustancias Nacionales y Lista de Sustancias no Nacionales de Canada Regulaciones federales de los EE. UU SARA 313 Seccibn 313 del Titulo III de la Ley de Enmiendas y Reautorizacion del Superfondo de 1986(SARA). Este producto no contiene sustancias quimicas sujetas a los requisitos de notificacion de la Ley y del Titulo 40 del Codigo de Regulaciones Federales, Parte 372 Categorias de peliqro de SARA 311/312 Peligro agudo para la salud No Peligro crOnico para la salud: No Peligro de incendio No Peligro de liberacion repentina de presiOn No Peligro de reactividad No CWA(Ley de Aqua Limpia)- Este producto no contiene ninguna sustancia regulada como contaminante de acuerdo con la Ley de Agua Limpia(40 CFR 122.21 y 40 CFR 122.42) CERCLA Este material, tal como se suministra, no contiene sustancias reguladas como peligrosas por la Ley de Responsabilidad, Compensacion y Recuperacidn Ambiental(CERCLA)(40 CFR 302)ni la Ley de Enmiendas y Reautorizaci6n del Superfondo (SARA)(40 CFR 355). Es posible que existan requisitos de informe especificos a nivel local, regional o estatal relacionados con la liberaciOn de este material Regulaciones estatales de los EE. UU Proposicion 65 de California Este producto contiene las siguientes sustancias quimicas incluidas en la Proposicion 65 Nombre de la sustancia Proposicion 65 de California Methanol-67-56-1 Developmental Ethylbenzene-100-41-4 Carcinogen Requlaciones estatales sobre el derecho a saber en los Estados Unidos Nombre de la sustancia Nuevo Jersey Massachusetts Pensilvania Xylene X X X 1330-20-7 Pagina 6/7 40193 Sure Klean®Weather Seal Blok-Guard®& Fecha de revision 17-jul.-2015 Graffiti Control II Ethanol X X X 64-17-5 16. OTRA INFORMACION NFPA Peligros para Ia salud Inflamabilidad 0 Inestabilidad 0 Propiedades fisicas y humana 1 quimicas - HMIS Peligros para la salud Inflamabilidad 0 Peligros fisicos 0 Proteccion personal X humana 1 Preparada por Regulatory Department Fecha de emision 02-oct.-2014 Fecha de revision 17-jul.-2015 Nota de revision Secciones actualizadas de la HDS 2311 Descargo de responsabilidad The information contained on the Material Safety Data Sheet has been compiled from data considered accurate.This data is believed to be reliable,but it must be pointed out that values for certain properties are known to vary from source to source.PROSOCO,Inc.expressly disclaims any warranty express or implied as well as any liability for any injury or loss arising from the use of this information or the materials described.This data is not to be construed as absolutely complete since additional data may be desirable when particular conditions or circumstances exist.It is the responsibility of the user to determine the best precautions necessary for the safe handling and use of this product for his unique application.This data relates only to the specific material designated and is not to be used in combination with any other material.Many federal and state regulations pertain directly or indirectly to the product's end use and disposal of containers and unused material.It is the purchaser's responsibility to familiarize himself with all applicable regulations. r"in de Ia Hoja de t)atos de Seguridad Pagina 7/7 Spectrem 2 Table of Contents 1 Spectrem 2 Color Chart 2 Spectrem 2 Data Sheet 4 Spectrem 2 Precast White SDS 18 Spectrem 2 Rustic Brick SDS 30 Spectrem 2 LEED Information Letter 31 Spectrem 2 Product Certification Letter 33 Spectrem 2 Adhesion and Compatibility 34 Tremco Sealant Maintenance Instructions 35 Tremco Silicone Sealant 36 Tremco Silicone Sealant Adhesion 37 Silicone Sealant Material Warranty SUBMI L REVIEW REVIEWED REVISE AND RESUBMIT 0 FURNISH AS CORRECTED C REJECTED C Subtuttal Review is for general conformance with the specifications and contract documents Notes or markings shall not be construed as relieving the contractor from compliance with project plans and japecnicanona Contractor shall be solely responsible for all 1 tails quantities,dimensions,fabrication,technique of assembly, vrortmanship,and safety requirements Arnold&Associates,Inc. 4 ‘14 < kd/a/i Sueclrem 2 This guide only offers a general representation of standard Colors our color offering. Colors viewed on a computer screen and then printed will vary and will never be a exact representation of the actual pigment. ALUMINUM STONE «' When matching is critical, please refer to our color card or sample color strips. 1111111•11— cam) ANODIZED ALUMINUM O BLACK «__Y BRONZE 11.01111-- CLEAR CLEAR GRAY LIGHT BRONZE LIMESTONE 1 OFF WHITE () PRECAST WHITE CIIMED WHITE 7REi1IOSpectrem® 2 - "" Sin9 p le-Com onent Neutral Cure Silicone Sealant for 2-Sided Commercial Sealants&Waterproofing i 0. Product Description Spectrem®2 is a high-performance,single-component,neutral-cure, 1111 SE WATERPROOFING medium-modulus silicone sealant. & REEANSTOORATION INSTITUTE Basic Uses Issued toy tremcn Incorporated Product: Spectrem 7 Silicone Sealant Spectrem 2 is ideal for a variety of perimeter caulking and glazing applications,including 2-sided structural glazing.Spectrem 2 may be used on C719:Pass V Lxt+53% Comp:-50 substrates such as aluminum,glass,steel,painted metal,plastic,stone, Concrete and brick. Substrate:Lnpnmed glass and anodized aluminum Features and Benefits Validation Date:9'16'13-9/1518 • With medium modulus,can be used as a structural tensile bead and weather sealant. No.92013-52918 Copyr.itt • Offering excellent adhesion to a variety of substrates including glass and SEALANT VALIDATION metal,a single product can be used for a variety of applications on the same job from 2-sided structural glazing to perimeter caulking and joint www.swrionline.org filling. • Resistance to driving rain,ozone,ultraviolet light,and temperature extremes safeguards against water penetration with exceptional Applicable Standards weatherability in all climate zones. Spectrem 2 meets or exceeds the requirements of the following • Wide variety of colors to choose from with custom colors and color specifications: matching also available for a particular project. • ASTM C920 Type S,Grade NS,Class 50,Use NT,M,G,A and 0 • No mixing required,so product is always ready to use for immediate • ASTM C1248 Standard Test Method for Staining of Porous Substrate by application with conventional caulking equipment. Joint Sealants • Greenguard Gold certification ensures safety for use in the most sensitive • ASTM C1184 Standard Specifications for Structural Silicone Sealants indoor environments including hospitals and schools. • U.S.Federal Specification TT-S-001543A(COM-NBS)Class A Availability • CAN/CGSB 19.13-M87 Immediately available from your local Tremco Sales Representative,Tremco • U.S.Federal Specification TT-S-00230C(COM-NBS)Class A,Type II distributor or warehouse. • Black meets all of AAMA 802.3-92(Type I and II),805.2-94(Group C), and 808.3-92 Packaging • Conforms to ASTM C1184 Use G and 0(Aluminum) 1/12-gal(300-mL)cartridges Application 20-oz(600-mL)sausages Spectrem 2 is easy to apply with conventional caulking equipment.Fill joint 2-gal(7.6-L)and 4.5-gal(17-L)pails completely and tool.At 75°F(23.9°C),50%RH,a durable skin will form 55-gal(208.2-L)drums typically within fewer than 10 minutes.Please visit www.tremcosealants.com for complete application instructions. All colors are not available in all package sizes.Contact Tremco Customer Service for more information. Joint Design May be used in any joint designed in accordance with accepted Colors architectural/engineering practices.Joint width should be 4 times anticipated Aluminum Stone,Anodized Aluminum,Black,Bronze,Gray,Limestone,Off movement,but not less than 1/4"(6 mm)wide. White,Precast White,White,Clear and Light Bronze Joint Backing Limitations Closed-cell polyethylene backer rods are preferred as joint backing to control • Do not apply to damp or contaminated surfaces. depth of sealant bead.Where depth of joint will prevent use of joint backing, • Use with adequate ventilation. an adhesive-backed polyethylene tape should be installed to prevent three- • Not intended for continuous water immersion. sided adhesion.Joint backing must be dry at time of sealant application. • Only black silicones are recommended for structural glazing applications. Sealant Dimensions Substrate Preparation For joints 1/4"(6 mm)to 1/2"(13 mm)wide,the width-to-depth ratio should be equal.Joints 1/2"(13 mm)wide or greater should have a depth of 1/2"(13 Surfaces must be sound,clean,and dry.Contact surfaces should be free of mm).Minimum joint size is 1/4"x 1/4"(6 mm x 6 mm). loose dirt,dust,oils,and any other contaminants.Tremco recommends that air temperatures be 40°F(5°C)or above before applying any sealant.If Clean Up colder weather is imminent,please refer to the Tremco Guide for Cold Tooling is recommended immediately after application to ensure firm,intimate Weather Applications at www.tremcosealants.com. contact with the joint interface.Dry tooling is preferred.Cleaning can be www.tremcosealants.com Page 1 of 2 Spectrem®2 Single-Com.,.hent.Neutral-Cure Silicone Sealant for 2-Sided Structural Glazi • accomplished with solvents such as IPA,Xylene,Toluene or MEK while sealant is in an uncured state. Warranty Tremco warrants its Products to be free of defects in materials,but makes no warranty as to appearance or color.Since methods of application and on-site conditions are beyond our control and can affect performance,Tremco makes no other warranty,expressed or implied including warranties of MERCHANTABILITY and FITNESS FOR A PARTICULAR PURPOSE,with respect to Tremco Products.Tremco's sole obligation shall be,at its option, to replace,or refund the purchase price of the quantity of Tremco Products proven to be defective and Tremco shall not be liable for any loss or damage. Please refer to our website at www.tremcosealants.com for the most up-to-date Product Data Sheets NOTE:All Tremco Safety Data Sheets(SDS)are in alignment with the Globally Harmonized System of Classification and Labelling of Chemicals(GHS)requirements TYPICAL PHYSICAL PROPERTIES PROPERTY TEST METHOD TYPICAL VALUES A Supplied. Sag ASTM C639 Sag ASTM D2202 0"to 0.03"(0 mm to 0.1 mm) Tack free time ASTM C679 20 to 40 min Tooling Time Skin Formation 10 to 15 min As Cures:Atter 14 days at 77`F+25`C), 55%RH Cyclic Movement ASTM C719 ±50% Elongation ASTM D412 235 to 260% Hardness(shore A) ASTM C661 37 to 40 Peel Strength ASTM C794 16 to 22 pH(2.81 to 3.86 kN/M) Aluminum and Glass Staining of Porous Substrates White Marble ASTM C1248 No Stain Primed&Unprimed Tear strength,die("C") ASTM D624 35 to 40 pH(6.14 to 7.02 kN/M) Tensile Strength at 100%Elongation ASTM C1135 90 to 100 psi(0.62 to 0.69 MPa) Tensile Strength at Max Elongation ASTM D412 220 to 230 psi(1.52 to 1.59 MPa) As Cured:After 21 days at 77 :25 50%RH Ultimate Elongation ASTM C1135 261% Ultimate Tensile Strength ASTM C1135 123 psi(0.85 MPa) 0816/SPEC2DS-ST EE wuns® 1 rFREO Please refer to our website at www.tremcosealants.com for the most u•to-date Product Data Sheets. ° w Tremco Commercial Sealants &Waterproofing 3735 Green Rd 1451 Jacobson Ave 220 Wicksteed Ave 1445 Rue de Coulomb Beachwood OH 44122 Ashland OH 44805 Toronto ON M4H1G7 Boucherville QC J4B 7L8 216.292.5000/800.321.7906 419.289.2050/800.321.6357 416.421.3300/800.363.3213 514.521.9555 www.tremcosealants.com Page 2 of 2 IRweo Version: 1.0 Revision Date:08/14/2015 SAFETY DATA SHEET 1. Identification Material name: SPECTREM 2 PRECAST WHITE Material: 947811 502 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: EH&S Department Telephone: 216-292-5000 Emergency telephone number: 1-800-424-9300(US); 1-613-996-6666(Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Carcinogenicity Category 1A Unknown toxicity-Health Acute toxicity, oral 50.49% Acute toxicity, dermal 51.58% Acute toxicity, inhalation, vapor 99.47 Acute toxicity, inhalation, dust or mist 99.99 Unknown toxicity-Environment Acute hazards to the aquatic 90.92% environment Chronic hazards to the aquatic 100% environment Label Elements Hazard Symbol: 1.4\> Nssep%," Signal Word: Danger Hazard Statement: May cause cancer. Precautionary Statement: 1/13 800000051882 REMCO Version: 1.0 Revision Date:08/14/2015 C Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Response: If exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not None. result in GHS classification: 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent(%)* Calcium Carbonate 1317-65-3 40-70% (Limestone) Amorphous silica 7631-86-9 3-7% Titanium dioxide 13463-67-7 0.5-1.5% Stearic acid 57-11-4 0.5-1.5% Crystalline Silica(Quartz)/ 14808-60-7 0.1 -1% Silica Sand *All concentrations are percent by weight unless ingredient is a gas.Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Call a POISON CENTER/doctor/.../if you feel unwell. Rinse mouth. Inhalation: Move to fresh air. Skin Contact: Wash skin thoroughly with soap and water. If skin irritation occurs: Get medical advice/attention. Eye contact: Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. Most important symptoms/effects,acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. 2/13 800000051882 TRENCO Version: 1.0 Revision Date:08/14/2015 Suitable (and unsuitable) extinguishing media Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials. media: Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media: Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical: Special protective equipment and precautions for firefighters Special fire fighting No data available. procedures: Special protective equipment Self-contained breathing apparatus and full protective clothing must be for fire-fighters: worn in case of fire. 6. Accidental release measures Personal precautions, No data available. protective equipment and emergency procedures: Methods and material for Collect spillage in containers, seal securely and deliver for disposal containment and cleaning according to local regulations. up: Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling: Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required.Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust. Conditions for safe storage, Store locked up. including any incompatibilities: 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits 3/13 800000051882 REMO Version: 1.0 Revision Date:08/14/2015 C Chemical Identity type Exposure Limit Values Source Calcium Carbonate PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air (Limestone)-Total Contaminants(29 CFR 1910.1000) dust. (02 2006) Calcium Carbonate PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air (Limestone)- Contaminants(29 CFR 1910.1000) Respirable fraction. (02 2006) Amorphous silica TWA 20 millions US.OSHA Table Z-3 (29 CFR of particles 1910.1000)(2000) per cubic foot of air TWA 0.8 mg/m3 US. OSHA Table Z-3(29 CFR 1910.1000)(2000) Titanium dioxide TWA 10 mg/m3 US.ACGIH Threshold Limit Values (2011) Titanium dioxide-Total PEL 15 mg/m3 US. OSHA Table Z-1 Limits for Air dust. Contaminants(29 CFR 1910.1000) (02 2006) Stearic acid TWA 10 mg/m3 US.ACGIH Threshold Limit Values (2011) Crystalline Silica TWA 0.025 US.ACGIH Threshold Limit Values (Quartz)/Silica Sand- mg/m3 (2011) Respirable fraction. Crystalline Silica TWA 2.4 US. OSHA Table Z-3(29 CFR (Quartz)/Silica Sand- millions of 1910.1000)(2000) Respirable. particles per cubic foot of air TWA 0.1 mg/m3 US. OSHA Table Z-3(29 CFR 1910.1000) (2000) Crystalline Silica TWA 0.3 mg/m3 US.OSHA Table Z-3(29 CFR (Quartz)/Silica Sand- 1910.1000) (2000) Total dust. Chemical name type Exposure Limit Values Source Calcium Carbonate STEL 20 mg/m3 Canada. British Columbia OELs. (Limestone) -Total (Occupational Exposure Limits for dust. Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) 4/13 800000051882 1RE,q,lcO Version: 1.0 Revision Date:08/14/2015 Calcium Carbonate TWA 3 mg/m3 Canada. British Columbia OELs. (Limestone) - (Occupational Exposure Limits for Respirable fraction. Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Calcium Carbonate TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of (Limestone) -Total Labor-Regulation Respecting the dust. Quality of the Work Environment) (12 2008) Amorphous silica - TWA 4 mg/m3 Canada. British Columbia OELs. Total (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Amorphous silica - TWA 1.5 mg/m3 Canada. British Columbia OELs. Respirable. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Amorphous silica TWAEV 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)(11 2010) Amorphous silica - TWA 6 mg/m3 Canada. Quebec OELs. (Ministry of Respirable dust. Labor-Regulation Respecting the Quality of the Work Environment) (12 2008) Titanium dioxide - TWA 10 mg/m3 Canada. British Columbia OELs. Total dust. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Titanium dioxide - TWA 3 mg/m3 Canada. British Columbia OELs. Respirable fraction. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Titanium dioxide TWAEV 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Titanium dioxide - TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of Total dust. Labor-Regulation Respecting the Quality of the Work Environment) (12 2008) Crystalline Silica TWA 0.025 Canada. British Columbia OELs. (Quartz)/Silica Sand - mg/m3 (Occupational Exposure Limits for Respirable fraction. Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Crystalline Silica TWAEV 0.10 Canada. Ontario OELs. (Control of (Quartz)/Silica Sand - mg/m3 Exposure to Biological or Chemical Respirable. Agents)(11 2010) Crystalline Silica TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of (Quartz)/Silica Sand - Labor-Regulation Respecting the Respirable dust. Quality of the Work Environment) (12 2008) 5/13 800000051882 IREI71C0 Version: 1.0 Revision Date:08/14/2015 Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required. Controls Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust. Individual protection measures,such as personal protective equipment General information: Use personal protective equipment as required. Eye/face protection: Wear goggles/face shield. Skin Protection Hand Protection: Use suitable protective gloves if risk of skin contact. Other: No data available. Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Hygiene measures: Observe good industrial hygiene practices.Wash hands before breaks and immediately after handling the product. 9. Physical and chemical properties Appearance Physical state: solid Form: Paste Color: White Odor: Mild sharp Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available. Initial boiling point and boiling range: No data available. Flash Point: No data available. Evaporation rate: Slower than Ether Flammability (solid,gas): No Upper/lower limit on flammability or explosive limits Flammability limit-upper(%): No data available. Flammability limit-lower(%): No data available. Explosive limit-upper(%): No data available. Explosive limit-lower(%): No data available. Vapor pressure: No data available. Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.34 Solubility(ies) Solubility in water: Practically Insoluble Solubility(other): No data available. Partition coefficient(n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. 6/13 800000051882 RR1 (0 Version: 1.0 Revision Date:08/14/2015 Viscosity: No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of Hazardous No data available. Reactions: Conditions to Avoid: Avoid heat or contamination. Incompatible Materials: Alcohols. Strong acids.Avoid contact with oxidizing agents(e.g. nitric acid, peroxides and chromates). Strong bases.Water, moisture. Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and Products: other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. Inhalation: In high concentrations,vapors,fumes or mists may irritate nose,throat and mucus membranes. Skin Contact: Causes mild skin irritation. Eye contact: Eye contact is possible and should be avoided. Information on toxicological effects Acute toxicity(list all possible routes of exposure) Oral Product: ATEmix:60,414.02 mg/kg Dermal Product: ATEmix:44,595.07 mg/kg Inhalation Product: No data available. Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: No data available. Serious Eye Damage/Eye Irritation 7/13 800000051882 M it alta Version: 1.0 Revision Date: 08/14/2015 C Product: No data available. Specified substance(s): Amorphous silica in vivo(Rabbit, 24 hrs): Not irritating Titanium dioxide in vivo (Rabbit, 24-72 hrs): Not irritating Stearic acid in vivo (Rabbit, 27-72 hrs): Not irritating Respiratory or Skin Sensitization Product: No data available. Carcinogenicity Product: No data available. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Titanium dioxide Overall evaluation: Possibly carcinogenic to humans. Crystalline Silica Overall evaluation: Carcinogenic to humans. (Quartz)/Silica Sand US. National Toxicology Program(NTP) Report on Carcinogens: Crystalline Silica Known To Be Human Carcinogen. (Quartz)/ Silica Sand US. OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: No data available. Specific Target Organ Toxicity-Single Exposure Product: No data available. Specific Target Organ Toxicity-Repeated Exposure Product: No data available. Aspiration Hazard Product: No data available. 8/13 800000051882 INENCO Version: 1.0 Revision Date: 08/14/2015 Other effects: No data available. 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Titanium dioxide LC 50(Mummichog (Fundulus heteroclitus), 96 h): > 1,000 mg/I Mortality Aquatic Invertebrates Product: No data available. Specified substance(s): Titanium dioxide EC 50(Water flea (Daphnia magna),48 h): > 1,000 mg/I Intoxication Chronic hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Titanium dioxide LC 0 (Coregonus autumnalis migratorius G., 30 d): 3 mg/I experimental result Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: No data available. BOD/COD Ratio Product: No data available. Bioaccumulative Potential Bioconcentration Factor(BCF) Product: No data available. Partition Coefficient n-octanol/water(log Kow) Product: No data available. 9/13 800000051882 TR ,� CO Version: 1.0 Revision Date:08/14/2015 C Specified substance(s): Stearic acid Log Kow: 8.23 Mobility in Soil: No data available. Other Adverse Effects: No data available. 13. Disposal considerations Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14.Transport information TDG: Not Regulated CFR/DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b)Export Notification(40 CFR 707,Subpt.D) None present or none present in regulated quantities. US.OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) None present or none present in regulated quantities. CERCLA Hazardous Substance List(40 CFR 302.4): Chemical Identity Reportable quantity Methanol 5000 lbs. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Delayed (Chronic) Health Hazard SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. 10/13 800000051882 TR NCO Version: 1.0 Revision Date: 08/14/2015 0 SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Methanol 5000 lbs. Copper phthalocyanine SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Calcium Carbonate 500 lbs (Limestone) Amorphous silica 500 lbs Titanium dioxide 500 lbs Stearic acid 500 lbs Crystalline Silica(Quartz)/ 500 lbs Silica Sand SARA 313(TRI Reporting) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances(40 CFR 117.3) None present or none present in regulated quantities. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention(40 CFR 68.130): None present or none present in regulated quantities. US State Regulations US.California Proposition 65 This product contains chemical(s)known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. US.New Jersey Worker and Community Right-to-Know Act Chemical Identity Calcium Carbonate(Limestone) Amorphous silica US.Massachusetts RTK-Substance List Chemical Identity Calcium Carbonate(Limestone) Amorphous silica Crystalline Silica(Quartz)/Silica Sand US. Pennsylvania RTK-Hazardous Substances Chemical Identity Calcium Carbonate(Limestone) Amorphous silica US.Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. Other Regulations: Regulatory VOC(less water 8 g/I and exempt solvent): VOC Method 310: 0.61 % Inventory Status: 11/13 800000051882 TRENCO Version: 1.0 Revision Date:08/14/2015 Australia AICS: All components in this product are listed on or exempt from the Inventory. Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory. Japan (ENCS) List: One or more components in this product are not listed on or exempt from the Inventory. China Inv. Existing Chemical Substances: All components in this product are listed on or exempt from the Inventory. Korea Existing Chemicals Inv. (KECI): All components in this product are listed on or exempt from the Inventory. Canada NDSL Inventory: One or more components in this product are not listed on or exempt from the Inventory. Philippines PICCS: All components in this product are listed on or exempt from the Inventory. US TSCA Inventory: All components in this product are listed on or exempt from the Inventory. New Zealand Inventory of Chemicals: All components in this product are listed on or exempt from the Inventory. Japan ISHL Listing: One or more components in this product are not listed on or exempt from the Inventory. Japan Pharmacopoeia Listing: One or more components in this product are not listed on or exempt from the Inventory. 16.Other information, including date of preparation or last revision Revision Date: 08/14/2015 Version#: 1.0 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children.The hazard information herein is offered solely for the consideration of the user,subject to their own investigation of compliance with applicable regulations,including the safe use of the product under every foreseeable condition. 12/13 800000051882 Simco Version: 1.0 Revision Date:08/14/2015 13/13 800000051882 /NERCO Version: 1.0 Revision Date:08/14/2015 SAFETY DATA SHEET 1. Identification Material name: SPECTREM 2 RUSTIC BRICK-30 CTG Material: 947877 502 Recommended use and restriction on use Recommended use: Sealant Restrictions on use: Not known. Manufacturer/Importer/Supplier/Distributor Information Tremco U.S Sealants 3735 Green Road Beachwood OH 44122 US Contact person: EH&S Department Telephone: 216-292-5000 Emergency telephone number: 1-800-424-9300(US); 1-613-996-6666(Canada) 2. Hazard(s) identification Hazard Classification Health Hazards Carcinogenicity Category 1A Unknown toxicity-Health Acute toxicity,oral 50.35% Acute toxicity,dermal 51.8% Acute toxicity, inhalation, vapor 99.47% Acute toxicity, inhalation, dust or mist 100% Unknown toxicity-Environment Acute hazards to the aquatic 91.97% environment Chronic hazards to the aquatic 100% environment Label Elements Hazard Symbol: 4 Signal Word: Danger Hazard Statement: May cause cancer. Precautionary Statement: 1/12 800000051891 rRimeor. Version: 1.0 Revision Date:08/14/2015 C Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use personal protective equipment as required. Response: If exposed or concerned: Get medical advice/attention. Storage: Store locked up. Disposal: Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Other hazards which do not None. result in GHS classification: 3. Composition/information on ingredients Mixtures Chemical Identity CAS number Content in percent(%)* Calcium Carbonate 1317-65-3 40-70% (Limestone) Amorphous silica 7631-86-9 3-7% Iron oxide 1309-37-1 0.5-1.5% Stearic acid 57-11-4 0.5-1.5% Crystalline Silica(Quartz)/ 14808-60-7 0.1 -1% Silica Sand *All concentrations are percent by weight unless ingredient is a gas.Gas concentrations are in percent by volume. 4. First-aid measures Ingestion: Call a POISON CENTER/doctor/.../if you feel unwell. Rinse mouth. Inhalation: Move to fresh air. Skin Contact: Wash skin thoroughly with soap and water. If skin irritation occurs: Get medical advice/attention. Eye contact: Any material that contacts the eye should be washed out immediately with water. If easy to do, remove contact lenses. If eye irritation persists: Get medical advice/attention. Most important symptoms/effects,acute and delayed Symptoms: May cause skin and eye irritation. Indication of immediate medical attention and special treatment needed Treatment: Symptoms may be delayed. 5. Fire-fighting measures General Fire Hazards: No unusual fire or explosion hazards noted. 2/12 800000051891 1IEI,!C0 Version: 1.0 Revision Date:08/14/2015 Suitable (and unsuitable) extinguishing media Suitable extinguishing Use fire-extinguishing media appropriate for surrounding materials. media: Unsuitable extinguishing Do not use water jet as an extinguisher,as this will spread the fire. media: Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical: Special protective equipment and precautions for firefighters Special fire fighting No data available. procedures: Special protective equipment Self-contained breathing apparatus and full protective clothing must be for fire-fighters: worn in case of fire. 6. Accidental release measures Personal precautions, No data available. protective equipment and emergency procedures: Methods and material for Collect spillage in containers, seal securely and deliver for disposal containment and cleaning according to local regulations. up: Notification Procedures: In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations. Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water sources or sewer. Environmental manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling: Do not handle until all safety precautions have been read and understood. Obtain special instructions before use. Use personal protective equipment as required.Ventilate well, avoid breathing vapors. Use approved respirator if air contamination is above accepted level. Use mechanical ventilation in case of handling which causes formation of dust. Conditions for safe storage, Store locked up. including any incompatibilities: 8. Exposure controls/personal protection Control Parameters Occupational Exposure Limits 3/12 800000051891 MEMO® Version: 1.0 Revision Date:08/14/2015 Chemical Identity type Exposure Limit Values Source Calcium Carbonate PEL 15 mg/m3 US.OSHA Table Z-1 Limits for Air (Limestone)-Total Contaminants(29 CFR 1910.1000) dust. (02 2006) Calcium Carbonate PEL 5 mg/m3 US. OSHA Table Z-1 Limits for Air (Limestone)- Contaminants(29 CFR 1910.1000) Respirable fraction. (02 2006) Amorphous silica TWA 20 millions US.OSHA Table Z-3(29 CFR of particles 1910.1000)(2000) per cubic foot of air TWA 0.8 mg/m3 US. OSHA Table Z-3(29 CFR 1910.1000) (2000) Iron oxide-Respirable TWA 5 mg/m3 US.ACGIH Threshold Limit Values fraction. (2011) Iron oxide-Fume. PEL 10 mg/m3 US. OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) (02 2006) Stearic acid TWA 10 mg/m3 US.ACGIH Threshold Limit Values (2011) Crystalline Silica TWA 0.025 US.ACGIH Threshold Limit Values (Quartz)/Silica Sand- mg/m3 (2011) Respirable fraction. Crystalline Silica TWA 2.4 US.OSHA Table Z-3 (29 CFR (Quartz)!Silica Sand- millions of 1910.1000) (2000) Respirable. particles per cubic foot of air TWA 0.1 mg/m3 US.OSHA Table Z-3(29 CFR 1910.1000)(2000) Crystalline Silica TWA 0.3 mg/m3 US. OSHA Table Z-3(29 CFR (Quartz)/Silica Sand- 1910.1000)(2000) Total dust. Chemical name type Exposure Limit Values Source Calcium Carbonate STEL 20 mg/m3 Canada. British Columbia OELs. (Limestone) -Total (Occupational Exposure Limits for dust. Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) TWA 10 mg/m3 Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances,Occupational Health and Safety Regulation 296/97, as amended)(07 2007) 4/12 800000051891 REIJICO Version: 1.0 Revision Date:08/14/2015 Calcium Carbonate TWA 3 mg/m3 Canada. British Columbia OELs. (Limestone) - (Occupational Exposure Limits for Respirable fraction. Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Calcium Carbonate TWA 10 mg/m3 Canada. Quebec OELs. (Ministry of (Limestone) -Total Labor-Regulation Respecting the dust. Quality of the Work Environment) (12 2008) Amorphous silica - TWA 4 mg/m3 Canada. British Columbia OELs. Total (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Amorphous silica - TWA 1.5 mg/m3 Canada. British Columbia OELs. Respirable. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Amorphous silica TWAEV 10 mg/m3 Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) (11 2010) Amorphous silica - TWA 6 mg/m3 Canada. Quebec OELs. (Ministry of Respirable dust. Labor-Regulation Respecting the Quality of the Work Environment) (12 2008) Crystalline Silica TWA 0.025 Canada. British Columbia OELs. (Quartz)/Silica Sand - mg/m3 (Occupational Exposure Limits for Respirable fraction. Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) (07 2007) Crystalline Silica TWAEV 0.10 Canada.Ontario OELs. (Control of (Quartz)/Silica Sand - mg/m3 Exposure to Biological or Chemical Respirable. Agents) (11 2010) Crystalline Silica TWA 0.1 mg/m3 Canada. Quebec OELs. (Ministry of (Quartz)/Silica Sand - Labor-Regulation Respecting the Respirable dust. Quality of the Work Environment) (12 2008) Appropriate Engineering Mechanical ventilation or local exhaust ventilation may be required. Controls Observe good industrial hygiene practices. Observe occupational exposure limits and minimize the risk of inhalation of dust. Individual protection measures,such as personal protective equipment General information: Use personal protective equipment as required. Eye/face protection: Wear goggles/face shield. Skin Protection Hand Protection: Use suitable protective gloves if risk of skin contact. Other: No data available. 5/12 800000051891 TRENCO Version: 1.0 Revision Date:08/14/2015 C Respiratory Protection: In case of inadequate ventilation use suitable respirator. Seek advice from local supervisor. Hygiene measures: Observe good industrial hygiene practices.Wash hands before breaks and immediately after handling the product. 9. Physical and chemical properties Appearance Physical state: solid Form: Paste Color: Red brown Odor: Mild sharp Odor threshold: No data available. pH: No data available. Melting point/freezing point: No data available. Initial boiling point and boiling range: No data available. Flash Point: No data available. Evaporation rate: Slower than Ether Flammability (solid, gas): No Upper/lower limit on flammability or explosive limits Flammability limit-upper(%): No data available. Flammability limit-lower(%): No data available. Explosive limit-upper(%): No data available. Explosive limit-lower(%): No data available. Vapor pressure: No data available. Vapor density: Vapors are heavier than air and may travel along the floor and in the bottom of containers. Relative density: 1.34 Solubility(ies) Solubility in water: Practically Insoluble Solubility (other): No data available. Partition coefficient(n-octanol/water): No data available. Auto-ignition temperature: No data available. Decomposition temperature: No data available. Viscosity: No data available. 10. Stability and reactivity Reactivity: No data available. Chemical Stability: Material is stable under normal conditions. Possibility of Hazardous No data available. Reactions: Conditions to Avoid: Avoid heat or contamination. 6/12 800000051891 MEMO Version: 1.0 Revision Date:08/14/2015 Incompatible Materials: Alcohols. Strong acids.Avoid contact with oxidizing agents(e.g. nitric acid, peroxides and chromates). Strong bases.Water, moisture. Hazardous Decomposition Thermal decomposition or combustion may liberate carbon oxides and Products: other toxic gases or vapors. 11. Toxicological information Information on likely routes of exposure Ingestion: May be ingested by accident. Ingestion may cause irritation and malaise. Inhalation: In high concentrations,vapors,fumes or mists may irritate nose,throat and mucus membranes. Skin Contact: Causes mild skin irritation. Eye contact: Eye contact is possible and should be avoided. Information on toxicological effects Acute toxicity (list all possible routes of exposure) Oral Product: ATEmix:61,165.71 mg/kg Dermal Product: ATEmix:44,812.24 mg/kg Inhalation Product: No data available. Repeated dose toxicity Product: No data available. Skin Corrosion/Irritation Product: No data available. Serious Eye Damage/Eye Irritation Product: No data available. Specified substance(s): Amorphous silica in vivo (Rabbit, 24 hrs): Not irritating Iron oxide in vivo (Rabbit, 1 -72 hrs): Not irritating Stearic acid in vivo (Rabbit, 27-72 hrs): Not irritating Respiratory or Skin Sensitization Product: No data available. Carcinogenicity 7/12 800000051891 TREMCO Version: 1.0 Revision Date: 08/14/2015 C Product: No data available. IARC Monographs on the Evaluation of Carcinogenic Risks to Humans: Crystalline Silica Overall evaluation: Carcinogenic to humans. (Quartz)/Silica Sand US.National Toxicology Program(NTP)Report on Carcinogens: Crystalline Silica Known To Be Human Carcinogen. (Quartz)/ Silica Sand US.OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050): No carcinogenic components identified Germ Cell Mutagenicity In vitro Product: No data available. In vivo Product: No data available. Reproductive toxicity Product: No data available. Specific Target Organ Toxicity-Single Exposure Product: No data available. Specific Target Organ Toxicity-Repeated Exposure Product: No data available. Aspiration Hazard Product: No data available. Other effects: No data available. 12. Ecological information Ecotoxicity: Acute hazards to the aquatic environment: Fish Product: No data available. Aquatic Invertebrates 8/12 800000051891 TREMCO Version: 1.0 Revision Date: 08/14/2015 C Product: No data available. Chronic hazards to the aquatic environment: Fish Product: No data available. Specified substance(s): Iron oxide LOAEL(Pimephales promelas, 33 d): 1.6 mg/I experimental result Aquatic Invertebrates Product: No data available. Toxicity to Aquatic Plants Product: No data available. Persistence and Degradability Biodegradation Product: No data available. BOD/COD Ratio Product: No data available. Bioaccumulative Potential Bioconcentration Factor(BCF) Product: No data available. Partition Coefficient n-octanol/water(log Kow) Product: No data available. Specified substance(s): Stearic acid Log Kow:8.23 Mobility in Soil: No data available. Other Adverse Effects: No data available. 13. Disposal considerations Disposal instructions: Dispose of waste at an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. Contaminated Packaging: No data available. 14. Transport information TDG: Not Regulated 9/12 800000051891 vE IWRE1!1CO Version: 1.0 Revision Date:08/14/2015 CFR/DOT: Not Regulated IMDG: Not Regulated 15. Regulatory information US Federal Regulations TSCA Section 12(b)Export Notification(40 CFR 707,Subpt.D) None present or none present in regulated quantities. US.OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) None present or none present in regulated quantities. CERCLA Hazardous Substance List(40 CFR 302.4): Chemical Identity Reportable quantity Methanol 5000 lbs. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Delayed (Chronic) Health Hazard SARA 302 Extremely Hazardous Substance None present or none present in regulated quantities. SARA 304 Emergency Release Notification Chemical Identity Reportable quantity Methanol 5000 lbs. SARA 311/312 Hazardous Chemical Chemical Identity Threshold Planning Quantity Calcium Carbonate 500 lbs (Limestone) Amorphous silica 500 lbs Iron oxide 500 lbs Stearic acid 500 lbs Crystalline Silica(Quartz)/ 500 lbs Silica Sand SARA 313(TRI Reporting) None present or none present in regulated quantities. Clean Water Act Section 311 Hazardous Substances(40 CFR 117.3) None present or none present in regulated quantities. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention(40 CFR 68.130): None present or none present in regulated quantities. 10/12 800000051891 1WREl!(O Version: 1.0 Revision Date:08/14/2015 US State Regulations US. California Proposition 65 This product contains chemical(s)known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm. US. New Jersey Worker and Community Right-to-Know Act Chemical Identity Calcium Carbonate (Limestone) Amorphous silica US.Massachusetts RTK-Substance List Chemical Identity Calcium Carbonate(Limestone) Amorphous silica Crystalline Silica (Quartz)/Silica Sand US. Pennsylvania RTK-Hazardous Substances Chemical Identity Calcium Carbonate (Limestone) Amorphous silica US.Rhode Island RTK No ingredient regulated by RI Right-to-Know Law present. Other Regulations: Regulatory VOC(less water 8 g/I and exempt solvent): VOC Method 310: 0.61 Inventory Status: Australia AICS: All components in this product are listed on or exempt from the Inventory. Canada DSL Inventory List: All components in this product are listed on or exempt from the Inventory. EINECS, ELINCS or NLP: One or more components in this product are not listed on or exempt from the Inventory. Japan (ENCS)List: One or more components in this product are not listed on or exempt from the Inventory. China Inv. Existing Chemical Substances: All components in this product are listed on or exempt from the Inventory. Korea Existing Chemicals Inv. (KECI): All components in this product are listed on or exempt from the Inventory. Canada NDSL Inventory: One or more components in this product are not listed on or exempt from the Inventory. 11/12 800000051891 ARMCO Version: 1.0 Revision Date:08/14/2015 Philippines PICCS: All components in this product are listed on or exempt from the Inventory. US TSCA Inventory: All components in this product are listed on or exempt from the Inventory. New Zealand Inventory of Chemicals: All components in this product are listed on or exempt from the Inventory. Japan ISHL Listing: One or more components in this product are not listed on or exempt from the Inventory. Japan Pharmacopoeia Listing: One or more components in this product are not listed on or exempt from the Inventory. 16.Other information, including date of preparation or last revision Revision Date: 08/14/2015 Version#: 1.0 Further Information: No data available. Disclaimer: For Industrial Use Only. Keep out of Reach of Children.The hazard information herein is offered solely for the consideration of the user,subject to their own investigation of compliance with applicable regulations, including the safe use of the product under every foreseeable condition. 12/12 800000051891 Tremco incorporated 11114EMCO 3735 Green Road Beachwood.OH 44122 216192.5000 www.tremcosealants.com Commercial Sealants&Waterproofing B L,/eta July 13,2015 ' 1 `J IJ iJ L\ 41EMB� RE: Spectrem 2-Green Building Product Information(LEED®Information) Tremco,as an organization, is committed to quality, responsive to both internal and external customers,our employees,our community and environment,and we will treat all with respect and good stewardship. Tremco Inc.certifies the following information for Spectrem 2 Regional Materials: Spectrem 2 is manufactured in Toronto,Ontario,Canada. No single extracted material is used to produce the majority of this product.Additionally,all raw materials come from one of several sources which in turn come from one of several raw material feed stocks. As such,point source for the raw materials cannot be determined. Recycled Content Information: Recycled content for Spectrem 2 is not available,and for the purposes of LEED reporting should be assumed to be zero. VOC Content Information: Spectrem 2 has a VOC content of 42g/I equaling 3%by weight as applied/mixed. Spectrem 2's VOC values are below limits set by SCAQMD. Additional Information: Note:VOC content values are as reported for the highest VOC content color for all Spectrem 2 colors.Other colors may have a lower VOC content reported on the MSDS. Should you have any questions or require additional information,please do not hesitate to contact Technical Services or your local Tremco Field Representative. Sincerely, r 1100 Amy Woodard Manager Compliance and Regulatory Tremco Incorporated 1REa71(O 3735 Green Road Beachwood.OH 44122 216.292.5000 www.tremcosealants.com Commercial Sealants&Waterproofing We certify that Spectrem°2 has been tested against ASTM C 920, Standard Specification for Elastomeric Joint Sealants and does conform to the specification requirements and is classified as follows: Type: S (Single Component) Grade: NS (Non-sag) Class: 50 (+/- 50%joint movement) Use: NT (Non-traffic) M (Mortar) G (Glass) A (Aluminum) 0 (Other) Spectrem 2 meets and exceeds the requirements of ASTM C 1184, Standard Specification for Structural Silicone Sealants. Silicone sealants are required to meet minimum physical properties which include a Shore A hardness range of 20-60, maximum tack free time of 3 hrs and a minimum tensile value of 50 psi when tested at the following conditions including, standard conditions, 80C(190F), -29 C (-20F)water immersion, and 5000hrs weathering. Spectrem 2 Black is listed to AAMA 800-92, Voluntary Specifications and Test Methods for Sealants, for Section 1.1, Back Bedding Glazing Compounds, 802.3 Types I and II, Section 1.1, Back Bedding Glazing Compounds, 805.2-92 (Group C), and Section 1.4, Exterior Perimeter Sealing Compound, 808.3. Spectrem 2 has been tested and passed ASTM C 1382, "Standard Test Method for Determining Tensile Adhesion Properties of Sealants when used in Exterior Insulation and Finish Systems (EIFS) Joints." Third party verification is available upon request. We further certify that Spectrem 2 conforms to the requirements of the following Federal Specifications: TT-S-00230C (COM-NBS), Type II, Class A Spectrem 2 meets CAN/CGSB-19.13-M87. Spectrem 2 meets the Chinese Specification GB-16776. Spectrem 2 meets the European Organization for Technical Approval (EOTA) specification ETAG-002, Structural Sealant Glazing Systems. Although Spectrem 2 is not NSF registered, or previously authorized by USDA, it does meet the requirements for use in Federally inspected food processing facilities provided it is not used in areas where food is being processed, prepared or packaged. The material must also be applied in a manner which prevents any direct or indirect contamination of food. Additionally, before any food product can be placed in the area of treatment, the sealant must be allowed to cure according to manufacturer's recommendations and the area should be sufficiently free of odor to prevent food contamination. Rev.09/26/14 Spectrem 2 may be used in registered establishments operating under the Canadian Food Inspection Agency. The Canadian Food Inspection Agency has approved Spectrem 2 for use in CFIA regulated facilities for situations involving non food contact. Rev.09/26/14 TREiliC0 Tremco Incorporated 3735 Green Road•Beachwood, Ohio 44122•216-292-5000 Global Sealants Division Integrated Technical Solutions Date: July 30, 2008 To: Distribution From: Rick Fiderius Technical Service Bulletin No. S-08-12 Tremco Spectrem 2 Silicone Sealant Adhesion and Compatibility with Grace Vycor® Plus The purpose of this bulletin is to confirm acceptable application methods for Spectrem 2 neutral cure silicone sealant when used in direct contact with Grace Vycor Plus self-adhering flashing. It is recommended by recognized industry standards AAMA 711 'Voluntary Specification for Self Adhering Flashing Used for Installation of Exterior Wall Fenestration Products' and ASTM E2112 'Standard Practice for Installation of Exterior Windows, Doors and Skylights'that compatibility of dissimilar products intended for use in direct contact, including sealants and flashing, be confirmed prior to use. CONTINUITY OF THE WEATHER BARRIER SYSTEM The air and water seal continuity of the building envelope has become a recognized issue to help assure the hygrothermal performance of a building. The critical interface at a transitional area, where it is essential for unlike building components to meet and seal, has been identified as an area where the long term adhesion and compatibility must ideally perform for the life of the building. To address this issue Tremco has performed adhesion and compatibility testing using accelerated weathering and elevated temperature conditioning to verify and confirm the acceptable use of Spectrem 2 silicone sealant with Grace Vycor Plus self adhering flashing. Adhesion and compatibility of the Spectrem 2 silicone was performed on what would typically be the exposed or facing side of the Grace Vycor Plus. Contact of Spectrem 2 silicone with the adhesive side of the Grace Vycor Plus, while less typical in standard construction practices, has also been tested to confirm compatibility. Incompatibility can occur when the adhesive side of a self adhered flashing is placed in direct contact with a wet sealant, which can result in failure from the softening and liquification of the flashing adhesive. Compatibility of Spectrem 2 sealant with the adhesive side of the flashing was confirmed under recognized test exposure conditions and service temperature classifications for self adhered flashings including 'Level 1' for exposures up to 50°C (122° F;l, and 'Level 2' for exposures up to 65°C (149° F). Application of Spectrem 2 to the facing surface of the Grace Vvcor Plus APPROVED: The adhesion and compatibility of Spectrem 2 is excellent on the facing of Vycor Plus. Prior to application the surface of the Vycor Plus must be clean and dry. Dry wipe the surface prior to sealant application to remove dust or contaminants. No primer is required. Application of Grace Vvcor Plus to Spectrem 2 (Vvcor Plus applied to wet or cured sealant) APPROVED: The Spectrem 2 is fully compatible with the adhesive side of Grace Vycor Plus. Please contact Tremco Technical Service at 866-209-2404 with any questions regarding this bulletin. TREIRCO Tremco Incorporated 3735 Green Road • Beachwood, Ohio 44122 •216-292-5000 Technical Service Bulletin No. S-11-05 Tremco Sealant Maintenance Instructions When installed properly, the chemical composition of a silicone and polyurethane sealants will provide performance for many years with out the need for replacement. However, it may be required to clean or repair the surface due to environmental conditions or mechanical or other damage. The following can be use as a guideline for cleaning and/or repairing the surface of the Tremco sealant. Cleaning If it is necessary to clean the surface of the sealant, the following should be considered: • The sealant and adjacent substrate surfaces can be power washed. • Proper protection of other building components should be considered prior to power washing. • Pressures up to 2000 psi are acceptable. • Allow a minimum of 12" between nozzle and sealant/substrate surface. • Continually move nozzle as to not concentrate on any one area too long. This could cause surface damage of the sealant or substrate. Repairing If it is found necessary to repair the sealant the following should be considered: • Sealant is performing properly, but aesthetically not tooled properly or completely, or slightly damaged on the surface o Clean surface of silicone sealant with isopropyl alcohol and the surface of a urethane sealant with xylene in order to remove any surface contaminants utilizing the two rag wipe method, and allow solvent to dry o Protect adjacent substrate by taping o Apply a thin bead of fresh sealant over the cleaned cured bead o Dry tool the sealant o Remove masking • Sealant is damaged and needs to be removed and replaced o Remove damaged area by cutting out sealant. o If sealant is still well adhered to substrate, it is acceptable to allow existing sealant to remain in joint and simply remove the damaged portion utilizing a v-cut. Follow instructions above to install additional sealant in joint o If adhesion to substrate is unacceptable, mechanically remove existing sealant cleanly from joint. o Clean and prime as deemed appropriate. o Protect adjacent substrate by taping o Apply a thin bead of fresh sealant over the cleaned cured bead o Dry tool the sealant o Remove masking o Check adhesion after sealant has cured (Cure depends on temperature&humidity, a minimum of 14 days is acceptable) Please contact Tremco Technical Service at 866-209-2404 with any questions regarding this bulletin. MAT 01/11 Tremco Incorporated 3735 Green Road • Beachwood, Ohio 44122•216-292-5000 IREI1C0 Global Sealants Division Integrated Technical Solutions Date: February 20, 2009 To: Distribution From: Stu Snell Technical Service Bulletin No. S-08-32 Tremco Structural Silicone Sealants Compliance with ASTM C 1184 The purpose of this bulletin is the confirm that Tremco structural silicone sealants Proglaze II, Proglaze SSG and Spectrem 2 meet the requirements as described in ASTM C 1184 " Standard Specification for Structural Silicone Sealants" This specification describes the properties of cold liquid, single applied or multi-component chemically curing silicone sealants that are to be used to structurally adhere components of a structural sealant glazing systems. Per ASTM C 1184, silicone sealants are required to meet minimum physical properties which include a Shore A hardness range of 20-60, maximum tack free time of 3 hrs and a minimum tensile value of 50 psi when tested at the following conditions including, standard conditions, 80C(190F), -29 C (-20F) water immersion, and 5000hrs weathering. Based on our internal lab and extensive field application testing all three of our silicone sealants meet and exceed these minimum requirements In summary, Proglaze II, Proglaze SSG and Spectrem 2 meet all the minimum physical and rheological properties as listed in this specification Please contact Tremco Technical Service at 866-209-2404 with any questions regarding this bulletin. TREMCO Tremco Incorporated 3735 Green Road • Beachwood, Ohio 44122•216-292-5000 Global Sealants Division Integrated Technical Solutions Date: October 28, 2008 To: Distribution From: Stu Snell Technical Service Bulletin No. S-08-19 Tremco Structural Silicone Sealants Adhesion and Compatibility with Dow Corning Silicone Sealants The objective of this bulletin is to clarify the compatibility and adhesion of Spectrem 2, Tremsil 600 Proglaze SSG and Proglaze II silicone sealants with Dow Corning 795,995,982 and 983 silicone sealants. These Tremco sealants routinely make both direct and indirect contact with the Dow Corning sealants in a variety of glazing applications. The Tremco silicone sealants listed above have been tested and found to be chemically compatible with and developed unprimed adhesion to Dow Corning 795, 995 and Dow Corning 983/982 silicone sealants. Chemical compatibility indicates no adverse chemical interactions when two sealants are in close proximity with each other. There were no such interactions with all sealant combinations tested Testing was carried out in both wet to wet and wet to dry conditions. Assembled samples were cured for 2 weeks at room temperature (77F and 50% relative humidity) and one week of water immersion. The Tremco silicone sealants listed above developed unprimed adhesion to the above listed Dow Corning silicone sealants in all conditions tested. In general all surfaces must be clean and dry prior to sealant application to ensure optimal adhesion. Cured silicone should be cleaned with an approved solvent such as IPA (isopropyl alcohol) prior to sealant application. Please contact Tremco Technical Service at 866-209-2404 with any questions regarding this bulletin. An ripm Cormany Tremco Incorporated 3735 Green Road•Beachwood,Ohio 44122•216-292-5000 www.tremcosealants.com • Warranty No: Commercial Sealants&Waterproofing Today's Date: ******** Exp: **** .*** Silicone Sealant Material Warranty PROJECT APPLICATOR NAME ARCHITECT/ GENERAL ENGINEER CONTRACTOR OWNER DATE OF SUBSTANTIAL COMPLETION PRODUCT(S) TYPE OF WORK Tremco Incorporated (`Tremco")hereby warrants to the Owner,subject to the terms,conditions and limitations stated herein,that the Tremco Sealant specified above is free of manufacturing defects and conforms to published physical properties and quality control standards in force at the time product was purchased and,when installed in accordance with Tremco's written Application Instructions and in applications approved by Tremco as suitable for the Product,will have a useful life under normal service conditions for a period of[#]vear(s)from the date of substantial completion. In the event the Product is proven not to have performed in accordance with the Warranty during the warrant perioi •- •w er shall immediately notify Tremco and confirm such notice in writing within thirty(30)days.Tremco' • responsibil y unde . .my shall be,at its option,either to refund the purchase price of or provide sufficient replaceme mat. ial to replac the •• •nforving product,and such refund or replacement shall constitute the limit of the Co •. s liabi' . d ob'gation.D ri • the t- • this Warranty,agents or employees of Tremco shall be afforded opport itiz to inr)any •.uc area- - ch ti - = remco may reasonably request. Tremco makes no warranty with respect to ap•eara ce • •lor Tremco's obligations under thi•.W rrant .re ex•res y onditi•nei .•in receipt of full payment for the Product and the Owner's compliance wi • -..• of its re•pon i 'lities .-scr•ed i t ' .rranty document.Any delay in full payment to Tremco shall not extend the Warr. y P- •o• No rep : ent. • - •f Tre c• ha he authority to make any representations or provisions except as stated herein.This Warranty is issued to • :•• -n.• ed owner and is transferable with the written consent of Tremco. THE ABOVE WARRANTY IS IN LIEU OF ANY AND ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, INCLUDING ANY WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE OR MERCHANTABILITY, EXCEPT AS EXPRESSLY PROVIDED HEREIN. TREMCO SHALL NOT BE LIABLE FOR DAMAGE TO THE PROJECT STRUCTURE OR INTERIOR CONTENTS OR FOR ANY OTHER CONSEQUENTIAL,SPECIAL OR OTHER DAMAGES ARISING FROM OR RELATED TO, DIRECTLY OR INDIRECTLY,THIS WARRANTY OR THE PERFORMANCE OF THE MATERIALS COVERED BY THIS WARRANTY,WHETHER BASED ON BREACH OF WARRANTY, NEGLIGENCE OR OTHER THEORY OF LIABILITY. TREMCO INCORPORATED Commercial Sealants&Waterproofing Michael J.Soeder,VP Sales,NA TO EXPEDITE PROCESSING,THIS DOCUMENT WILL BE COMPLETED AND DELIVERED IN ELECTRONIC FORM ONLY. AN ELECTRONIC SIGNATURE FROM A TREMCO REPRESENTATIVE ON A COMPLETED WARRANTY DOCUMENT IS VALID AND BINDING AND IS ENFORCEABLE TO THE SAME EXTENT AS A PENNED SIGNATURE. Buildings R; eo, ACRYLITHANETM HS2 0 Acrylic Urethane Catalyzed Coating • Technical Data Coverage 670 sf/gal at 1.5 mils DFT JP Thinner Spray 21092 up to 15% 21093 up to 3% Brush or Roll Not Required Clean Up 21092 PRODUCT DESCRIPTION The technical specifications for this data sheet are based on A high performance, two component coating for use where product 45080 White. appearance,durability,color and gloss retention plus chemical and corrosion resistance are paramount. For use on automo- CURED FILM PERFORMANCE biles,trucks,trailers, railway cars,service stations, bulk tanks or chemical(acid or caustic)trailers. Description Test Method Results Q-UV A 340 ASTM D4587 >90%gloss For best results, use one of the JONES-BLAIRTM engineered (4,000 hrs) retention(60°) systems for a total coating system. color change DE<.5 FEATURES Xenon Arc ASTM G147-96 >95%gloss (1,000 Hrs)quartz retention(60°) borosilicate filters • Excellent color retention EMMAQUA ASTM G90-98 >95%gloss • Solvent resistant 290 MJ/M2 retention(60°) • Chemical resistant Q-Trac ASTM D4141 >90%gloss • Excellent gloss retention 290 MJ/M2 retention(60°) and Chromate free Exterior Exposure ASTM D1014 >90%gloss • Lead • Low andOC 45°South retension,3 Dallas,Texas Years 24 Hour Chemical ASTM 1308 DI Water,10% PRODUCT DATA Resistance H2SO4 10% Exposure NaOH,25% Description Results (No Effect) H3PO4,48% Vehicle Type Acrylic Polyester Urethane HF,Xylene& Colors Available in a variety of colors. j Mineral Spirits Gloss Full Gloss and Semi-Gloss Impact Resistance ASTM D2794 160 F&160 R VOC(mixed) 328 g/I(2.73 lbs/gal) Weight/Gallon(mixed) 11.1 pounds EQUIPMENT RECOMMENDATIONS Solids by Weight(mixed) 76% Solids by Volume(mixed) 63%(Theoretical) Listed below are general equipment guidelines for the applica- Viscosity(mixed) 35"/Zahn 3 tion of this product. Job site conditions may require modifica- Flash Point(white) 102°F tions to these guidelines to achieve the desired results. Dry Heat Resistance 300°F(149°C) Freight Classification See MSDS BRUSH: Use a solvent resistant bristle. Packaging 1 Gallon(mixed unit) ROLLER: Use a 1/4"nap solvent resistant core. APPLICATION DATA SPRAY APPLICATION(General): The following spray equip- ment has been found suitable and is available from menu- Description Results facturers such as Binks, DeVilbiss and Graco. Application Spray,Brush or Roll AIR ATOMIZED SPRAY: Mix Ratio 3:1 by Volume Atomizing Catalyst 99951 or 99961 Model Air Cap Fluid Tip Fluid Delivery Pressure Recommended Thickness 1.5-3.0 mils DFT Pressure Binks#18 63 pb 66 20 oz/min 45-60 psi Dry Time @ 77°F,50%RH DeVilb,ss No Accelerator Spray Brush/Roll Pressure Mec-510 704 tx 20 oz/min 45-60 psi Recoat 4 hours 6 hours AIRLESS SPRAY: Tack Free 6 hours 8 hours Handle 8 hours 12 hours Model Pump Ratio Fluid Tip Fluid Pressure Filter Mesh With.5 fl oz/gal 99041 Graco Bulldog 30:1 .011-.013 1800-2200 100 Recoat 3 hours 4 hours Tack Free 4 hours 7 hours Binks B 8D 35:1 .011-.013 1800-2200 100 Handle 6 hours 11 hours Pot Life @75°F,50%RH GENERAL SURFACE PREPARATION No Accelerator 2X Viscosity 3 hours All surfaces must be sound, dry, clean and free of oil, dirt, Gel Time 12 hours grease, wax, mildew, loose or flaking paint and other surface With.5 fl oz/gal 99041 contaminants. Remove loose,peeling,flaking or scaling paint 2X Viscosity 1.5 hours and rust by scraping, sanding or wire brush or blasting. Gel Time 3.5 hours El LI FPI .sliansv `TO' E 11111 d re- " 11.0:g g 1 :,. 011E,1 cc, 1 A $( ¢1 o °� ad Z 0° For best results, an SSPC-SP-5(NACE 1)near white blast is Clearcoat: 1 dry mil ofACRYLITHANETM HS2 Clear(optional minimum for severe exposure. For moderately severe (non- for ultimate gloss and durability). immersion)exposures an SSPC-SP-6 (NACE 3)commercial blast can be used. SYSTEM-B DIRECTIONS FOR USE For maximum chemical resistance while affording excellent corrosion resistance and durability in non-salt atmospheres. TINTING: May be tinted with HS tint colors only. Recommended for use in inland areas and for resistance to acid and alkali. Sandblasting is recommended. THINNING: See Application Data. National EPA, AIM and VOC compliance levels will not be exceeded with these levels First coat Primer: 3 dry mils of 33010(white)or 33514(gray) of thinner. or 33114(coral)UREPRIME®HS2. Note: Always know local VOC restrictions for coating applica- Topcoat: 3 dry mils of ACRYLITHANET"^ HS2 in the desired tions in your area before thinning this product. Thinning rec- color for the finish coat. ommendations meet Federal VOC restrictions for architectural coatings. This product and other referenced products may Clearcoat: 1 dry mil ofACRYLITHANETM HS2 Clear(optional not meet VOC restrictions for your application and may not be for ultimate gloss and durability). available in your area. Carefully read and observe warning on thinner labels. SYSTEM-C APPLICATION: Mix thoroughly before use. Add 1 quart of Recommended for refurbishing existing equipment and struc- 99951 or 99961 per%gallon unit of HS2 then mix thoroughly tures that have a surface suitable for refinishing by sanding again. Only apply when air and surface temperature are and spot cleanup with hand and power tools. between 40°— 100°F (7°- 38°C) and when the surface tem- perature is at least 5 degrees(F)or 3 degrees(C)above the First coat Primer: 2 dry mils of 33010(white)or 33514 ;gray) dew point. or 33114 (coral) UREPRIME® HS2 (preferred) or 3 mils of 15077 White STANTESTTM Primer or 15632 Gray STAN- DRYING TIME: See Application Data for typical dry times. TESTTM Primer. Low temperature, high humidity, poor ventilation and thick films will retard drying. Accelerator 99041 may be added at Topcoat: 2 dry mils of ACRYLITHANETM HS2 in the desired the rate of up to 0.5 fl oz per mixed gallon of HS2 to reduce color for the finish coat. the drying time. Clearcoat: 1 dry mil ofACRYLITHANETM"HS2 Clear(optional CLEAN UP: Clean up paint tools or spills immediately with for ultimate gloss and durability). recommended thinner, carefully observing cautions on paint and thinner labels. Dried paint may be removed by scraping. ALTERNATE PRIMERS: Contact JONES-BLAIR® ;:om- pany. ENGINEERED SYSTEMS HEALTH AND SAFETY SYSTEM-A Read the Material Safety Data Sheet (MSDS) and container For maximum corrosion resistance and durability. Recom- labels for detailed health and safety information. This product mended for use in coastal and marine exposures above the is intended for industrial use by properly trained professional splash zone over a sandblasted surface. applicators only. First coat Primer: 3 dry mils of 33910 CHEM-O-Zn"II Organic Zinc Rich Primer. Second intermediate coat: 3-5 dry mils of 33010 (white) or 33514(gray)or 33114(coral)UREPRIME®HS2. Topcoat: 3 dry mils of ACRYLITHANETm HS2 in the desired color for the finish coat. The information,data and suggestions contained herein are believed to be reliable,based upon our knowledge and experience;however,it is expressly declared that Seller does not guarantee the result to be obtained in Buyer's process. SELLER HEREBY EXPRESSLY DISCLAIMS ANY IMPLIED WARRANTY OF MERCHANTABILITY FOR FITNESS FOR A PARTICULAR PURPOSE AND/OR ANY OTHER WARRANTY,EXPRESS OR IMPLIED as to any and all products and/or suggestions described herein,whether such products are used alone or in combination with other materials. Buyer must make its own determination of the suitability of any product for its use,and the completeness of any information contained herein. Nothing contained herein shall be construed to constitute inducement or recommendation to practice any invention covered by any patent without authority from the owner of the patent. 09192006 AcrylithaneHS2TD.indd jb JONES-BLAIR® 2728 Empire Central-P.O.Box 35286-Dallas,TX 75235-Telephone(214)353-1600-Fax(214)350-7624-www.jones-blair.com Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 1.IDENTIFICATION Product Name ACRYLITHANE HS2 NEUTRAL TINT BASE Product Code 4300-022 Document ID G4300-022 Revision Number 1 Prior Version Date None Intended Use Industrial Maintenance Coating Restrictions On Use For Industrial Use Only Chemical Family Acrylic Urethane Enamel Chemical Manufacturer/Importer JONES-BLAIR®Company,LLC 2728 Empire Central Dallas,TX 75235 1-214-353-1600 Emergency Telephone Number: ChemTrec Center 1-800-424-9300 International: 703-527-3887 2.HAZARD(S)IDENTIFICATION Classification of the chemical in accordance with paragraph(d)of§1910.1200; Hazard Pictograms GHS Classification Skin Sensitisation Category 1 Skin Corrosion/Irritation Category 2 Serious Eye Damage/Eye Irritation Category 2A Carcinogenicity Category 2 Specific Target Organ Systemic Toxicity(STOT)-Single Exposure Category 2 Flammable Liquid Category 3 Signal Word Warning Hazard Statements Flammable liquid and vapour.Causes skin irritation. May cause an allergic skin reaction.Causes serious eye irritation.Suspected of causing cancer. May cause damage to organs. Precautionary Statements Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat,sparks,open flames and hot surfaces.No smoking.Keep container tightly closed.Ground/bond container and receiving equipment. Use explosion-proof electrical,ventilating, and lighting equipment.Use only non-sparking tools.Take precautionary measures against static discharge.Do not breathe dust,fume,mist,vapours or spray.Wash thoroughly after handling. Do no eat,drink or smoke when using this product.Contaminated work clothing should not be allowed out of the workplace.Wear protective gloves, protective clothing,eye protection and face protection. Use personal protective equipment as required. ACRYLITHANE HS2 NEUTRAL TINT BASE Page 1 of 7 Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 Response IF ON SKIN(or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing. IF exposed or concerned: Get medical attention.IF exposed or if you feel unwell:Call a POISON CENTER or physician. If skin irritation or rash occurs:Get medical attention. If eye irritation persists:Get medical attention. Take off contaminated clothing and wash before reuse.In case of fire: Use alcohol resistant foam,carbon dioxide,dry chemical,or water spray for extinction. Storage Keep container tightly closed.Store in a well-ventilated place.Keep cool.Store locked up. Disposal Dispose of contents and container in accordance with all local,regional, national and international regulations. Hazards Not Otherwise Not applicable Classified(HNOC) Additional Information Not applicable 3.COMPOSITION/INFORMATION ON INGREDIENTS Chemical Component CAS# Ethyl 3-ethoxypropionate 763-69-9 5-10 Methyl Amyl Ketone 110-43-0 3-7 n-Butyl acetate 123-86-4 3-7 Ethylene glycol monobutyl ether acetate 112-07-2 1 -5 Light aromatic solvent naphtha 64742-95-6 0.5-1.5 Bis(1,2,2,6,6-pentamethyl-4-piperidyl) 41556-26-7 0.1 - 1 sebacate Ethylbenzene 100-41-4 0.1 -1 methyl 1,2,2,6,6-pentamethyl-4-piperidyl 82919-37-7 0.1 1 sebacate The specific chemical identity and/or exact percentage(concentration)of composition has been withheld as a trade secret. 4.FIRST-AID MEASURES Inhalation Remove individual to fresh air after an airborne exposure if any symptoms develop as a precautionary measure. Eye Contact In case of contact,immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention immediately. Skin Contact Wash with soap and water. Remove contaminated clothing and launder.Get medical attention if irritation develops or persists. Ingestion If swallowed,do not induce vomiting. Get medical attention immediately. Induce vomiting as a last measure. Induced vomiting may lead to aspiration of the material into the lungs potentially causing chemical pneumonitis that may be fatal. Most Important Acute Symptoms Not Available and Effects Most Important Delayed Symptoms Not Available and Effects Special treatment needed: No additional first aid information available ACRYLITHANE HS2 NEUTRAL TINT BASE Page 2 of 7 Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 5.FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use alcohol resistant foam,carbon dioxide,or dry chemical extinguishing agents.Water spray or fog may also be effective for extinguishing if swept across the base of the fire.Water can also be used to absorb heat and minimize fire damage. Unsuitable Extinguishing Media No data available Fire and/or Explosion Hazards Vapors may be ignited by sparks,flames or other sources of ignition if material is above the flash point giving rise to a fire(Class B).Vapors are heavier than air and may travel to a source of ignition and flash back. Container may explode in heat of fire. Hazardous Combustion Products Carbon dioxide, Carbon monoxide,Toxic fumes,Toxic gases Special Protective Equipment and Do not enter fire area without proper protection including self-contained Precautions for Fire-Fighters breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Do not enter fire area without proper protection including self-contained breathing apparatus and full protective equipment. Fight fire from a safe distance and a protected location due to the potential of hazardous vapors and decomposition products. Flammable component(s)of this material may be lighter than water and burn while floating on the surface. 6.ACCIDENTAL RELEASE MEASURES Personal Precautions,Protective Exposure to the spilled material may be irritating or harmful.Follow Equipment and Emergency Procedures personal protective equipment recommendations found in Section VIII of this SDS.Additional precautions may be necessary based on special circumstances created by the spill including the material spilled,the quantity of the spill,the area in which the spill occurred.Also consider the expertise of employees in the area responding to the spill. Methods and Material for Containment Prevent the spread of any spill to minimize harm to human health and and Cleaning Up the environment if safe to do so. Dike with suitable absorbent material. Gather and store in a sealed container pending disposal. Shut off ignition sources; including electrical equipment and flames.Do not allow smoking in the area. 7.HANDLING AND STORAGE Precautions for Safe Handling Harmful or irritating material.Avoid contacting and avoid breathing the material.Use only in a well ventilated area. As with all chemicals,good industrial hygiene practices should be followed when handling this material.Wash thoroughly after handling. Do not get in eyes,on skin and clothing. Ground and bond containers when transferring material. Use spark-proof tools and explosion-proof equipment."Empty" containers retain product residue(liquid and/or vapor)and can be dangerous. Remove contaminated clothing and wash before reuse. Conditions for Safe Storage Store in a cool dry place.Keep container(s)closed. Keep away from sources of ignition. Materials to Avoid/Chemical Oxidizing agents, Caustics(bases,alkalis),Acids Incompatibility 8.EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Limits ACRYLITHANE HS2 NEUTRAL TINT BASE Page 3 of 7 Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 Chemical Component OSHA PEL ACGIH TLV-TWA ACGIH STEL Methyl Amyl Ketone 100ppm;465mg/m3 50ppm;233mg/m3 (TWA) TWA n-Butyl acetate 150 ppm TWA;710 150 ppm TWA;713 200 ppm STEL;950 mg/m3 TWA mg/m3 TWA mg/m3 STEL Ethylene glycol monobutyl ether 2oppm TWA acetate Ethylbenzene 100 ppm TWA;435 100 ppm TWA;434 125 ppm STEL;543 mg/m3 TWA mg/m3 TWA mg/m STEL Appropriate Use local exhaust ventilation or other engineering controls to minimize exposure. Engineering Controls Engineering controls must be designed to meet the OSHA chemical specific standard in 29 CFR 1910. Explosion proof exhaust ventilation should be used. Respiratory Protection General or local exhaust ventilation is the preferred means of protection. In cases where ventilation is inadequate,respiratory protection may be required to avoid overexposure. Follow respirator manufacturer's directions for respirator use. Eye Protection Wear safety glasses with side shields when handling this product.Wear additional eye protection such as chemical splash goggles and/or face shield when the possibility exists for eye contact with splashing or spraying liquid,or airborne material.Have an eye wash station available. Skin Protection Where use can result in skin contact, practice good personal hygiene.Wash hands and other exposed areas with mild soap and water before eating,drinking,and when leaving work. Clothing suitable to prevent skin contact. General Hygiene As with all chemicals,good industrial hygiene practices should be followed when Conditions handling this material.Wash thoroughly after handling. Do not get in eyes,on skin and clothing.Ground and bond containers when transferring material. Use spark-proof tools and explosion-proof equipment."Empty"containers retain product residue(liquid and/or vapor)and can be dangerous.Remove contaminated clothing and wash before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical State Liquid Color Colorless Odor Ester-Like Odor Threshold No data available pH No data available Melting Point/Freezing Point(TM) No data available/No data available Initial Boiling Point and Boiling Range Low(T) 257.0 High(7) 337.5 Flash Point('F/`C) 102/39 Evaporation Rate 0.40(n-Butyl Acetate= 1.0) Flammability(solid,gas) No data available Upper Flammable/Explosive Limit 7.9% Lower Flammable/Explosive Limit 1.1 % Vapor Pressure 8.00 mbar Vapor Density 4.00 Relative Density 4.500 Solubility in Water Low; 10-39% Partition coefficient: n-octanol/water No data available Auto-ignition Temperature No data available Decomposition Temperature: No data available Viscosity 20-30 Z4 Volatiles,%by volume 44.39 ACRYLITHANE HS2 NEUTRAL TINT BASE Page 4 of 7 Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 Volatiles,%by weight 27.62 Volatile Organic Chemicals(g/L) (Regulatory, Calculated) 396.22 (Actual, Calculated) 396.22 Density 11.88-12.08 lbs./Gal 10.STABILITY AND REACTIVITY Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions No data available Conditions to Avoid Temperatures above flash point in combination with sparks, open flames,or other sources of ignition. Contamination. Incompatible Materials Oxidizing agents, Caustics(bases,alkalis),Acids Hazardous Decomposition Products Carbon dioxide, Carbon monoxide,Toxic fumes,Toxic gases 11.TOXICOLOGICAL INFORMATION Routes of Exposure Inhalation Ingestion Skin contact Eye contact Immediate(Acute)Health Effects by Route of Exposure Inhalation Toxicity Vapor harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Skin Contact Can cause moderate skin irritation. Skin Absorption May be harmful if absorbed through skin. Eye Contact Causes eye irritation. Ingestion Toxicity Harmful if swallowed.Aspiration of material into the lungs can cause chemical pneumonitis which can be fatal. Long-Term(Chronic)Health Effects Carcinogenicity Possible cancer hazard.Contains ethylbenzene which may cause cancer based on animal data.(Risk of cancer depends on duration and level of exposure.) Inhalation NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Product Toxicology Data Oral Acute Toxicity Estimate(ATE) 5,638.96 mg/kg Inhalation Dust/Mist Acute Toxicity Estimate 53.79 mg/L (ATE) Inhalation Vapor Acute Toxicity Estimate 51.41 mg/L (ATE) Dermal Acute Toxicity Estimate(ATE) 39,445.28 mg/kg Component Toxicology Data Chemical Component Oral LD50 Dermal LD50 Inhalation LC50 Oral LD50 Male Rat>5000 Dermal LD50 Rabbit— Inhalation LC50(6h)Male Ethyl 3-ethoxypropionate mg/kg 4080-4680 mg/kg Rat>998.00 mg/L Oral LD50 Female Rat— 4309 mg/kg Methyl Amyl Ketone Oral LD50 Rat 1600 mg/kg Dermal LD50 Rabbit Inhalation LC50(4h)Rat> 10,206 mg/kg 16.70 mg/L n Butyl acetate Oral LD50 Rat 10,760 Dermal LD50 Rat 12,789 Inhalation LC50(4h)Rat> mg/kg mg/kg 21.00 mg/L ACRYLITHANE HS2 NEUTRAL TINT BASE Page 5 of 7 Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 Ethylene glycol monobutyl ether Oral LD50 Rat 1880 mg/kg Dermal LD50 Rabbit 1500 Inhalation LC50(6h) :2at> acetate mg/kg 4.59 mg/L Light aromatic solvent naphtha Oral LD50 Rat 8400 mg/kg Dermal LD50 Rat>2000 Inhalation LC50(4h)Rat mg/kg 5.60 mg/L Ethylbenzene Oral LD50 Rat 3500 mg/kg Dermal LD50 Rabbit 5510 Inhalation LC50(4h)Rat mg/kg 17.00 mg/L Carcinogen Information Chemical Name IARC Carcinogen OSHA Carcinogen NTP Carcinogen Ethylbenzene 2B 12. ECOLOGICAL INFORMATION Ecotoxicity(aquatic and No data available terrestrial,where available) Mobility in soil No data available 13. DISPOSAL CONSIDERATIONS Safe Handling of Waste Refer to other sections of this SDS to determine the toxicity and physical characteristics of the material to determine the proper waste identification and disposal in compliance with applicable regulations. 14.TRANSPORT INFORMATION This section provides basic shipping classification information and does not contain all regulatory transportation details. Refer to all applicable regulations for domestic, international,air,vessel and ground transportation requirements and restrictions. DOT Basic Description: Paint Hazard Class: 3 UN Number: UN1263 Packing Group: III Other: Not regulated for non-bulk domestic ground shipments for packaging of 450 liters(119 gallons)or less(DOT 49CFR 173.150(f)). Marine Pollutant: No 15. REGULATORY INFORMATION TSCA Status All components of this product are either listed on the TSCA Inventory; or,are not subject to the inventory notification requirements. Regulated Components SARA EHS Chemicals CAS# Not applicable CERCLA n-Butyl Acetate 123-86-4 3-7 Ethyl Benzene 100-41-4 0.1 -1 SARA 313 Ethylene glycol monobutyl ether acetate 112-07-2 1 -5 Ethylbenzene 100-41-4 0.1 -1 SARA 311/312 ACRYLITHANE HS2 NEUTRAL TINT BASE Page 6 of 7 Safety Data Sheet Revision Date:06-15-2015 Product Code:4300-022 Health(Acute): Y Health(chronic): Y Fire(Flammable): Y Pressure: N Reactivity: N U.S.State Regulations: California Prop 65 Chemicals Cancer CAS# Ethyl Benzene 100-41-4 0.1 -1 Cumene 98-82-8 0.01 -0.1 Benzene 71-43-2 0.001-0.01 Reproductive Toluene 108-88-3 0.001-0.01 Benzene 71-43-2 0.001-0.01 Canadian Regulations: CEPA DSL: The components of this product ARE listed on the Canadian Domestic Substances List. WHMIS Hazard Class: B3 D2A 16.OTHER INFORMATION Revision Date 06-15-2015 Disclaimer This SDS has been prepared in accordance with the OSHA Hazard Communication Standard(29 CFR 1910.1200)and Canada's Controlled Product Regulations(CPR).To the best of our knowledge the information contained herein is accurate. Determination of safe handling,application and use of this material is the responsibility of the end user.This information is furnished without warranty,expressed or implied. ACRYLITHANE HS2 NEUTRAL TINT BASE Page 7 of 7