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SS9901-SP050222Environmenta~ystems_Divisi~n~ SUBMITTAL PACKAGE #052492S-001 DEFOREST LIFT STATION PASSIVE DRUM SCRUBBER MODEL DS-300P Revise .~ ~)s~;bnnI r C. R¢iec ed C~ !LL, TX OWNER Deforest Lift Station 600 Deforest Road Coppell, TX 75019 CONTRACTOR Can-Fer Construction 11031 Grissom Lane Dallas, TX 75229 Ph: (972) 484-4344 Fax: (972) 484-4223 MANUFACTURER Purafil, Inc. 2654 Weaver Way Doraville, GA 30340 Ph: 800-222-6367 Fax: 770-263-6922 REPRESENTATIVE Newman Regency Group 7320 Ashcroft, Suite 306 Houston, TX 77081 Ph: (713) 981-7448 Fax: (713) 981-8642 INDEX TAB 1 1.0 DRUM SCRUBBER SPECIFICATIONS TAB2 2.0 PRODUCT DRAWING TAB4 3.0 MEDIA INFORMATION 4.0.1 MEDIA BROCHURES 4.0.2 MATERIAL SAFETY DATA SHEETS TAB 5 4.0 WARRANTY INFORMATION 1.0 DRUM SCRUBBER SPECIFICATIONS 1.0.1 This submittal defines the requirements for a 150-gallon drum scrubber (DS-300) as manufactured by Purafil, Inc., Environmental Systems Division. 1.0.2 1.0.3 The drum contains 450 lbs of Odorcarb II Media and 400 lbs of Odormix Select Media. ~i~ ~ ~c~,~ ~c I~-'~ L,~> ~ ~e dram scrubber has an 8" Flexible Coupling inlet connector that will provide veaical ~rflow through the media bed. ~e contractor will be responsible for ductwork leading to ~e dram scrubber. 1.0.4 Major components of the scrubber system shall include: Corrosion resistant 150 gallon LDPE drum Eight inch inlet with eight inch flexible coupling Three quarter inch pvc drain pipe 450 pounds of Odorcarb II Media 400 pounds of Odormix Select Media First...inclean air SERVICE GUIDE #122 Installation, Operation & Maintenance Instructions Drum Scrubbers 100 CFM, 300 CFM, 500 CFM Models Purafil, Inc. * 2654 Weaver Way * Doraville, GA 30340 * Telephone: (770) 662-8545 * Fax: (770) 263-6922 TABLE OF CONTENTS 1.0 PRE-INSTALLATION INSTRUCTIONS 1.1 SAFETY CONSIDERATIONS 1.2 RECEIVING INSTRUCTIONS 1.3 INSPECTION 1.4 STORAGE 1.5 FOUNDATIONS AND CLEARANCES 2.0 BASIC DESIGN OF THE DRUM FILTER FIGURE 1: BASIC DESIGN 3.0 INSTALLATION 3.1 POSITIONING THE UNIT 3.2 MEDIA BANK FILLING INSTRUCTIONS (INITIAL START-UP) 3.3 MEDIA BANK FILLING INSTRUCTIONS (MEDIA REPLACEMENT) 3.4 POST-START INSPECTION/CHECK 4.0 MAINTENANCE 4.1 REPLACEMENT PARTS AND MATERIALS 4.2 MEDIA REPLACEMENT 4.3 SPECIAL PRECAUTIONS 4.4 PURAFIL® STAIN REMOVAL 5.0 WARRANTY 6.0 TROUBLE SHOOTING 7.0 SAMPLING RECORD 1 1 2 3 3 4 5 5 5 6 7 7 8 9 10 11 12 1.0 PRE-INSTALLATION INSTRUCTIONS 1.1 SAFETY CONSIDERATIONS · Read this Service Manual carefully. Be thoroughly familiar with the controls and the proper use of the equipment. · This manual should be retained with the scrubber because it contains the information necessary for proper maintenance. · Keep all nuts, bolts, and screws tight to be sure the equipment is in safe working condition. CAUTION: · Installer should be a trained, experienced service person. · Check the assembly and component weights to be sure that the rigging equipment can handle them safely. · Be sure that the scrubber is well balanced in the transporting device. · Always conduct a thorough check when the installation is complete. · Never enter an enclosed blower cabinet or reach into a housing while fan is running. · The motors in PURAFIL® equipment get very hot. This is normal and should not be regarded as a problem. However, take special care to avoid touching hot areas of the motor. 1.2 RECEIVING INSTRUCTIONS Systems are normally shipped already assembled and with motors mounted. All scrubbers are securely attached to skids. It is recommended that the scrubber be left on the skid for protection and ease of handling while transporting. Straps, rigging, slings, or hooks attached to the skids may be used with proper care. The scrubber is well protected with triple wallboard and is secured with metal bands. Forklifts may be used under the skids, but exercise caution to prevent damage. Upon receiving systems from Purafil, Inc., note any shipping damage, obvious or hidden, to your carrier and on your Bill of Lading. All problems should be handled - 1 - Service Guide #I22 - Rev. 08/03 between the customer and carrier except for U.P.S. shipments, which require the customer to contact Purafil, Inc. for action. · If the scrubber is to be stored before use, see Section 1.4 in this manual for storage instructions. · If the scrubber is to be installed immediately, be sure to check Section 3.0 in this manual for installation instructions. · To uncrate the scrubber, cut the metal bands and remove the packaging. · For positioning and special handling, see Section 3.1 in this manual. 1.3 INSPECTION The condition of the scrubber upon its arrival is critical to its proper operation. Prior to start-up, inspect the scrubber carefully, according to the checklist below. Correct any inadequacies before start-up to prevent possible damage or inefficiency. Note: should there be any questions concerning the scrubber, refer to the numbers found on the scrubber identification plate when contacting the PURAFIL® representative. PRE-OPERATION CHECK LIST YES NO CONDITION 1. Check the configuration and material with the sales order form 2. Measurements fit submittal requirements 3. Parts include particulate filters, media, and gage units 4. Latches hold securely and gaskets seal properly 5. Labels and serial numbers are present 6. Airflow direction is consistent with installation requirements (Check labels attached to scrubber) Note: Checking specific points is also an imperative step after the scrubber is started up. See section 3.4 in this manual for checklist. - 2 - Service Guide #122 - Rev. 08/03 1.4 STORAGE The scrubber should be protected from the elements during storage, especially when storage time is extensive. While indoor storage is considered best, outdoor storage can be adequate when precautions are taken. OUTDOOR STORAGE PRECAUTIONS Cover the equipment with a tarp. Intake and discharge openings must be well covered. (Use of black plastic as a cover may cause excessive condensation and rusting.) · If there is the possibility of moisture collection, allow for proper drainage. · Do not place heavy equipment on top of the scrubber. · Store Purafil® media in a dry place with less than 95% relative humidity. 1.5 FOUNDATION AND CLEARANCES FOUNDATIONS Some scrubbers may require new or reinforced foundations, due to their weight. Always be sure to check that the existing foundation is adequate for the scrubber to be installed. Scrubbers to be used indoors require particular attention to strength of foundation. In some instances, a concrete base is best suited to the system. Concrete lessens the chance for vibration than metal structures do. CLEARANCE All scrubbers should be easily accessible for the required periodic maintenance. Do not block return and discharge grilles. The local PURAFIL® representative can recommend sufficient minimum clearances. - 3 - Service Guide #122 - Rev. 08/03 2.0 BASIC DESIGN OF THE DRUM FILTER Designed to clean odorous air, the drum filter, coupled with the final particulate filter, contains an inlet pipe, blower, a media bed housed in a LDPE drum, and diffuser. Pre-engineered in a single scrubber, the drum scrubber is designed to exhaust recycled air. The drum scrubber is typically supplied with Purafil® Medias. The drum scrubber has a quiet, Iow horsepower motor and Iow-pressure drop. The drum filter includes the following components: 1. INLET PIPiNG/DIFFUSER - Air enters through a 4" (100 CFM model) or 8" (300, 500 CFM models) Fernco fitting prior to entering the drum. 2. MEDIA BED- 100 CFM model - consists of 1 ft30dorox Select media, 2 ft3 (cubic feet) of Odorcarb media and 2 ft3 (cubic feet) of Odormix Select media. Each cubic foot of media is contained in a MediaSak for easy handling and disposal. 300 CFM model - comes complete with 7 ft3 (cubic feet) of Odorcarb media (225 lbs) and 3 fts (cubic feet) of Odormix media (320 lbs.). 500 CFM model - comes complete with 14 ft~ (cubic feet) of Odorcarb media (315 lbs.) and 3 ft~ (cubic feet) of Odormix media (440 lbs.). 3. BLOWER - the air is then propelled further by the blower assembly, which includes a mill and chemical duty motor and direct drive blower. This assures an even, quiet airflow. 4. FINAL FILTER - any remaining contaminants, such as media dust and airborne contaminants are removed in this final stage by a high efficiency particulate filter. FIGURE 1: BASIC DESIGN - 4 - Service Guide #122 - Rev. 08/03 3.0 INSTALLATION After the entire pre-operative inspection is completed (Section 1.3), follow this next sequence for installation: (1) Remove the scrubber from the skid and position it in the designated operation location. (2) Install the particulate filter. (DS-300 and DS-500 models only) (3) Plug in the electrical connections. (4) Start the scrubber. (5) Perform post-start inspection check ( Section 3.5). Note: Before initial start-up of system, contact your local PURAFIL® representative. Their name and phone number is attached to your system. Operate afl DS models at the lowest airflow required to maintain a negative pressure and maximize media life. 3.1 POSITIONING THE SCRUBBER The standard scrubber can simply be transported by lift to its pre-designed operation location (if it is in close proximity to the skid), according to facility safety requirements. 3.2 MEDIA FILLING INSTRUCTIONS (FOR INITIAL START-UP) The drums are specifically designed for media manufactured by Purafil, Inc. Proper filling, installation, and maintenance of the media are critical for efficient operation. The Purafil Media allows the system to perform at maximum efficiency, through proper shape and bed depth. Drum filters are pre-filled with media at the factory. 3.3 MEDIA FILLING INSTRUCTIONS (FOR MEDIA REPLACEMENT) Replace the media once a media analysis has determined that it is time. (300, 500 CFM models only) TAKE CARE WHILE POURING THE FIRST 6 INCHES so it will not crush as much therefore reducing the amount of dusting. For 100 CFM Model: · Media replacement is accomplished by removing the motor/blower lid assembly. Disconnect power supply. Remove Media Saks (5). · Install new Media Saks (5). · Install motor/blower lid assembly. · See Section 4.3 for disposal precaution. - 5 - Service Guide #122 - Rev. 08/03 For 300, 500 CFM Model: · Remove motor/blower lid assembly. Disconnect power supply. · Remove Polymedia (blue) filter. · Remove layer of Odormix media. · Remove middle Polymedia (blue) filter. · Remove layer of Odorcarb media. · Install new Odorcarb media. · Install middle Polymedia (blue) filter. · Install new Odormix media. · Install top Polymedia (blue) filter. · Install motodblowerlid assembly. · Connect power supply. · See Section 4.3 for disposal precaution 3.4 POST-START INSPECTION/CHECK Before initial start-up of system, contact your local PURAFIL® representative. Their name and phone number is attached to your system. Operate all DS models at the lowest airflow required to maintain a negative pressure and maximize media life. YES NO CONDITION 1. Joints, seals, and gaskets do not leak. 2. Particulate filters have been installed. (DS-300, DS-500) - 6- Service Guide #122 Rev. 08/03 _ 4.0 MAINTENANCE 4.1 REPLACEMENT PARTS AND MATERIALS While Purafil's products are built for durability, some parts of the scrubber will require replacement during the normal lifetime of the equipment. Replacement items may be ordered from your local PURAFIL® representative or from Purafil, Inc. Consumables: In order to maintain proper performance levels, particulate filters and PURAFIL® Media must be replaced periodically, as they have a finite life (See Sampling Procedure Service Guide). Moving Parts: Bearings, motors, etc. are all subject to gradual deterioration and/or sudden breakdown. 4.2 MEDIA REPLACEMENT NEED FOR SAMPLING (300, 500 CFM models only) · PURAFIL® media has a finite life, which is a function of the available potassium permanganate (KMnO4) expressed as a percentage. After start-up, your local Purafil representative will work with the owner periodically to secure media samples. Purafil, inc. will provide regular laboratory analysis of such samples to establish life cycles. Note: the color change of media does not indicate the level of remaining life. Since every installation varies due to the type and quantity level of the contaminant, operators must develop a sample schedule best suited to their system. However, until a schedule can be established, we recommend that a sample is taken following initial startup and sent for analysis, so a replacement date can be projected with a recommended sampling schedule. To take a sample from the media: 1. For the DS-300 and DS-500, utilize the media sampling ports located on the outside of the drum and insert the sampling probe into the media bed. 2. Open the entry port of the sampling probe, pulling up until the port cover slides open. 3. Close the sampling probe by pushing down and pour the contents into the plastic sample bag provided by your PURAFIL® representative. 4. Seal tightly and label the laboratory bag. Use the same label name on the Transmittal Sheet. 5. Place a label on the media bed to show that a sample was taken from it. - 7 - Service Guide #122 - Rev. 08/03 6. Fill out the PURAFIL® Sample Transmittal and send it with the samples to the local representative, or send it to the Purafil, Inc. laboratory. A replacement sampling kit will be mailed to you. A sampling record sheet is included with this manual. Record the following data, and file all related reports with the record sheet: · Date that the sample is taken and mailed · Results of life analysis as reported by the Purafil Laboratory After the Purafil® laboratory has analyzed a sample, a Certificate of Analysis will be sent to you detailing the approximate percentage of total life consumed. A projected replacement date will be given for each scrubber if installation and sampling dates are provided. The projected replacement dates may be used in updating budget requirements as well as a guide in ordering replacement material. However, since contaminant load is rarely constant, avoid relying too heavily on projected replacement dates. By maintaining records of the life expenditures of each filter bank, the media banks with the greatest percentage of life expended can be replaced before others that have less life expended. 4.3 SPECIAL PRECAUTIONS Disposal PURAFIL® media is a non-toxic, non-flammable substance. Filtration of contaminants through PURAFIL® media causes molecular changes to occur, and the resulting product is usually not harmful to the environment. Although special precautions are generally not required when disposing of spent media, government regulations may require specific disposal procedures if the resulting product could be harmful to the environment. Large quantities of PURAFIL® media should not be disposed of in dumpster-like equipment because the weight of the media could cause difficulties in handling the dumpster. Independent laboratory analysis for Environmental Protection Agency toxicity characteristics may be required if the contaminants eliminated from your environment include heavy metals and pesticides. Inhalation A well-ventilated work area is suggested for changing the PURAFIL® media, as dusting occurs in fresh media due to handling abrasion. Workers should avoid direct inhalation of considerable PURAFIL® dust, as it induces sneezing. In closed, unventilated spaces, dust masks such as the 3-M No. 8500 are suggested. - 8 - Service Guide #122 - Rev. 08/03 Water Avoid exposing the PURAFIL® media to water or precipitation, as this dissolves permanganate content. Storage of media should be in a dry place with less than 95% relative humidity. Exposure of permanganate solution to the skin causes brown staining which is temporary and not harmful. This staining can be removed by washing in a diluted solution of water and sodium bisulfite. Eye Contact if dust is exposed to the eyes or delicate membrane, flush thoroughly with water and seek treatment by a physician. Follow normal procedures for exposure to abrasive dust. 4.4 PURAFIL® STAIN REMOVAL The following stain removal procedure is stated here as information only, and neither Purafil, Inc., any of its subsidiaries, nor any agent or employee of Purafil, Inc. make any warranty or other representation regarding the efficacy or safety of this procedure. The stain removal could cause further damage to the garment or to the item from which one may attempt to remove the stain. If the dust from PURAFIL® media comes in contact with organic material, there are two possible stain problems: 1. Manganese dioxide (MnO2), which is insoluble, characterized by a medium brown color, and is found in expended PURAFIL media, can usually be removed by normal washing. 2. New (unused) PURAFIL® media contains potassium permanganate (KMnO4), which is a strong oxidant and will react with and discolor any organic material with which it comes in contact. These stains, which will be brownish black in color, may be removed using a solution of sodium bisulfite in water, after the garment has been removed from the person. However, if the permanganate has damaged the fiber, removal of the stain may make the damage more apparent. CAUTION: This procedure should start with a very weak solution, gradually increasing the strength until the stain is removed. Use of too strong a solution could conceivably cause additional fabric damage. NOTE: Sodium bisulfite gives off sulfur dioxide (SO2) gas; therefore, it must be used in a well-ventilated area. - 9 - Service Guide #122 - Rev. 08/03 5.0 WARRANTY PURAFIL warrants hardware equipment manufactured by PURAFIL to be free from defects in material and workmanship under normal use and service for one (1) year from substantial completion. PURAFIL's obligation under this warranty shall be limited to replacing any parts thereof, which shall be demonstrated to have been defective. THIS WARRANTY IN LIEU OF ALL OTHER WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING THE WARRANTIES Or- MERCHANTABILITY AND FITNESS. PURAFIL MAKES NO WARRANTIES AS 'fL) MERCHANTABILITY OR AS TO THE FITNESS OF THE MERCHANDISE FOR ANY PARTICULAR USE AND SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE, DIRECTLY OR INDIRECTLY, ARISING FROM THE USE OF SUCH MERCHANDISE OR FOR CONSEQUENTIAL DAMAGES. No person, firm or corporation is authorized to assume for PURAFIL any other liability in connection with the sale of these goods. Equipment, pads, and material manufactured by others and incorporated in PURAFIL equipment are warranted by PURAFIL ONLY TO THE EXTENT OF THE ORIGINAL MANUFACTURERS LIABILITY TO PURAFIL. - 10 - Service Guide #122 - Rev. 08/03 6.0 TROUBLESHOOTING SYMPTOM PROBLEM CHECKS/REMEDY Media Bank Airflow too low Filters loaded Replace filters - 11 - Service Guide #122 - Rev. 08/03 7.0 SAMPLE RECORD , Sampling Record/Schedule Represented By Imporiant Notice The information contained in this Bulletin reflects the results of various testing and analytical procedures believed by PURAFIL, INC. (a U.S.A. corporation) to be useful indicators of the relative performance of air filtration systems and media. It is intended for use by persons having appropriate scientific and technical knowledge and experience at their own risk. This bulletin does not in any way constitute a representation, warranty, promise, or guarantee by PURAFIL, INC. of the installed performance of PURAFIL® media. - 12 - Service Guide #122 - Rev. 08/03 Z h_ LO X bJ Z Iii 0 0 x 0 O I,I hJ o o 0 O O Purafil ESD's OdorcarbTM II Media Proven Performance Odorcarb' It Media is highly effective at removing odorous hydrogen sulfide gas (H2S) and is the primary media in Purafil ESD's odor control systems for waste- water treatment applications. Characteristics · Landfill disposable · New and spent media is non-toxic · UL Classified Class 2 Media Odorcarb~ II, an activated alumina- based media shall consist of manufac- tored, generally spherical porous pellets measuring 1/16" to 1/8" in diameter. Pellets shall be formed from a combina- lion of powdered activated carbon, alu- mina and other binders, suitably impreg- nated with caustic chemicals to enhance the capacity for removal of hydrogen sul- fide. Impregnants shall be applied dudng pel- let formation, such that the impregnant is uniformly distributed throughout the vol- ume of the pellet. Disposal Requirements Spent OdorcarbTM II Media should be dis- posed of according to local, state and federal guidelines. The Chemisorptive Process The chemisorptive process shall remove contaminant gases by means of adsorp- tion, absorption, and chemical reaction. Gases shall be trapped within the pellet where an irreversible chemical reaction changes the gases into harmless solids, eliminating the possibility of desorption. Removal Capacity Odorcarb- II Media shall meet the fol- lowing removal capacity for hydrogen sulfide: 35.0% minimum by weight. 100 lbs (45.36 kg) of OdorcarbTM II Media shall remove a minimum of 35 lbs (15.88 kg) of hydrogen sulfide. Physical Properties OdorcarbTM II Media shall have the follow- ing physical properties: · Moisture Content: 35% Max · Crush Strength: 35% - 70% Max · Abrasion: 4.5% Max · Bulk Density: 45 Ibs~t~ (721 kgs/m3) · Pellet Diameter: 1/16" - 1/8" (1.5 mm - 6.5mm) lng the Drum Scrubber with airflows from 100 to 1,000 CFM (170 to 1699 ma/hr), Tub Scrubber with airflows from 500 to 6,000 CFM (850 to 10,194 m3/hr) and Deep Bed Scrubber with airflows from 600 to 8,000 CFM (1,020 to 13,592 m~/h0. OdorcarbTM II Media shall also be effective in Vessel Scrubbers with air- flows from 8,000 to 20,000 cfm (13,592 to 33,980 m~/hr). Other Media Applications Purafil ESD's OdorcarbTM II Media is ideal for use in environments requiring control of hydrogen sulfide gas, such as waste- water treatment plants, pumping sta- tions, wet wells, lift stations and sludge holding tanks. Purefil ESD's Odorcarb' II Media can be used with other media manufactured by Purafil, Inc. Specific media are available for selection based upon the composi- lion of the contaminants present, gaseous concentration levels, airflow requirements and environmental con- cerns. These media include OdoroxidantTM, for the removal of sulfur dioxide, hydrogen sulfide, aldehydes and many organic compounds; Odormix' for broad-spectrum removal of sewerage odors; OdorkolTM for the removal of hydrocarbons; Odorkol" AM for the removal of ammonia; Chloresorb® II for the specific gas removal of chlorine; CSO' for emergency removal of chlorine and sulfur dioxide. Application Guidelines OdorcarbTM Il Media shall perform effec- tively under the following conditions and guidelines: · Temperature: -4°F to 125°F (-20°C to 51°C) Purafil ESD, Your Single Source For... · Media Manufacturing · Equipment Design & Manufacturing · Complimentary Media Life Analysis · Monitoring Instruments & Programs · Humidity: 10 - 95% RH · Airflow: OdorearbTM II Media shall be effective in Purafil ESD systems, includ- Purafil, Inc. · 2654 Weaver Way · Doraville, Georgia 30340 · Phone: (770) 662-8545 · Fax: (770) 263-6922 · www.purafil,com OdorcarbTM II Media MSDS Page 1 of 7 Revision Date: 7/20/2004 MATERIAL SAFETY DATA SHEET 1. PRODUCT AND COMPANY IDENTIFICATION Product Name (as used on the label): OdorcarbTMII Media Product Synonyms: Puracarb I1 WW, OdorcarbTM II Supplier Name and Address: Purafil, Inc. 2654 Weaver Way Doraville, GA 30340 / USA Supplier Contact Numbers: Telephone: (770) 662-8545 Facsimile: (770) 263-6922 2. COMPOSITION / INFORMATION ON INGREDIENTS Preparation Chemical Nature: The preparation is a combination of both solid base substances as well as liquid impregnants. The combined properties of the preparation are less reactive than the most reactive individual substances listed below. COMPONENTS Common ChemicalName Synonyms CAS Number Wt % Water dihydrogen oxide 7732-18-5 <35 aluminum oxide (non-fibrous) activated aluminas; 1333-84-2* <32 activated and amorphous aluminas -- <32 proprietary ingredient -- activated carbon carbon; 7440-44-0 <32 carbon, activated potassium hydroxide caustic potash, liquid 1310-58-3 >5 *For TSCA inventory reporting purposes, CAS No. 1344-28-1 was assigned for all aluminum oxide instead of the CAS No. 1333-84-2 as indicated above. 3. HAZARDS IDENTIFICATION OdorcarbTM II Media MSDS Page 2 of 7 Revision Date: 7/20/2004 Most Important Hazards: _ if crashed or handled extensively, dust may evolve and can be irritating to the eyes, skin, and respiratory tract. - Wet activated carbon removes oxygen from the air causing severe hazards for workers in enclosed spaces. The product is by no means one hundred percent activated carbon, but it may have the potential to act as described above. Before entering such an area, sampling and work procedures for low oxygen levels should be taken to ensure ample oxygen availability, observing all local, state, and federal regulations. - Solutions of this product may be caustic due to high pH. Adverse Human Health Effects: - The following medical conditions may be aggravated by exposure to the product: asthma, chronic lung disease, and skin rashes. In solution, this product may produce a basic (caustic) solution and similar precautions should be taken as those for basic (caustic) solutions when such a solution is produced. Environmental Effects: If contacted by water, the active ingredients may produce a basic solution depending on amounts of media and water. If such a solution is produced, the pH should be checked and kept within local regulations by buffering with suitable neutral or acidic agent. Emergency Overview: Inhalation: Move to fresh air. If breathing difficulty occurs or persists, seek medical attention. Skin Contact: Wash area with soap and water. Eye Contact: Flush with large quantities of water for 15 minutes. Seek medical attention. Ingestion: Seek medical attention. 4. FIRST-AID MEASURES First aid measures should be taken as indicated below for the following routes of exposure. Inhalation: Move to fresh air. If breathing difficulty occurs or persists, seek medical attention. Sldn Contact: Wash area with soap and water. Eye Contact: Flush with large quantities of water for 15 minutes. Seek medical attention. Ingestion: Seek medical attention. Notes to Physician: Treatment is recommended to be symptomatic and supportive. If patient has been exposed to this product in solution, the solution may be basic (caustic), treat the affected person appropriately. 5. FIRE-FIGHTING MEASURES OdorcarbTM II Media MSDS Page 3 of 7 Revision Date: 7/20/2004 Suitable Extinguishing Media: If involved in a 15rte, flood with plenty of water. Specific Hazards: When involved in a fire, the dilute potassium hydroxide may liberate hydrogen and the solid base materials may liberate carbon monoxide. Protection of Firefighters: Fire fighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus and full protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions: Protective clothing appropriate for the environment should be worn. Goggles or safety glasses with side shields, NIOSH approved dust masks, rubber or plastic gloves, and full cover clothing covering arms and legs are recommended. Environmental Precautions: See section 3. HAZARDS IDENTIFICATION, Environmental Effects. Methods for Cleaning Up: Clean up using dry procedures (broom, shovel, etc.); avoid dusting. Recovery: Product may be recovered for use if it has not come in contact with liquid, changed color, or been exposed to significant amounts of gaseous contaminants. Neutralization: See section 3. HAZARDS IDENTIFICATION, Environmental Effects. Disposal: See section 13. DISPOSAL CONSIDERATIONS. OdorcarbTM II Media MSDS Page 4 of 7 Revision Date: 7/20/2004 7. HANDLING AND STORAGE Handling: Use air conveying (vacuum) for bulk removal. If manual handling is used for transfer (from vessel, slingbags, boxes, or pails), use mechanical ventilation or other measures to remove airborne dust. Technical Measures: The following precautions should be taken when handling the product. Prevention of User Exposure: Goggles or safety glasses with side shields are recommended. NIOSH approved dust masks are recommended. Rubber or plastic gloves are recommended. Full cover clothing covering arms and legs is recommended. Precautions for Safe Handling: - Wet activated carbon removes oxygen from the air causing severe hazards for workers in enclosed spaces. The product is by no means one hundred percent activated carbon, but it may have the potential to act as described above. Before entering such an area, sampling and work procedures for low oxygen levels should be taken to ensure ample oxygen availability, observing all local, state, and federal regulations. Avoid crushing the product to keep dusting to a minimum. As described under Handling above, mechanical ventilation or other measures may be needed to remove airborne dust. - Protect from water and exposure to contaminated air (gaseous, particulate, and aerosol contaminated), otherwise the product may be rendered useless. Storage: General good storage practices should be followed. Storage Conditions: The following storage conditions should be maintained. Suitable Conditions: Store in a cool, dry area and keep in original, closed containers. Incompatible Products: Product should be kept protected from water and exposure to contaminated air (gaseous, particulate, and aerosol contaminated), otherwise the product may be rendered useless. Packaging Materials: The following materials are used and should be used for packaging of the product. These are intended to keep contaminants away from the product. Recommended Materials: - Corrugated boxes of 350 lb, double wall quality, with 4 mm plastic liners. - Injection molded, polystyrene pails and lids including a neoprene seal. Not Suitable Materials: Porous materials allowing contact with water, air, and the contaminants contained therein. OdorcarbTM II Media MSDS Page 5 of 7 Revision Date: 7/20/2004 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Measures: Minimize eye and skin contact by using appropriate protective equipment. Use local or general room ventilation to control airborne dust that may be generated. Personal Protective Equipment: The following recommendations are made for appropriate personal protective equipment for the following. Respiratory Protection: NIOSH approved dust mask Hand Protection: Rubber or plastic gloves Eye Protection: Goggles or safety glasses with side shields Skin and Body Protection: Full cover clothing covering arms and legs. Hygiene Measures: Do not inhale dust and avoid contact with eyes. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Form: Spherical pellets approximately 1.5 - 6.4 mm (1/16 - 1/4 in.) in diameter Color: Black Odor: No significant odor PH: Not relevant Temperature of Physical State Change: Not relevant Flashpoint: Not relevant Ignition Temperature: >300°C (572°F)[~] Bulk Density: 0.721 g/cc (45 lb/ft3) Solubility: Insoluble 10. STABILITYAND REACTIVITY Stability: Stable under normal conditions. Hazardous Reactions: none known Materials to Avoid: Protect from water and exposure to contaminated air (gaseous, particulate, and aerosol contaminated), otherwise the product may be rendered useless. Hazardous Decomposition Products: When involved in a fire, the dilute potassium hydroxide may liberate hydrogen and the solid base materials may liberate carbon monoxide. Intended Use and Foreseeable Misuse: Intended use is for air purification from gaseous contaminants. The product is not intended to remove dangerous particulates or biological contaminants. Other media/systems would be required for those. The product is not intended to purify water. 11. TOXICOLOGICAL INFORMATION Odorcarbm II Media MSDS Page 6 of 7 Revision Date: 7/20/2004 Acute Toxicity: Expected to be low[21, not tested Local Effects: See section 3. HAZARDS IDENTIFICATION, Adverse Human Health Effects. Sensitization: Primary skin irritation and corrosivity (rabbits): expected to be low[21, not tested Eye irritation (rabbits): expected to be an irritantI2~, not tested Primary Route of Entry: Inhalation, ingestion, skin contact, eye contact 12. ECOLOGICAL INFORMATION Not determined. See Section 3. HAZARDS IDENTIFICATION, Environmental Effects. 13. DISPOSAL CONSIDERATIONS Waste From Residues: New product (media) can generally be disposed of in a landfill. Spent media that has removed toxic chemicals should be examined for specific hazards. Local regulations should always be consulted and followed. Contaminated Packaging: Not relevant 14. TRANSPORT INFORMATION International Regulations: Odorcarb II media contains approximately 30% (by weight) activated carbon, which is produced by a steam activation process. Because of this Odorcarb II is not subject to the provisions of the International Dangerous Goods Code (IMDG) or the labeling and packaging requirements of International Maritime Organization OMO) Class 4.2. Proper Shipping Name: Not Applicable 15. REGULATORY INFORMATION Regulations: This section contains information specifically applicable to the chemical product relative to the following regulations. Local regulations should always be consulted and followed. SARA Title III (Superfund Amendments and Reauthorization Act) Section 302 Extremely Hazardous Substances (40CFR355): Not Listed Section 312 Hazard Categories (40CFR370.2): Only expected as Acute (eye irritant), see section 11 TOXICOLOGICAL INFORMATION Section 313 Reportable Ingredients (40CFR372): None liste& 16.OTHER INFORMATION OdorcarbTM II Media MSDS Page 7 of 7 Revision Date: 7/20/2004 Disclaimer: The information contained herein is accurate to the best of our knowledge. We do not suggest or guarantee that any hazards listed herein are the only ones, which exist. Purafil, Inc. makes no warranty of any kind, express or implied, concerning the safe use of this material in your process or in combination with other substances. Effects can be aggravated by other materials and/or this material may aggravate or add to the effects of other materials. The user has sole responsibility to determine the suitability of the material for any use and the manner of use contemplated. [~ According to ASTM D 3466-76 - Standard Test Method for Ignition Temperature of Granular Activated Carbon. [2] According to methods described in US Government Document 29CFR1910.1200. Purafil ESD's Odormix Media AppUcations Purafil ESD's Odo~mix Med~a is designed for broad spectrum remove[ of odorous gases, includin] mercaptans, hydrocarbons, hydrogen sulfide and sulfur dioxide. Odormix Media is recommend- ed when space within Purafil ESD's multi- stase scrubber is limited; in this applica- tion, Odormlx substitutes for two media passes. Odormix is also recommended as a polishing media. Application Guidelines Pu~afll ESD's Odormix Media shall perform egzctively under the ~ollowin~ conditions ami guidelines: · 1/emperatum: -4°F to 125°F -20°C to 51~C · Humidity: 10 - 95% RH · .~dlow: Odormix Media shall be elfective in Purefil ESD systems, includ ~ 100 to 500 CFM (170 to 850 m%~), Tub ~:rubber with air (1,700 to 6,800 m?~r) and Deep myhr). C)do~rn~x Medle shgl also be to O.S m/s). · MedlI P~rformance: Purafi[ ESD's · lydia I;~: Regular media samples of Odormix Media shaft be tsken for pro iecting remaining rnec]ia I~te, ~roviclin~ Proven Performance Purafil ESD's Odormix Media offers broad spectrum removal of odorous gases related to se'*,emge treatment operations. Characteristics · Landfill disposable · UL Class 1 listed as non-flammable · Medias are pre-mixed at the Factory · Substitutes For a two-pass media system · New and spent media is non-toxic Purafil ESD... Your Single Source · Media Manufacturing · Equipment Design & Manufactur;ng · Laboratory ~.na~ysis & Testing Services · Monitorin] Instruments & Pro~rams Media P~ra[ii ESD's Odormix Media shall consist of an equal mix (by volume) of Purafil ESD's Odoroxidant Media and Odorkol Media. Odoroxidant Media shall be manufac- tured of generally spherical, porous pellets formed [rom a combination of powdered activated alumina ~ed other binders, suitably impregnated with potassium permanganate to provide optimum adsorption, abso~tion and oxidation of a wide variety o~ gaseous contaminants. The potassium permanganate shall be applied during pellet formation, such that the impregnant is uniformly distributed throughout the pellet volume and is totally avaibble for ~eaction. Tl~e Odorkol Media shall be a premium grade, activated car- bon with a high surface area available for adsorption. Physical Properties Odoroxidant Media shall have the following phy~cal prope~ies: · Moisture Content: 35% Maximum · Crush Strenstl~: 35% - 70% · Abrasion: 4.5% Maximum · Bulk Density: 50 Ib~/ft~ (800 ~'/m~)* · Nominal Pellet Diameter: 1/8" (3.175mm) · Potassium Permanganate Content: 8% Mtn, · Percentage o{ Pellet Remaining: 80-85% after screening Odorko[ Media sha[[ ~ave the fo[lowing physical prope~- ties: · Moisture Content: 5.0% Maximum · CTC: 55 Minimum · Base Material: Activated Carbon · Bulk Density: 30 Ibs/ft~ (480 Ics/m~)* · Nominal Pellet Diameter: 1/8'* (3.175mm) *Odormix Media bulk density is 40 Ibs/~ (640 kdm') Disposal Requirements Spent Odormix Media should be disposed of according to local, state and federal guidelines. Other Media Purafil ESD's Odormix Media can be used with other media manufactured by Purafi[, Inc. Specific media are available for selection based upon the composition of the contaminants present, gaseous concentration [eve]s, aidlow requirements and environmental concerns. These media include Odoroxidant®, for the removal o~ sulfur dioxide, hydm~en sulfide, aldehydes and many organic compounds/ Odorcarbe tor the removal o[ hydrogen suJ~ide, sulfur diox- ide and chlorine~ Odorkol® for thc removal of hydrocar- bons] Odorkol AM* for the removal of ammonia~ and Chlorosorb~ II br the specific gas removal o~ chlorine. _ MATERIAL SAFETY DATA SHEET Section 1. Identity of Material PRODUCT NAME OR NUMBER ODORMIXTM SYNONYMS Select CP Blend® Media, Carbon/Purafll® Blend FORMULA C + KMn04 on A1203 CASNUMBER N/A CHEMICAL FAMILY Activated Carbon + Inorganic Oxidizer REGULATED DOTPROPERSHIPPINGNAME NMFC 13090 ALUMINA IDENTIFICATION SHIPPING ID NUMBER UN N/A NA N/A EPAP~,ZARDOUSWASTEIDNUMBER N/A Activated Carbon 40-50 7440-44-0 Aluminum Oxide 20-30 1344-28-1 Potassium Permanganate 7-10 7722-64-7 Section 2. Hazard Specifications HAZARF~ UNDER?gCF 11910 1:30 TLV= N/A I YES NO YES NO PEL = N/At PPMI rnglrns COMBUSTIBLE LIQUID X SKIN HAZARD X NFPA HAZ~'RD SIGNALi N/A FLAMMABLE MATERIAL X EYE HAZARD X HEALTH I FLAMMABILITY PYROPHORIC MATERIAL X TOXIC AGENT X STABILITY] SPECIAL EXPLOSIVE MATERIAL X HIGHLY TOXIC AGENT X DOT ~RD CLASS UNSTABLE MATER[AL X SENSITIZER X WATER REACTIVE MATERIAL X CARCINOGEN X OXIDIZER X REPRODUCTIVE TOXIN X ORGANIC PEROXIDE X BLOOD TOYJN X CORROSIVE MATER[AL X NERVOUS SYSTEM TOXIN ~ EPA HAZ~,R D WASTE CLASS N/A COMPRESSED GAS X LUNG TOXIN IRRITANT X LIVER TOXIN X KIDNEY TOXIN X Section 3. Safe Usage Data EYES Goggles or safety glasses recommended pROTECTiVE RESPIRATORY Dust mask recommended EQUIPMENT TYPES GLOVES Rubber gloves recommended OTHER None GENERAL MECHANICAL Yes VENTILATION LOCAL EXHAUST If dusting is excessive HANDLING&STORAGE Store containers in a cool, dry area. Wet activated carbon removes oxygen PRECAUTIONS from the air causing severe hazard for workers in enclosed spaces. Before entering such an area, sampling and work procedures for Iow oxygen levels should be taken to ensure ample oxygen availability, observing all local, state, & federal regulations. Lewis Publishers Grants Permission To Use This Form Which Is Designed To Comply With The MSDS Requirements of 29 CFR 1910 1200 NOTE: While the information and recommendations set forth herein are believed to be accurate, Purafil, Inc. makes no warranty implied or otherwise and disclaims all responsibility from reliance thereon. Section 4. Emergency Response Data FIRE EXTINGUISHING ~EDIA Odormix media is not flammable SPECIAL PROCEDURES None UNUSUAL HAZARDS None EXPOSURE FIRSTAID MEASURES Dust Inhalation: move to fresh air. Ingestion: seek medical attention. Skin Contact: wash area. Eye Contact: flush with large quantities of water, seek medical attention. SPILLS STEP TO BE TAKEN Clean floor with broom or shovel RQ= WASTE DISPOSAL New material may be disposed of in landfill in accordance with local, state and federer regulations.; spent material that has removed toxic chemicals should be examined for specific hazards. Section 5. Physical Hazard Data FLAMMABILITY LFL = N/A % FLASH POINT N/A °F °c METHOD USED UFL = N/A % STABILITY STABLE X CONDITIONS TO AVOID None UNSTABLE HAZARDOUS DECOMP Dilute KUnO4, carbon monoxide may be PDTS generated in the event of fire. H~,.DOUS MAY OCCUR CONDmONS TO AVOID None POLYMERIZATION WILL NOT OCCUR X INCOMPATIBILITY MATERIALS TO AVOID Protect from water and exposure to contaminated air otherwise media may be rendered useless EFFECTS OF EXPOSURE EMERGENCY TREATMENT Section 6. Health Hazard Data Odormix media is believed to be non-toxic upon oral, dermal, and inhalation exposure and is a non- irritant of the skin. Breathing of dust may cause sneezing. Skin may feel dry after contact. Odormix media is an eye irritant. Flush eye with large quantities of water; seek medical attention. Section 7, Physical and Chemical Properties ( =~) N/A SOLUBILITY IN HzO Partially soluble WILL 9~SSOLVE ~. Concentrated acids & alkalies APPEARANCE Spherical purple pellets + black particulate solid (50:50 vol:vol) is MATERIAL PASTE pOWDER ODOR NO significant odor (SOLID) LIQUID GAS Section 8. Manufacturer or Supplier Data FIRM'S NAME & MAILING ADDRESS Environmental Systems (A Division of Purafil, Inc.) P.O. Box 1188 Nomross, Georgia 30091 U.S.A. NAME (PRINT) Christopher O. Muller SIGNATURE TITLE MGR. GAS TECHNOLOGY DATE July 6, 2000 EMERGENCYTELEPHONENO. (770) 662-8545 4.0 WARRANTY INFORMATION PURAFIL® warrants hardware equipment manufactured by PURAFIL® to be free from defects in material and workmanship under normal use and service for one (1) year from shipment date. PURAFIL®'s obligation under this warranty shall be limited to replacing any parts thereof which shall be demonstrated to have been defective. THIS WARRANTY IS EXPRESSLY IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR IMPLIED, INCLUDING THE WARRANTIES OF MERCHANTABILITY. PURAFIL ® MAKES NO WARRANTIES AS TO MERCHANTABILITY OR AS TO THE FITNESS OF THE MERCHANDISE FOR ANY PARTICULAR USE AND SHALL NOT BE LIABLE FOR ANY LOSS OR DAMAGE, DIRECTLY OR INDIRECTLY, ARISING FROM THE USE OF SUCH MERCHANDISE OR FOR CONSEQUENTIAL DAMAGES. No person, firm or corporation is authorized to assume for Purafil® any other liability in connection with the sale of these goods. Equipment, parts and material manufactured by others and incorporated in Purafil® equipment are warranted by PURAFIL® ONLY TO THE EXTENT OF THE ORIGINAL MANUFACTURERS LIABILITY TO PURAFIL®